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-One of the things that they're interested in doing as opposed to what you might have thought about, what I might have thought about the Catholic Church
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-is that they're very open to looking at ideas that are that are outside the mainstream,
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-and they're not stuck in, at least in the sciences, they're not stuck in these dogmatic views, for example, of the availability of the second law.
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-I don't know what they're like on on the religious studies side.
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No, I think it's the same way.
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I mean, they want people to examine their inner lives and to look at the world in total humanistically, holistically.
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And so you can talk about anything you want, pretty much
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more so than at a big university where you offend somebody and then they'll go clamp you.
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So there's more academic freedom here, in my opinion, than you do you have in a public university.
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-Well, we certainly couldn't be doing this work.
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No, this is a very unusual time and place.
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We have a big enough university to have support, a small enough university to allow academic freedom.
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I would have been fired for this. You see
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+What is the thermodynamics?
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Is the science of how heat work and matter interact, basically.
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How does he get converted into into work?
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How does work at converted into heat?
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What is his effect on that
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thermodynamics if you take it apart,
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you have thermo, which invokes the idea of heat.
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Dynamics, which invokes the idea of mechanical objects of some sort.
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So if you put them together, thermodynamics indicates
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you're looking at how heat and mechanical objects or physical objects interact along with work.
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So it's the study of work, heat and regular matter.
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And the laws that govern them are called the laws of thermodynamics, and there are four of them.
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The zeroth law is basically a statement that you can have a thermometer, you can measure temperature or determine what equilibrium is.
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First law, conservation of energy.
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Second, law is a statement that can be stated in various ways,
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one of which is that the entropy or disorder in any physical process or the entropy of the universe increases for any spontaneous physical process.
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The third law is a way of finding of fiduciary entropy.
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So the way it's stated oftentimes is that, for instance, the entropy of a perfect crystal, that absolute zero-zero,
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which means that a perfectly organized zero temperature object in principle have zero entropy, is perfectly organized.
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Any deviation, any rising in temperature or any movement away from the crystal in state will increase its disorder.
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So it's the zeroth and third laws, the one dealing with thermometers and the one dealing with absolute values of entropy are definitional in a sense.
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They're there to kind of bracket the two central laws, which are the first and second.
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The first tells you that energy is conserved.
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The second one says that the entropy of the universe never decreases.
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So those are the real information content.
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That's the real information content of the laws of thermodynamics.
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"Clausius" stated it.
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The energy developed is constant to entropy, stripe on a maximum ¿?.
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Which means the energy of the universe is constant.
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The entropy of the universe strives toward a maximum, and that pretty much summarizes thermodynamics.
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Everything else follows from that in principle, but it gets a lot more complicated.
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I mean, obviously the real world is a lot more complicated and shows more variation these four laws indicate.
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But nonetheless, the laws of thermodynamics are considered by many to be among the most absolute laws in nature,
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because they apply virtually to everything, anything with more than just a few particles.
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Thermodynamics has something to say about it.
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+Why?
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Well, because when small particles interact, the they need to conserve energy or the entire system needs to conserve energy
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that certainly is within the purview of thermodynamics.
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And also since systems tend to explore the range of possibilities that are available to them,
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they will tend to inhabit that region of possibility space, which maximizes their possibilities for existence,
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which would indicate a striving toward maximum disorder or maximum possibility,
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which is somewhat the essence of the second law.
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So whenever you have more than a few particles interacting like gas molecules,
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if you throw them in a box, they will tend to go to a maximum entropy state.
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Rather than collecting, let's say, all on one corner where their order would be maximized, let's say.
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So nature just tends to go toward maximum entropy states.
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That's an experimental observation.
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You can make arguments for it based on probability theory, but ultimately it's an experimental fact.
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All laws of physics ultimately are contingent upon them being observed in nature.
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You can't prove a physical law by the very nature of law is something that is axiomatic,
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that cannot be proven, is something that is simply observed about the world.
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And you can either, whether you agree or disagree with it, the observations of the world are what they are.
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Theories you might be able to derive from more basic laws.
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Or regular observations you might be able to explain in terms of your theories.
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But when you get about the most fundamental things in science,
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the laws of science, by their very nature cannot be proven otherwise they wouldn't be laws,
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they'd be derivable from something more fundamental.
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The laws of nature are not written on a wall anywhere.
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They're not written on the on the particles of nature, the atoms or the molecules.
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They are the invisible rules by which everything operates, apparently.
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And we have to infer what they are from our observations.
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They are they're human constructs about what the universe is doing.
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+Give your definition of the second law, while we're talking
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there is no definition of the second law.
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There are probably between half a dozen and two dozen definitions, depending on how you want to count them.
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Not all the statements of the second law are compatible with each other.
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Some of them are more popular than others.
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So I can I can give you maybe the first top few if you want to hear those.
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It shouldn't really be called a law, should be called a principle in a sense or a meta law,
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because it it has lots of different definitions and not everyone agrees with what they are.
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Here's a statement by "Truesdell", who was one of the great historians and mathematicians of science.
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He says "every physicist knows exactly what the first and second laws mean.
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But it is my experience that no two physicists agree on them."
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+Well, that's true.
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That's generally the case.
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But let me just kind of go through with ones that people consider the best and most important, one's called "Kelvin-Plank".
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No device operating in a cycle can produce the sole effect of extraction of a quantity of heat from a heat reservoir and the performance of an equal quantity of work.
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In other words, you can't take random thermal motion, you know, in steam or water or whatever it happens to be,
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and rectify that into some sort of gross mechanical motion, into some coherent motion without somehow performing work to do that,
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in which case you somehow have to have created entropy in that process, which compensates for any decrease in entropy
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in organizing all those molecules in the first place.
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+Do you agree that some ¿?
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Sure, the laws of poker in hell, how about that?
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The zeroth law, there exist poker in hell
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first law, you can't win
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second law, you can't break even.
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The third law, you can't leave the game
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+Put hell somewhere in the middle of the heat and rectification of energy and work.
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Energy in the world is conserved, Energy in the universe is conserved.
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But with any kind of process you carry out
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There almost always be an inevitable tax on that energy
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which comes in the form of degradation of that energy into a more impoverished form,
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which you would call heat, something that's less usable.
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That's a working man's definition of the second law.
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The second law is a tax on the first law.
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let's see if I can find, here's a simpler one.
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There are no perfect refrigerators, perfectly efficient refrigerators.
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There are no perfectly efficient heat engines.
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there is no possible process for which the sole effect is that heat flows from a reservoir at a given temperature to a reservoir at a higher temperature.
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In other words, heat tends to flow from hot to cold, but it will not spontaneously flow from cold to hot.
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So when you have something like a cup of cold iced tea, you know, in a warm room, heat flows from the room into the iced tea and melts the ice.
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But you're not going to have your glass of ice tea spontaneously freeze and cast its heat into the room.
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That's not going to happen ever.
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So all of this can be, if you look at these various definitions,
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you can kind of convince yourself that what this amounts to is to say that
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for any real natural process, the entropy change in the universe will never decrease.
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It might not increase, but it will never decrease.
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The entropy of the universe, the disorder will always tend to increase.
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And if you're going to impose order on a system, you have to pay for it by creating more disorder somewhere else
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than the amount of order that you established in the process.
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that's why I say when you compare it to poker in hell, you say you can't win.
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That's like saying you can't get something for nothing.
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You can't win, which means you can't get free.
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get energy out of your system or work out of your system for free.
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That's the first of law.
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The second, I would say you're not even going to keep the work that you had originally.
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You're going to lose some of the energy Which would not be able to recover and use again.
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That's why you say you can't break even, means you only can lose.
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And the final statement having to do with the third law, which says that there's always entropy in any system that you can define.
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That means you can't leave the game regardless of how you want to play the game.
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Thermodynamics is going to apply to you and you're always going to lose in the end.
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It's like going to Las Vegas.
If you play long enough, you're going to lose it all.
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+ Can you talk about any of the things that have been observed, experiments or whatever in history
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+ or recently that at any point in time that have been used to demonstrate this principle
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The second law?
+Yeah.
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okay i have a nice and neat stack of paper here.
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I can throw the stack of paper into the air
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and it is possible that it will all fly up in the air, flutter about and land in a perfect stack on the floor.
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That's possible.
But "Tony" just laughed.
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Why?
Because he knows it's not going to happen.
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because he understands intuitively the second law, as does everybody.
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But it is theoretically possible to do that.
And it can happen.
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but what the second law says is that it's unlikely to happen.
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So anything you do in your life
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well, maybe with maybe one or two exceptions.
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And those don't violate the second law.
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But everything you do in your life increases the entropy of the universe.
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Just the very act of living increases the entropy of the universe.
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The only way to stop increasing the entropy of the universe is to shoot yourself and lie in your grave and decompose
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When you're all done decomposing and reached equilibrium.
You're not increasing the entropy of the universe anymore.
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And that's the only way to do it.
It's a no win situation.
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you're always going to lose energy into heat,
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which is why we keep eating in order to motivate our are coherent mechanical motions of our arms and legs and our minds and everything else.
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We have to keep feeding ourselves with chemical energy and burning it with oxygen from the air.
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And by constantly feeding ourselves, we can get work out of the system and out of our systems and do mechanical work.
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But in the process we're generating all sorts of entropy.
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We only have poorly been 20% efficient first because of the heat, maybe more than that.
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But we're incredible entropy generators.
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Life itself is the second law's greatest ally
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because by the act of living, we're constantly driving cars, we're building nuclear bombs,
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were burning fossil fuels, we're cleaning up our rooms.
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Everything we do, everything about life generates entropy far more than the chemicals, the inert chemicals.
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If we were to be decomposed into inert chemicals would do themselves.
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When I was a kid, I used to argue with my mom about this because
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it turns out that even when you clean up your room and turn it into what you consider an organized state,
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you've had to use the vacuum cleaner, you've had to use broom, and you had to do a lot of work in order to clean it up.
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The very act of cleaning up the room creates more entropy, more disorder on a universal level than if you just let the room in its messy state.
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So I used to argue
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So I said, Mom, look, if I don't organize my room, then I'm saving the world from a disorganized heat death.
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She never bought it, but it's actually true.
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If you really want to keep the world organized, don't do anything at all.
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Entropy is a measure of disorder.
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That's the common definition.
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But actually, nobody really knows what entropy is either.
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+I just thought I meant some sort of de-escalating into disorder.
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That that's a process.
But entropy itself has various definitions.
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the book here that I've written with "Nikulov" Has 21 different versions of entropy,
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and there are probably another 30 which have been discovered as well
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Entropy can be defined in fairly reasonable terms only for equilibrium systems, for non-equilibrium systems,
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which is virtually any system of interest, because we're only interested in how things change and the dynamic nature of the universe.
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Entropy cannot be well-defined for non-equilibrium processes.
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No one knows how to do it.
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+And what is a non-equilibrium process?
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A non equilibrium process is one that is changing in time, basically.
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Some non-equilibrium process is the process which causes the system to change as macroscopic characteristics like pressure and temperature.
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It's like a ball rolling down a hill.
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Once the ball's at the bottom of the hill and stops, that would be considered equilibrium.
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But any time the ball's is rolling down the hill, or bouncing or anything, that would be considered a non-equilibrium process.
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That's a poor description of it.
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Equilibrium is a state where the macroscopic properties,
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thermodynamic properties of a system like pressure and temperature are no longer changing.
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Any time these things are spontaneously changing or being changed from the outside, then that's considered a non-equilibrium system.
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It's a process of change.
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The problem with talking about it this way is that the whole arrow of time and the second law are entwined with each other.
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Why does time go forward?
Why does why did all these pieces of paper flutter to the ground?
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how come they don't pick themselves up and come back into my hand in reverse?
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Why don't they? The energy is there, but it doesn't happen.
There's a particular arrow of time.
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there's a particular tendency of the universe to move from one level of entropy to a higher level of entropy.
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And that, in a sense, defines the direction of time.
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So it's sometimes difficult to define non-equilibrium without defining time.
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But as soon as you start talking about time, you're almost implicitly implying the second law. So that gets confusing.
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+So how does the second law relate to equilibrium?
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The second law, I would say that systems tend toward an equilibrium state if given the chance.
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that is a state toward maximum entropy.
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+So what we call equilibrium implies a movement towards entropy?
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An isolated system will tend to move toward a maximum equilibrium state.
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And when it reaches a maximum equilibrium state from which it doesn't change any more apparently, that's called equilibrium.
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So you can consider equilibrium to be the maximum equilibrium state of a system
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in terms of working, in terms of the second law.
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I mean, the last section of this books called "The Second Law Mystique", and I call it that because there's,
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can I read a little bit?
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Perhaps more has been written about the second law across the breadth of human knowledge and endeavor than about any other physical law.
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Direct and indirect references to it can be found in all branches of science, engineering, economics, art, literature, psychology, philosophy, and the popular culture.
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Quite aside from his profound physical, technological, social, philosophical and humanistic implications.
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The second law is famous for being famous.
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It has become the epitome of scientific truth, notorious for its absolute status, virtually unquestioned by the scientific community.
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Much of its mystique can be traced to the in premature of scientists like "Einstein", "Plank", "Eddington", "Fermi", "Poincaré", "Clausius" and "Maxwell".
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Their reputations are reciprocally burnished by association with this fundamental law.
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Thus, a cycle of mystique is established.
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The following are representative quotes from Sciences and Humanities dealing with the second law and his absolute status
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outside of theater rarely does one find such melodrama.
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"Eddington" was considered one of the great scientists of the early 20th century, right up there with "Einstein".
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The law that entropy always increases.
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The second law of thermodynamics holds, I think, the supreme position among the laws of nature.
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If someone points out to you that your pet theory of the universe is in disagreement with "Maxwell's" equations
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and so much the worse for "Maxwell's" equations, if it is found to be contradicted by observation.
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Well, these experimentalists bungle things sometimes.
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But if your theory is found to be against the second law of thermodynamics, I can give you no hope.
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There is nothing for it but to collapse in deepest humiliation.
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"Einstein" wrote So the classical thermodynamics is the only theory of universal content concerning which I am convinced
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that within the framework of applicability of its basic concepts will never be overthrown.
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Now, when statements like this get popularized and these are probably the two most famous statements considering the second law
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that goes around the second law, this mystique, which if you even question, you are pretty much thrown out or ostracized from science.
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And so what we're fighting, as much as the difficulties of the experiment we're proposing,
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is the second law Mystique, which is an invisible, self-imposed censorship that science has put upon itself about what it can speak about
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it's worse than dogma because, well, you're right, it's dogma, but it's a dogma that has associated with it an extreme amount of ridicule,
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which tends to dissuade people from even entering the subject.
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Because one word that we have consciously avoided up to this point is the term perpetual motion machine.
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+That's a lot.
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There you go.
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So we tend to avoid the perpetual motion machine.
Instead, you hide behind the word "Maxwell Demon".
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"Maxwell Demon", of course, is legitimized by the great "James Clerk Maxwell".
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But if you use perpetual motion machine, the ridicule that goes behind that can be traced all the way back to "Leonardo Da Vinci" in the 14th century.
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15th, 16th century.
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+If I were to get an argument with you about the second law
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... The second law and they just insist that the second law's defined such and such and so and so
250
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And anything else is, it cannot be in violation of that because there's no such thing as violating the second law.
251
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What kind of argument? How would you paraphrase the argument?
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Well, first of all, I say it's unscientific because you can't prove all that.
253
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By the very nature you can't prove it, you can't verify it, you can over observe it over and over again.
254
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But if you believe "Popper", for instance, and this is simply somewhat simplistic, but "Popper" would say
255
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the only valid laws of nature are always intrinsically falsifiable,
256
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which means that if you can't find, and if you can't at least come up with a well, how should I put it?
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To claim that a law cannot be violated really doesn't make sense because the law is only a law if it has a possibility of being violated.
258
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In other words, you have to have laws and observation about the world.
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And it is true as long as it keeps being observed in the world,
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as soon as it stops being observed in the world, or as soon as you find an exception,
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then you can say that it is no longer a law and use some sort of modification.
262
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+And you're talking a little bit about "Maxwell" and what he observed and what's his involvement
263
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well, "Maxwell" was a theoretician primarily.
264
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But in regard to the "Maxwell Demon", what "Maxwell" was trying to do was what he would say, pick a hole in the second law.
265
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And the way he was trying to do that was to envision some sort of little creature, which was later called by,
266
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"Kelvin" was the person that first named.
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the "Maxwell Demon", which was a small creature which could, on an individual atomic basis, sort atoms either by sort one into one chamber,
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sort of another one into another chamber, such as to create a, let's say, an artificial temperature difference between two chambers.
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By creating a temperature difference, you can create a heat engine by which you can do work.
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So this little creature essentially takes an equilibrium gas, one with maximum entropy all mixed up
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and sorts it out into two kinds of particles,fast and slow particles,
272
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and then uses the difference in their temperature or their energies to do work.
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This would subvert the second law because you've taken an original high entropy equilibrium state
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and turned it into a system whereby you can actually get more work out,
275
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and that would be forbidden by the second law
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you've taken disorganize state created more order by sorting the particles in and using that order to do work
277
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+and lost nothing
and lost nothing.
278
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so it relies on the sentients of your "Maxwell Demon",
279
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and the demon himself has to be able to see the particles and then you can argue saying that he wouldn't be able to do that.
280
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And under equilibrium configurations, you'd have to be able to think and be able to sort lots and lots of particles,
281
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maybe a mole of particles 10 to the 23rd, something like that, which would be very difficult computationally.
282
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On top of that, you'd have to store the information in order to do it and ultimately have to erase it.
283
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And apparently the erasure of the information is the Achilles heel of the "Maxwell's Demon".
284
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The process of erasure ultimately creates entropy, which offsets the entropy decrease that he created by sorting the gas.
285
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So at least in my mind, it's fairly well settled.
286
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And I think in the scientific community mind, it's basically settled that the sentient "Maxwell Demon" won't work.
287
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On the other hand,
288
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there are two dozen or more nonsentient "Maxwell Daemons", which have come to light in the last 10, 15 years,
289
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which apparently have not been refuted by the scientific community and do possibly hold a chance
290
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for violating the second law under certain extreme thermodynamic conditions.
291
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And that's what colleagues of mine and I have been working on here at USD.
292
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But also what about a half a dozen other research groups around the world have worked on
293
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the one that we're proposing with and semiconductors is the only one that I'm aware of that is concrete,
294
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experimentally viable, verifiable and can be done at room temperature.
295
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That would have a very clean cut result.
296
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The rest of them are more exotic.
297
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Okay, to introduce this particular "Maxwell demon", take a piece of common aluminum foil
298
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and bite on it with a metal fillings and you'll usually use found to be pretty unpleasant.
299
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What happens is that you have electrons which can be transferred between the different metals,
300
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between the aluminum and by the silver-mercury amalgam in the filling.
301
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And as the electrons are transferred between the two metals and kind of even out between them,
302
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this charge transfer amounts to a current which can be felt through the nerves in beneath the filling
303
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and gives you a slight and unpleasant shock.
304
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This demonstrates that when you bring two metals together, you get what's called a contact potential,
305
00:27:27,847 --> 00:27:35,587
which is the potential difference between two different pieces of metal, 2 to 3 different kinds of metals as the "Fermi" levels, as they're called,
306
00:27:35,787 --> 00:27:40,743
even out between the two metals as well as the water levels of the electrons, so to speak,
307
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find a common bubble that causes one metal to charge positively,one to charge negatively.
308
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And that establishes a potential difference between the metal, a voltage usually on the order of about a volt or so.
309
00:27:51,580 --> 00:27:55,059
Well, the same kind of thing can happen if you have two different kinds of semiconductor.
310
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Semiconductors, of course, are ubiquitous in society.
311
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they're things largely made out of silicon.
312
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There are small, very small devices, and they're doped,
313
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contaminated with very small impurities, 1 part in a million or so of impurity elements.
314
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There are two basic kinds of impurities.
315
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Ones which render of electrons into the silicon lattice
316
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and once which create positive holes in silicon lattice.
317
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The ones that liberate extra electrons into the lattice are called N type semiconductors,
318
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and these would be created by doping, let's say one part in a million or so into the silicon of something like phosphorus.
319
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On the other hand, if you were to dope it with a different element, something like boron,
320
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that would create excess holes in the lattice and you can create two different kinds of silicon,
321
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one which is N type and one is P type.
322
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And if you were to join them along an interface, the ones with extra free electrons,
323
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these extra electrons can diffuse into the positive or the P type silicon
324
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and the holes from this p side can diffuse into the N side.
325
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This cross charged defusion creates a charge imbalance across a very small region called the depletion region.
326
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We have positive charges here, negative charges here.
327
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And this creates an electric field in the silicon in a potential difference between these two pieces of silicon,
328
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which is on the order of about a half to a full volt.
329
00:29:23,390 --> 00:29:27,371
+Is this a common occurrence or is this something else, especially though the silicon that you have?
330
00:29:27,372 --> 00:29:36,914
Not at all, this is found in your electronic watches, your computers, anything that has a transistor in it.
331
00:29:37,040 --> 00:29:39,889
This is what's called a PN diode or NP diode.
332
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These are very, very common electrical devices.
333
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They're the mainstay of semiconductor electronics.
334
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This process is well known, understood, theoretically and verified experimentally.
335
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There's really no question that this occurs, at least within the scientific community presently.
336
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Now, if you were to take this particular piece of silicon and kind of bend it around into a new shape like this,
337
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you would still have the charge diffusion right at this junction here
338
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and you'd have a different potential on this side versus this side.
339
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this side would be biased positively, this side negatively by this charge diffusion.
340
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If you then wrap this around and bring it down to a small, to a region where you have a physical separation opening between these two,
341
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if you have positive charges here and negative charges here, that establishes an electric field across this region
342
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and there would be a potential drop across this region equivalent to the one here
343
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the electric field stores energy and the electric field energy I can write down its is proportional to the square of the electric field intensity or strength.
344
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The stored electric field energy here turns this device essentially into a capacitor.
345
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This is a capacitor which stores the electrostatic energy in the gap.
346
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You haven't paid for this.
347
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You've not hooked this up to a battery.
348
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There's no external voltage source associated with this.
349
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This has established this energy in this yellow region, the electric field,
350
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solely by the existence of this depletion region, which is unavoidable.
351
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So you now have a capacitor which in principle will stay charged forever.
352
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Now, capacitors, they're used in electronics to drive all sorts of things like the flash cameras which "Tony" has
353
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or cardiac defibrillators.
354
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You find it in a you know, in the emergency room or something like that.
355
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And what a capacitor does is that it stores electric field energy.
356
00:31:41,360 --> 00:31:43,009
Well, as it stores energy.
357
00:31:43,010 --> 00:31:48,380
It occurred to us whether we could extract that energy somehow and one way which we found we could do it.
358
00:31:48,380 --> 00:31:51,778
There are several ways and I'll go over both of them
359
00:31:51,779 --> 00:31:54,642
is to use just a small plug of a dielectric,
360
00:31:54,643 --> 00:32:01,279
Just as a piece of metal is pulled into a magnetic field, dielectric are pulled into electric fields.
361
00:32:01,280 --> 00:32:09,650
So you can imagine that if you were to put a small plug of material here that we friction ¿?Within this channel, it can get pulled into the electric field.
362
00:32:10,820 --> 00:32:18,991
And if this were also a conductor with the conductor positive charges, the negative charges together have them short out which would kill the electric field,
363
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leaving a larger electric field ahead of them, which would continue to pull this plug forward in the field.
364
00:32:26,030 --> 00:32:30,619
As it shorted out the field here, it would still see a higher field here being pulled in this direction.
365
00:32:30,650 --> 00:32:34,369
The field back behind it would not have recovered as fast yet the field ahead will always be larger.
366
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And this plug can be pulled all the way through the channel as it comes to the end of the channel.
367
00:32:39,050 --> 00:32:41,720
There's no further electric field here, so it's no longer being accelerated.
368
00:32:41,930 --> 00:32:44,569
But meanwhile, the electric field behind it has been rebuilding itself.
369
00:32:45,200 --> 00:32:51,170
Once it rebuilds itself, it pulls the plug back and the process can repeat again and again.
370
00:32:51,560 --> 00:33:00,656
So we have shown based on calculations of real dielectrics, with real frictional coefficients,
371
00:33:00,657 --> 00:33:06,099
with real electrical conductivities, that in principle you could build a small plug,
372
00:33:06,100 --> 00:33:14,599
something on the order of a fraction of a micron size which could be pulled in and out through this channel millions of times per second and never really stop.
373
00:33:14,870 --> 00:33:17,119
It doesn't require a new power source.
374
00:33:17,210 --> 00:33:20,290
Because the power is being supplied by the electric field,
375
00:33:20,490 --> 00:33:23,900
which itself is being generated by thermal processes somewhere else.
376
00:33:24,710 --> 00:33:34,759
So this would be a non sentient "Maxwell demon" that challenges the Second law by creating organized motion out of thermal processes, out of heat.
377
00:33:34,790 --> 00:33:37,369
There is no other power source driving this.
378
00:33:39,110 --> 00:33:41,659
So that's one version of a "Maxwell Demon".
379
00:33:41,660 --> 00:33:48,530
if you were to tie a small magnet to it and have it go in and out of a coil of wire, you would have an electrical generator.
380
00:33:48,530 --> 00:33:56,309
So you could generate electrical power from this mechanical motion in principle.
381
00:33:59,420 --> 00:34:06,589
Well, I came up with the idea probably about, oh, four years ago, three or four years ago, something like that.
382
00:34:06,590 --> 00:34:08,479
It took about a year to develop it.
383
00:34:08,480 --> 00:34:17,569
Dr. "Jeffrey Wright" was instrumental in helping carry out numerical simulations, as was "Andrew Putnam", one of my former students who did a terrific job.
384
00:34:17,570 --> 00:34:20,360
+Do you have constraints with regard to the weight of the ¿?
385
00:34:20,900 --> 00:34:23,030
+The mass involved, the drag and all those things?.
386
00:34:23,150 --> 00:34:23,480
Yes.
387
00:34:23,480 --> 00:34:34,070
We've investigated what we consider all the salient parameters of the system, including electrical conductivity, dielectric constants, mass friction, all of these.
388
00:34:34,070 --> 00:34:39,235
And we find that if you build it small enough, something smaller than about a micron in size,
389
00:34:39,435 --> 00:34:44,899
you can make a device which in theory should be able to perform as indicated in this video.
390
00:34:45,980 --> 00:34:47,258
+Have you built that yet?
391
00:34:47,259 --> 00:34:48,349
no, we have not.
392
00:34:48,350 --> 00:34:49,879
We would like to.
393
00:34:49,880 --> 00:34:57,679
The technical difficulties put it probably at the state of the art of micro manufacturing, maybe a little bit beyond.
394
00:34:57,680 --> 00:35:05,170
But we think within the next five or ten years, the state of the art for micro electromechanical and nano electromechanical manufacturing
395
00:35:05,171 --> 00:35:08,989
will probably reach the point where this could be manufactured if there was the will to do so.
396
00:35:10,040 --> 00:35:14,209
+ And okay, does this put out more than it takes?
397
00:35:15,380 --> 00:35:19,340
Well, again, this is a theoretical study we've done.
398
00:35:19,340 --> 00:35:24,679
This is not an experimental study based on the theoretical studies it should be able to put out more.
399
00:35:24,890 --> 00:35:29,212
It should be able to take energy heat from the heat bath and turn it into mechanical work
400
00:35:29,412 --> 00:35:35,288
at a power rate and a power density, which is rather large in the sense that if you calculate the volume of this device,
401
00:35:35,488 --> 00:35:40,429
each one of these devices will put out roughly a nanowatt of power, which is a very, very small amount.
402
00:35:40,430 --> 00:35:43,340
But these are devices are very small themselves about the size of a blood cell.
403
00:35:43,730 --> 00:35:47,729
So if you were to stack them all together into something the size of this table,
404
00:35:47,730 --> 00:35:53,834
they could instantaneously put out as much power in principle as a nuclear power plant
405
00:35:54,657 --> 00:35:58,014
* The problem would be that you freeze entire room.
406
00:36:00,710 --> 00:36:06,079
The problem is that if it's turning heat into work, it would put out a power level of about a gigawatt per cubic meter.
407
00:36:06,560 --> 00:36:10,550
But this thing would cool down to roughly absolute zero in 3 seconds if you were in the numbers.
408
00:36:10,580 --> 00:36:16,340
+So getting energy from nothing but, you know, converting thermal energy into mechanical energy and that thermal energy have got to come from somewhere.
409
00:36:16,400 --> 00:36:16,970
That's right.
410
00:36:16,970 --> 00:36:18,349
The room is full of mechanical energy.
411
00:36:18,380 --> 00:36:19,550
Let me give you a demonstration.
412
00:36:19,857 --> 00:36:23,780
If you take this table here, this table is at roughly about 300 kelvin.
413
00:36:24,980 --> 00:36:26,956
About room temperature, 20 degrees C,
414
00:36:27,156 --> 00:36:32,030
The molecules in here are all moving about in this table at roughly the speed of sound.
415
00:36:32,360 --> 00:36:37,430
But they're all moving in different and random directions such that all their momentum essentially cancel.
416
00:36:38,660 --> 00:36:45,289
If you were to divide up this table perfectly into those molecules which are moving to the left, to the right, forward, backwards, up and down.
417
00:36:46,110 --> 00:36:47,270
And simply divide those up.
418
00:36:47,870 --> 00:36:54,349
This table would decompose at the speed of sound of six parts going in opposite in opposite directions at roughly the speed of sound.
419
00:36:54,500 --> 00:36:57,829
That's how much energy is intrinsically present in this table in the form of heat.
420
00:36:58,010 --> 00:36:59,099
And that's true of everything else.
421
00:36:59,120 --> 00:37:02,779
Your shoes, your legs, you, all the other tables, the wall, the ceiling, the air.
422
00:37:02,930 --> 00:37:09,671
All of these have intrinsic energy, but you can't tap them because of the randomization of the molecular motions.
423
00:37:09,950 --> 00:37:13,010
They tend to cancel each other out, and it's very, very difficult to rectify them.
424
00:37:13,010 --> 00:37:20,059
In fact, to rectify their motions creates more entropy than the reduction in entropy that this rectification would imply.
425
00:37:20,660 --> 00:37:22,039
That is what the second law says.
426
00:37:22,040 --> 00:37:26,000
You can't achieve this rectification without paying for it and paying for it dearly.
427
00:37:26,450 --> 00:37:34,079
So in subverting the second law, what in principle would allow you to do is rectify the intrinsic heat in a room like this.
428
00:37:34,550 --> 00:37:39,865
And as a result, you can run all the appliances in the room forever without ever plugging anything into the wall,
429
00:37:40,065 --> 00:37:42,170
simply recycling the heat energy again and again.
430
00:37:42,920 --> 00:37:44,420
And that would be a rather wonderful thing.
431
00:37:44,660 --> 00:37:49,250
it could in principle be a solution basically forever to an energy problem.
432
00:37:49,580 --> 00:37:53,030
As long as the universe is not frozen, it will have plenty of energy to run itself.
433
00:37:53,570 --> 00:37:54,756
It's all present here
434
00:37:54,956 --> 00:38:00,349
+And you could, in theory, have some other thing that generates heat next to it to get on top of it?
435
00:38:00,470 --> 00:38:01,370
No, no, not really.
436
00:38:01,370 --> 00:38:08,599
If you think about it, if you run the TV camera you're using right now has a battery in it, that battery is running it.
437
00:38:08,600 --> 00:38:11,659
But most of that energy ends up as heat, which goes into the room.
438
00:38:12,110 --> 00:38:18,199
If you had something which could collect that heat and re-use it, it would simply take that he turn it back into electrical energy and run your camera again.
439
00:38:18,830 --> 00:38:20,250
So it's not like you've ever lost the energy.
440
00:38:20,250 --> 00:38:23,570
It's just being turned and went into another form which you could recycle.
441
00:38:23,600 --> 00:38:29,329
When we develop this, we recognize that this is the electrostatic equivalent of a magnetic railgun.
442
00:38:29,660 --> 00:38:31,310
-Right, exactly,exactly.
443
00:38:31,310 --> 00:38:34,399
but it's not magnetism electrics, electrostatics here.
444
00:38:34,760 --> 00:38:37,369
But this is like a electrostatic railgun, in a sense.
445
00:38:37,550 --> 00:38:39,859
No one's ever come up with this. And it only works on a small scale.
446
00:38:39,860 --> 00:38:42,469
This will not work on a tabletop size.
447
00:38:42,590 --> 00:38:47,690
It will only work when you have very intense fields on very small objects.
448
00:38:48,050 --> 00:38:55,435
And for it to be sustained by the intrinsic biasing of this semiconductor requires that it be some micron or
449
00:38:55,443 --> 00:38:58,157
+ The size of the nature of semiconductors?
450
00:38:58,300 --> 00:39:02,170
Well, because the forces are so small, you only can move small bits of matter.
451
00:39:02,170 --> 00:39:03,460
And so you have to build them very small.
452
00:39:03,730 --> 00:39:07,060
And to get these naturally, to get to these intense electric fields.
453
00:39:07,060 --> 00:39:09,969
And that gap requires that you build the gaps are very, very small.
454
00:39:09,970 --> 00:39:12,999
+So it's very powerless, there's no power applied to this.
455
00:39:13,000 --> 00:39:14,709
Well, let's be clear about it.
456
00:39:14,720 --> 00:39:19,629
It is being powered by ultimately by the thermal energy in the device.
457
00:39:19,660 --> 00:39:24,540
In other words, the heat in the device is powering it because you're not getting energy for free here.
458
00:39:24,580 --> 00:39:26,710
Second of all, it's not about that.
459
00:39:26,800 --> 00:39:28,479
+But there's no external power supply.
460
00:39:28,750 --> 00:39:29,750
That's correct.
461
00:39:29,890 --> 00:39:34,479
+There's no voltages charging the materials.
462
00:39:34,610 --> 00:39:38,580
No, the charging it's actually created by a trade off.
463
00:39:38,590 --> 00:39:41,658
But what you have here is, on the N types of the conductor,
464
00:39:41,659 --> 00:39:47,050
you have the electrons which want to diffuse out and you have in the P type you have holes that wanted to diffuse out.
465
00:39:47,050 --> 00:39:53,080
So when you bring these two together, these electrons and holes naturally diffuse into the other medium.
466
00:39:53,290 --> 00:39:56,379
But when that occurs you get a charge separation which creates the electric field.
467
00:39:56,380 --> 00:40:01,411
So it's a natural diffusive second law process which gives rise to the second law violation,
468
00:40:01,611 --> 00:40:03,489
which is the irony of it all.
469
00:40:04,030 --> 00:40:05,650
Second law actually turns on itself here.
470
00:40:06,130 --> 00:40:12,969
The violation occurs because you have turned heat energy into mechanics, into macroscopic motion of this piston.
471
00:40:13,480 --> 00:40:14,679
That's where the violation comes.
472
00:40:14,680 --> 00:40:16,150
You've turned heat into work.
473
00:40:16,480 --> 00:40:20,590
That's that's forbidden by the most fundamental statement of the second law.
474
00:40:20,680 --> 00:40:26,008
If you want to define the second law in terms of what you can and cannot do with heat,
475
00:40:26,208 --> 00:40:32,417
then what you've done is that you have turned disorganized random thermal motions in your solid
476
00:40:32,617 --> 00:40:39,546
into some a rectified macroscopic motion of a block of material, you have rectified disorganized motion
477
00:40:39,746 --> 00:40:44,530
that violates the idea that the entropy of the universe must always increase.
478
00:40:44,530 --> 00:40:47,559
Here we have shown a way in which the entropy of the universe can decrease.
479
00:40:47,560 --> 00:40:54,039
You have taken random thermal motions and turn them into directed coherent motions of a macroscopic block of material.
480
00:40:55,180 --> 00:41:02,860
So that is a statement of the second law, which deals with entropy that would have come about by "Clausius" about 1865 when he first discovered entropy.
481
00:41:04,390 --> 00:41:09,760
A couple of years ago, we hit on an alternative form of this, which actually is superior to it because you can build it more easily.
482
00:41:09,760 --> 00:41:12,100
This one requires very fine micro machinery parts.
483
00:41:12,850 --> 00:41:16,839
A simpler version, which we're actually in the process of building prototypes for.
484
00:41:17,170 --> 00:41:22,132
Is this where you have the same basic idea, again, a P type semiconductor, N type semiconductor
485
00:41:22,332 --> 00:41:27,250
arranged such that you have a positive and negative potential established between the two regions.
486
00:41:27,970 --> 00:41:31,840
Again, the yellow corresponds to the electric field in a gap between the N and P region.
487
00:41:32,140 --> 00:41:33,140
We call this the hammer.
488
00:41:33,400 --> 00:41:34,400
I call this the anvil.
489
00:41:35,800 --> 00:41:39,309
These are very thin slivers of semiconductor which are flexible.
490
00:41:39,460 --> 00:41:44,320
So silicon is known to make very good springs.
491
00:41:44,380 --> 00:41:45,820
And these are cantilever springs.
492
00:41:46,690 --> 00:41:48,550
So this is a cutaway two dimensional drawing of it.
493
00:41:49,540 --> 00:41:52,510
Imagine you have positive charges here, negative charges here.
494
00:41:52,900 --> 00:41:56,409
Under these circumstances, these positive charges would be attracted to the negative charges.
495
00:41:56,410 --> 00:42:03,639
And presumably this could pull down the N region, stretching these springs, causing the N region to come down, touch the P region and short out.
496
00:42:04,510 --> 00:42:10,449
Once it shorts out, the electric field has been obliterated.
497
00:42:10,450 --> 00:42:15,130
And so there's no longer a pull downward, this material then is released.
498
00:42:15,250 --> 00:42:17,050
It gets pulled up by the springs.
499
00:42:17,410 --> 00:42:22,870
Meanwhile, the electric field can rebuild in the gap by the same thermal processes that created them originally.
500
00:42:23,786 --> 00:42:31,570
Then the attraction would occur again and the hammer would be pulled down to the anvil.
501
00:42:31,840 --> 00:42:33,669
Touch, discharge, come back.
502
00:42:34,120 --> 00:42:42,010
Now we've done a number of simulations which were using realistic physical characteristics of silicon and P in diodes.
503
00:42:42,100 --> 00:42:46,192
We find that if you can match the timescale over which the electric field rebuilds,
504
00:42:46,392 --> 00:42:52,750
which we call the electrical time constant, we should be on the order of tens to hundreds of nanoseconds.
505
00:42:53,200 --> 00:42:56,679
If you match that time constant to the mechanical time constant of the spring.
506
00:42:56,680 --> 00:43:00,136
In other words, the normal resonant frequency of this cantilever,
507
00:43:00,336 --> 00:43:05,612
when you match these two, then you can set up what's called a resonant electromechanical oscillation,
508
00:43:05,613 --> 00:43:08,919
kind of like what happens when you push a kid on a swing.
509
00:43:08,920 --> 00:43:12,387
You hit them at the right frequency, You can build up the oscillation
510
00:43:12,587 --> 00:43:17,454
same way you can use the electric field energy here to build up an oscillation in this hammer-anvil
511
00:43:17,654 --> 00:43:19,420
and create a self-sustained oscillation.
512
00:43:20,860 --> 00:43:27,320
This can be demonstrated using today's technology doesn't require anything beyond which has already been developed.
513
00:43:27,520 --> 00:43:34,510
but again, it has to be built very small, the reasons being the time constant for rebuilding this electric field are very short.
514
00:43:34,510 --> 00:43:38,231
They're the time constants are in the order of tens to hundreds of nanoseconds,
515
00:43:38,431 --> 00:43:43,837
which means that the frequencies associated with mechanical oscillation have to be on the order of 1 to 10 megahertz,
516
00:43:44,037 --> 00:43:46,239
very high frequency, maybe even a hundred megahertz.
517
00:43:46,540 --> 00:43:49,179
At those frequencies, you have to build the devices very small.
518
00:43:49,180 --> 00:43:52,930
Otherwise they tear themselves apart by their mechanical accelerations.
519
00:43:54,010 --> 00:43:58,650
So they have to be built small to sustain the high accelerations and frequencies.
520
00:43:58,860 --> 00:44:02,909
And also to create these large energy densities associated with the electric field.
521
00:44:03,240 --> 00:44:07,769
So overall, this thing has to be built probably on the order of about one micron in size or smaller to make it work.
522
00:44:08,940 --> 00:44:12,340
Nonetheless, this is well within nanotechnology.
523
00:44:12,360 --> 00:44:23,460
I mean,modern standard off the shelf transistors now are being built down to size scales on the order of about a 10th of a micron or something like that.
524
00:44:24,000 --> 00:44:27,239
So using standard technology, you can build something this size.
525
00:44:27,780 --> 00:44:29,220
And how do you generate electricity?
526
00:44:30,240 --> 00:44:38,457
Well, again, if you had a magnet here on the top of the hammer and it were and we're moving up and down through some sort of electric coil,
527
00:44:38,657 --> 00:44:44,369
it would presumably generate electrical power like a regular electrical generator at high frequency.
528
00:44:44,970 --> 00:44:46,530
But this would have lots of other uses, too.
529
00:44:46,950 --> 00:44:51,454
But nonetheless, the energy that you get out of this or the power you can get out of this
530
00:44:51,654 --> 00:44:58,889
is actually fairly small on the order of about 10 to the minus 9 watts on that order to the minus 8 watts, which is very, very small.
531
00:44:58,890 --> 00:45:02,839
It's like an ant or a flea crawling up a wall, something very small.
532
00:45:02,850 --> 00:45:05,280
But on the other hand, this is very small itself.
533
00:45:06,180 --> 00:45:12,090
So although this doesn't put out much power by itself, if you were to couple these to a large number of them.
534
00:45:12,120 --> 00:45:18,474
In other words, if you were to have as many of these as would fit in the volume of a desk about a cubic meter or so,
535
00:45:18,674 --> 00:45:25,649
the power output for that desk instantaneously would be on the order of that of a nuclear power plant about 10 to the 9 watts.
536
00:45:26,940 --> 00:45:32,053
Now, of course, that could not go on very long, because if what we're saying is true
537
00:45:32,253 --> 00:45:42,085
that you're converting thermal energy heat into mechanical energy and if you're creating mechanical energy at a rate of 10 to the 9 watts
538
00:45:42,086 --> 00:45:45,749
that comes from heat, your objects going to cool down very fast, in fact.
539
00:45:45,870 --> 00:45:51,636
So a block the size of a desk would cool down to absolute zero in a few seconds at that power output rate,
540
00:45:51,836 --> 00:45:56,978
The way you would actually use it would be to make large panels of very thin micron thin panels,
541
00:45:57,178 --> 00:46:01,209
spread them out across a wall and then convert it to make electricity that way.
542
00:46:01,230 --> 00:46:05,940
So instead of having a block a meter high, you slice it into a million slices
543
00:46:06,150 --> 00:46:10,503
so now you have one square kilometer of this material, and then you can use it.
544
00:46:10,703 --> 00:46:13,920
Also it would absorb energy, it would absorb its ambient heat better.
545
00:46:13,920 --> 00:46:21,360
So if you had something like a chalkboard which was paneled over with this stuff, the chalkboard here is about a meter and a half by about 5 meters.
546
00:46:21,450 --> 00:46:23,369
It's about 7 and a half square meters.
547
00:46:25,560 --> 00:46:32,880
If it's absorbing 100 watts per square meter, you could get about 750 watts of power just from that blackboard sitting there.
548
00:46:33,120 --> 00:46:37,559
It would cool down slightly, but it could power everything else in this room continuously, forever.
549
00:46:38,040 --> 00:46:43,080
You'd be turning up the heat in this room into work and then using our electrical power.
550
00:46:43,080 --> 00:46:46,156
That electrical power would run all the all the computers in the room,
551
00:46:46,356 --> 00:46:49,523
and then the heat generated by the computer would go back into the panels,
552
00:46:49,723 --> 00:46:52,219
go back into electricity, and go back into the computers again.
553
00:46:52,230 --> 00:46:53,399
You'd be recycling energy.
554
00:46:53,400 --> 00:46:58,370
The whole idea of recycling energy is foreign to our way of thinking, because of the second law,
555
00:46:58,570 --> 00:47:04,709
we naturally assume the energy that we use coming out of the wall or used in an automobile is used once and never used again.
556
00:47:06,450 --> 00:47:13,093
But if you were to actually subvert the second law and again, it has not been broken experimentally yet, but if you could
557
00:47:13,094 --> 00:47:18,059
you could reuse energy again and again forever, it would be completely recyclable energy.
558
00:47:18,750 --> 00:47:22,578
-Have you tried filing patents on this?
559
00:47:22,778 --> 00:47:24,149
We published this
560
00:47:25,080 --> 00:47:27,270
well, we put it this way in terms of patenting it.
561
00:47:28,410 --> 00:47:34,589
We have a company which was instituted to do to protect the intellectual property rights.
562
00:47:34,590 --> 00:47:37,460
And we're thinking about what exactly would work out right now.
563
00:47:37,470 --> 00:47:41,520
But in terms of this, this was published in Foundations of Physics back in 2000.
564
00:47:41,520 --> 00:47:44,070
To many patent rights associated with this have evaporated.
565
00:47:44,730 --> 00:47:46,860
This one has not been published per say.
566
00:47:47,310 --> 00:47:54,870
It's iffy because this resident cantilever idea, it's already been tried for ones that are powered with batteries.
567
00:47:55,260 --> 00:47:58,915
We're planning on powering it with its own potential.
568
00:47:59,115 --> 00:48:00,570
but we have a few ideas.
569
00:48:01,080 --> 00:48:04,139
This one is how to turn this energy into chemical energy.
570
00:48:04,140 --> 00:48:06,250
In other words, electrostatic energy to chemical energy.
571
00:48:06,420 --> 00:48:07,889
We're working on a paper on it right now.
572
00:48:08,370 --> 00:48:09,479
It's unclear where it's going to go.
573
00:48:09,750 --> 00:48:13,199
So you can turn this off the record or just do what you want.
574
00:48:14,520 --> 00:48:15,520
Here's the basic.
575
00:48:17,460 --> 00:48:19,799
+Talk about it if you want, is totally good.
576
00:48:22,680 --> 00:48:24,540
Your N and P region, positive and negative.
577
00:48:24,540 --> 00:48:30,082
So you have positive charges here, negative charges here and an electric field going down through this material
578
00:48:30,282 --> 00:48:37,800
if you take some sort of neutral atom, bring it in to this... this could be any P material or two different metals like aluminum
579
00:48:38,510 --> 00:48:41,730
and your filling doesn't really matter what it is, bring in a neutral atom.
580
00:48:42,180 --> 00:48:44,709
The neutral atom can ionize in the surface.
581
00:48:44,710 --> 00:48:48,683
This is called surface ionization. I use it all the time in making plasmas
582
00:48:48,883 --> 00:48:55,656
when this dissolves it gets accelerated by this electric field and will be entered and it will be accelerated across this gap
583
00:48:55,856 --> 00:49:03,869
basically from rest up to the velocity associated with about a 1 volt drop in potential.
584
00:49:04,680 --> 00:49:11,099
to put that in perspective, if you take an atom and accelerated through one volt potential
585
00:49:11,100 --> 00:49:14,969
when it thermalices,it randomizer its motion comes to an equilibrium temperature.
586
00:49:15,240 --> 00:49:18,419
It'll be at a temperature of 12,000 degrees, twice the temperature of the sun.
587
00:49:19,680 --> 00:49:23,099
Okay, so you bring in this neutral atom.
588
00:49:23,430 --> 00:49:27,179
Ionized, it dissolves, comes down here and comes and when it arrives at the bottom,
589
00:49:27,379 --> 00:49:31,408
there's lots of energy indicated by the start which can stimulate other chemical reactions,
590
00:49:31,409 --> 00:49:33,643
basically enough energy to drive a chemical reaction.
591
00:49:33,644 --> 00:49:41,880
And then It can just give up the electron again or pick up an electron from the other side and recycle through the system or just leave.
592
00:49:42,060 --> 00:49:48,965
But the point is, by falling through this gap this ion can get enough energy to drive the temperature of your gas up
593
00:49:49,165 --> 00:49:53,489
by several thousand degrees in principle or to stimulate chemical reactions.
594
00:49:53,580 --> 00:49:58,229
So we've turned electrostatic energy into chemical energy by this method, but it only happens locally.
595
00:49:58,230 --> 00:49:59,940
After all, where did this energy come from originally?
596
00:50:00,090 --> 00:50:01,090
It came from heat.
597
00:50:01,350 --> 00:50:06,984
So if you let this thing relax again, it's never going to be hotter than what it started out for the whole lattice,
598
00:50:07,184 --> 00:50:14,569
but it'll be a local temperature rise of 4000 degrees or I mean, if you spread it out to three dimensions at 12,000 goes to 4000 divided by three,
599
00:50:14,769 --> 00:50:17,789
but it'll go up toward the temperature of the sun locally.
600
00:50:17,790 --> 00:50:18,959
It's really rather remarkable.
601
00:50:19,440 --> 00:50:23,940
And all we've used here is the intrinsic bias associated with either metals or semiconductors.
602
00:50:24,930 --> 00:50:25,890
Very simple process.
603
00:50:25,890 --> 00:50:26,988
+And when did you think of this?
604
00:50:27,188 --> 00:50:32,879
I thought of this this summer, actually, I was at a conference in Prague and there was a physical chemist there.
605
00:50:32,880 --> 00:50:35,280
Her name is "Tamar Seidemann" from Northwestern University.
606
00:50:35,281 --> 00:50:41,219
She and I chatted after my talk and we sat down at lunch and hatched this idea on a lunch in a cafe in Prague.
607
00:50:42,660 --> 00:50:47,460
+What i wanted to ask you back to the first one of the ¿? What was it like for you to think of this?
608
00:50:48,180 --> 00:50:51,030
Well, I thought of it out of desperation, frankly.
609
00:50:51,030 --> 00:50:59,504
I mean, I had been kicked around professionally, I guess, for about ten years on these various other Second Law challenges,
610
00:50:59,704 --> 00:51:03,844
the two plasma challenges which I developed in the early 1990s,
611
00:51:04,044 --> 00:51:11,039
the chemical ones, which I did in the mid 1990s, and the gravitational one which I did in the late 1990s.
612
00:51:11,520 --> 00:51:18,420
And so all of these were exotic thermodynamic thermodynamic regimes, ones which are not easily accessible or testable.
613
00:51:19,440 --> 00:51:23,252
When I was in Cincinnati in 1995, one of my friends in plasma physics, "Jeffrey Bowles"
614
00:51:23,452 --> 00:51:27,239
We were crossing the street and said, you know, plasmas are a lot like solid state physics.
615
00:51:27,540 --> 00:51:30,829
So if you found one in plasma, there should be one of solid state physics.
616
00:51:30,830 --> 00:51:31,830
There should be an analog.
617
00:51:32,250 --> 00:51:36,772
And I didn't know anything about solid state physics in 1995, but by 2000 I taught myself enough
618
00:51:36,972 --> 00:51:41,192
that I back engineered the solid state challenge for thinking about the plasma challenge,
619
00:51:41,392 --> 00:51:42,899
which I developed ten years earlier.
620
00:51:42,900 --> 00:51:48,952
So it's really based on a hunch given to me by a friend crossing the street in Cincinnati back in 1995,
621
00:51:49,152 --> 00:51:51,420
and he didn't know what he was talking.
622
00:51:51,430 --> 00:51:54,989
He just threw out the idea and I had to chew on it for a while and I came up with this.
623
00:51:56,010 --> 00:52:00,599
And then then "Jeff Wright" got involved after I'd come up with it and we kind of fleshed it out.
624
00:52:00,870 --> 00:52:06,690
He and "Andrew", those guys were very instrumental in making this thing work,
625
00:52:06,691 --> 00:52:09,354
so most of us were serendipitous,
626
00:52:09,554 --> 00:52:19,100
+ so we might get into a little bit about how this wasn't possible 100 years ago when these laws were formulated
627
00:52:19,210 --> 00:52:28,060
Well, if you look at science over the last 100 years, there's almost no area of science which has not been transformed in one way or another.
628
00:52:29,260 --> 00:52:34,179
You can look at classical mechanics where space and time were considered absolutes in the Newtonian sense.
629
00:52:34,480 --> 00:52:36,159
And this and these ideas were shattered.
630
00:52:36,220 --> 00:52:42,130
Starting about 1905, with with "Einstein's" special general theory of Relativity in 1905 and 1916.
631
00:52:42,700 --> 00:52:47,281
So the ideas of absolute time and space have been revised
632
00:52:47,481 --> 00:52:55,630
or ideas about the corpuscular solid nature of matter has dissolved under the development of quantum mechanics,
633
00:52:55,830 --> 00:52:58,639
where solid particles now become waves.
634
00:52:58,839 --> 00:53:03,914
Our ideas about determinism have been undermined by chaos theory.
635
00:53:03,915 --> 00:53:09,340
All of these, a lot of our presumptions about the world have been undermined by discoveries in the 20th century.
636
00:53:11,650 --> 00:53:18,270
But thermodynamics, which dates back 150 years, were virtually untouched in the sense that people were unwilling to look at these,
637
00:53:18,470 --> 00:53:26,057
look at the laws of thermodynamics seriously in light of developments in the 20th century, and see whether they still applied.
638
00:53:26,140 --> 00:53:29,380
There was always a mystique around the second law that no one really wanted to attack.
639
00:53:31,960 --> 00:53:33,730
Starting roughly around 1990.
640
00:53:33,730 --> 00:53:39,340
There was the mid 1990s were starting to be a push toward reexamining the second law in terms of quantum mechanics.
641
00:53:40,130 --> 00:53:47,379
And then there were a lot of several renegade groups who looked at absolute challenges to it, and we just started picking at it.
642
00:53:47,380 --> 00:53:48,489
I don't know why it started.
643
00:53:48,490 --> 00:53:51,797
It seems to have been kind of a confluence of a lot of people's work,
644
00:53:51,997 --> 00:53:56,999
and there were half a dozen groups around the world that all worked, sort of working on the same problem
645
00:53:57,000 --> 00:54:00,710
all about within about five years of each other without knowing about each other.
646
00:54:00,730 --> 00:54:01,810
It was just rather coincidence.
647
00:54:02,500 --> 00:54:06,219
You had "Lindsey Gordon" in New Zealand.
648
00:54:06,220 --> 00:54:09,400
He was probably the first guy in the modern Second Law movement.
649
00:54:09,400 --> 00:54:15,999
He started about 1984 to make some proposals about what biochemical membranes might be able to do in terms of subverting the second law.
650
00:54:16,840 --> 00:54:18,940
These articles were largely stillborn.
651
00:54:18,940 --> 00:54:21,760
They were more or less ignored by the scientific community.
652
00:54:22,150 --> 00:54:23,219
Early 1980s.
653
00:54:23,230 --> 00:54:27,909
"Jack ¿?" From Texas made some proposals about rectifying heat.
654
00:54:28,300 --> 00:54:35,769
These were largely ignored. The first stuff and the new stuff in the 1990s was from San Diego.
655
00:54:36,130 --> 00:54:41,757
We put we proposed above total over the last ten years about five different challenges in different areas.
656
00:54:41,758 --> 00:54:44,739
Plasma physics, chemical physics, gravitational physics and solid state.
657
00:54:46,930 --> 00:54:50,980
There was work by "Father ¿?" From Charles University in Prague.
658
00:54:52,060 --> 00:54:56,530
He proposed about eight or so theoretical challenges which are based on quantum mechanics.
659
00:54:57,670 --> 00:55:05,241
He was looking at membrane pumps and noticed that quantum mechanical rules allow subversion of the second law
660
00:55:05,441 --> 00:55:10,159
and basically violating what's called detailed balance in quantum mechanics.
661
00:55:11,620 --> 00:55:22,425
A group in the Netherlands and Armenia, "Newman Hazen" and "Oliver Gideon" showed that quantum mechanical entanglement,
662
00:55:22,426 --> 00:55:30,159
which is all the rage now in quantum theory, can give rise to second law challenges as well.
663
00:55:30,170 --> 00:55:32,260
They came up with two or three of those themselves.
664
00:55:33,850 --> 00:55:40,629
You also have work by "Peter Kes" in Superconductivity,
665
00:55:40,630 --> 00:55:48,829
where you propose a very simple mechanism whereby you can use the quantum mechanical superconducting transition
666
00:55:48,830 --> 00:55:51,369
to create a small engine which he calls the "magneto ¿? Engine"
667
00:55:51,760 --> 00:56:02,800
This is closely related to work by "Aleksey Nikolov" Who was looking at soft rectification with currents driven in superconducting loops, mesoscopic superconducting loops.
668
00:56:03,310 --> 00:56:13,280
So there's a whole slew of different challenges out there right now, and there appears to be no general rubric under which they fall.
669
00:56:13,300 --> 00:56:14,349
They're all individual.
670
00:56:15,010 --> 00:56:19,719
Some of them are related to each other, but there seem to be different groupings, but no overall vision of all of them.
671
00:56:19,750 --> 00:56:26,969
You don't really knows what connects them all, aside from the fact that they all seem to turn disorder into order spontaneously.
672
00:56:26,980 --> 00:56:35,710
In July of 2002, we had what's called the first international conference on quantum limits to the second law, and that was held here at the University of San Diego.
673
00:56:35,710 --> 00:56:39,827
We brought together about 120 researchers from 25 countries around the world,
674
00:56:40,027 --> 00:56:47,260
and it was the first conference, to my knowledge, in history, to discuss the possible violation of the second law or challenges to it.
675
00:56:47,710 --> 00:56:52,256
Again, none of these challenges have actually been experimentally verified yet,
676
00:56:52,257 --> 00:56:57,070
although there have been corroborative experiments on several of them indicating that the basic processes work.
677
00:56:57,520 --> 00:57:03,077
In other words, you can show, for instance, that superconducting transition occurs in a certain way,
678
00:57:03,078 --> 00:57:05,615
which would be favorable second law violation
679
00:57:05,616 --> 00:57:09,554
or my plasma ones, I've conducted high temperature plasma experiments which show a voltage
680
00:57:09,555 --> 00:57:11,349
the way you'd expect for a second law violation.
681
00:57:12,490 --> 00:57:15,609
But it's one thing to show the underlying processes work.
682
00:57:15,610 --> 00:57:18,689
It's another thing to actually get useful work out of the system.
683
00:57:18,690 --> 00:57:27,343
That's the trick is to, you know, cross all your teams, dot all your eyes and cover all your bases
684
00:57:27,344 --> 00:57:30,360
as to where all your heating work went and balance everything out.
685
00:57:30,360 --> 00:57:34,142
It's very difficult to do that and experiments and make it make an airtight case.
686
00:57:34,143 --> 00:57:39,000
But I think there's enough corroborative evidence right now to seriously question the second law
687
00:57:39,001 --> 00:57:43,199
+ Is possible to give an example of the kind of demonstration.
688
00:57:43,530 --> 00:57:44,280
Sure.
689
00:57:44,280 --> 00:57:52,612
And this one, I think in particular, the double, the resient cantilever, if you could build this thing on the size of a blood cell or so you started oscillating,
690
00:57:52,812 --> 00:57:55,290
if it just keeps oscillating forever, it doesn't stop.
691
00:57:55,680 --> 00:57:57,179
There's something fishy going on.
692
00:57:57,960 --> 00:57:59,639
I mean, assuming you're not driving it some other way.
693
00:57:59,640 --> 00:58:05,130
So you'd have to isolate it from all sound sources, all vibrational sources, all electrical sources, all electromagnetic sources.
694
00:58:05,640 --> 00:58:12,630
And then you have to follow tests where you slowly make other ones, with less doping, and see at what point it fails.
695
00:58:12,930 --> 00:58:16,149
You build up a case that the second law is viable there.
696
00:58:16,380 --> 00:58:23,909
the second law's so lock tight and believed by the scientific community that the standards of proof of second law violation are extremely high.
697
00:58:24,270 --> 00:58:26,619
And so you couldn't just simply make something that starts vibrating.
698
00:58:26,620 --> 00:58:27,719
and expect people to believe you.
699
00:58:28,020 --> 00:58:39,494
You'd have to do all sorts of different tests and gather enough evidence so that any objection anyone raises, you can counter with experimental evidence
700
00:58:39,694 --> 00:58:47,543
when at last you have counted every piece, every possible exception and every possible caveat to anywhere that occurs to anybody
701
00:58:47,544 --> 00:58:56,190
such that they have no further way of arguing against you then the intellectual honesty dictates that they must agree that the second law is viable.
702
00:58:56,190 --> 00:59:02,249
But until you exhaust all of these caveats, you're not going to convince the scientific community of the truth of this.
703
00:59:02,690 --> 00:59:07,043
+Once you get through all the exceptions to prove it out to the ¿?
704
00:59:07,686 --> 00:59:09,099
They might do that.
705
00:59:09,100 --> 00:59:14,017
But on the other hand, if you market this thing and people start buying it and they start creating home power and using this
706
00:59:14,217 --> 00:59:17,524
and they're not paying any power bills, and I think people will start paying attention
707
00:59:17,724 --> 00:59:19,409
because then the proof is in the pudding.
708
00:59:19,410 --> 00:59:21,449
The second law is an experimental observation.
709
00:59:21,960 --> 00:59:26,730
So if you can experiment, you have to experimentally prove this.
710
00:59:26,730 --> 00:59:31,530
You can't really do as we've done so far and simply write it out on paper and say it should work.
711
00:59:32,100 --> 00:59:36,449
That's nice and fine, but maybe nature has a trick up her sleeve, which is to keep you from making this thing work.
712
00:59:36,450 --> 00:59:38,969
And you don't know what it is until you try it.
713
00:59:39,390 --> 00:59:44,670
And ultimately, scientific truth is determined by experiment.
714
00:59:45,030 --> 00:59:48,090
Well, we put it this way God is an experimentalist,
715
00:59:48,290 --> 00:59:49,690
after all he created the world.
716
00:59:49,830 --> 00:59:53,699
If he had been a theorist, he would have written down the equation only and got the sign wrong.
717
00:59:58,300 --> 01:00:01,749
And so I truly believe that.
718
01:00:02,590 --> 01:00:05,589
But ultimately, truth is determined by experiment.
719
01:00:05,590 --> 01:00:07,599
Theory can certainly help you out to understand it.
720
01:00:07,600 --> 01:00:10,419
But it's not going to determine truth, experiment determs truth.
721
01:00:10,420 --> 01:00:13,179
And so I'm absolutely adamant about this.
722
01:00:13,180 --> 01:00:17,349
The second law is inviolable until it's viable, until it is violated.
723
01:00:18,580 --> 01:00:26,970
+What were some of the things that they observed back in ¿? days that caused them to formulate the second law?
724
01:00:26,971 --> 01:00:35,485
well, most obvious is that you throw a bunch of wood into your steam engine or coal with water in it,
725
01:00:35,486 --> 01:00:41,800
and you burn all the wood and make steam and you get a certain amount of mechanical energy out and you're all done.
726
01:00:41,800 --> 01:00:45,129
Everything's a lot hotter and you can't seem to use that burned up wood again.
727
01:00:46,240 --> 01:00:52,456
I guess the most obvious observation, you get some work out, but you've created a lot of heat and a lot of entropy ultimately,
728
01:00:52,656 --> 01:01:00,300
and you can't get it back once it goes off into the atmosphere and the heat dissipates, you can't gather it back again and use it to drive your engine.
729
01:01:00,310 --> 01:01:04,449
That's an observation about the world, and it's a very powerful one.
730
01:01:04,450 --> 01:01:11,139
It's been it stood all experimental tests for the last 250 years.
731
01:01:11,140 --> 01:01:13,449
And before that, even if you want to look back further.
732
01:01:13,450 --> 01:01:16,577
So the second law is a very, very powerful and useful law
733
01:01:16,578 --> 01:01:24,340
the question that we're raising is are there ways of subverting it in subtle ways which may be useful to humanity and to science ultimately, in other ways?
734
01:01:24,730 --> 01:01:27,670
+Are there any more obvious ways in which it gets converted?
735
01:01:27,670 --> 01:01:32,629
+And actually in observable conditions in nature?.
736
01:01:33,550 --> 01:01:34,859
To my knowledge, there are no
737
01:01:35,020 --> 01:01:39,579
if there were known subversions of the second law, It would not be a law in the same sense that it is now.
738
01:01:39,580 --> 01:01:48,280
the second law would not be absolute if we actually knew ways of subverting it or if it was agreed that it was subverted already in nature.
739
01:01:48,490 --> 01:01:51,432
+The way the sun works has not been subverted
740
01:01:51,433 --> 01:01:52,317
No. not at all
741
01:01:53,557 --> 01:01:59,570
the stars are tremendous entropy generators, tremendous entropy generators.
742
01:01:59,571 --> 01:02:05,050
In fact, it's only by these gradients of entropy that you have life on this planet.
743
01:02:05,200 --> 01:02:14,695
I mean, the fact that the sun is a blackbody radiation source that is at about 5700 degrees kelvin casting heat on this planet
744
01:02:14,895 --> 01:02:22,499
and that we degrade into and use in photosynthesis, solar energy and so on,
745
01:02:22,500 --> 01:02:27,280
and then discard and then run our machines and discard that waste heat back out into space.
746
01:02:28,600 --> 01:02:34,073
We're always creating entropy in the process, but it actually is a continuous down conversion of the quality of energy
747
01:02:34,074 --> 01:02:39,909
as it comes from the core of the sun to the surface to earth, back out into space as heat that keeps this place running.
748
01:02:39,910 --> 01:02:45,260
If you didn't have this gradient in entropy, where the entropy is increasing all the way down the chain,
749
01:02:45,261 --> 01:02:49,569
through all these reactions, we would be essentially in equilibrium now and we all be dead.
750
01:02:50,020 --> 01:02:51,570
+So it's cold and dead.
751
01:02:52,120 --> 01:02:54,070
Well, cold or hot and dead doesn't matter.
752
01:02:54,070 --> 01:02:56,513
If you go to the core of the sun, you can be hot and dead.
753
01:02:56,514 --> 01:03:03,954
But the point is it's only by the continuous non-equilibrium degradation of high energy sources into lower energy,
754
01:03:04,154 --> 01:03:11,590
lower quality energy sources and heat or higher entropy that the world progresses from one state into the other.
755
01:03:11,800 --> 01:03:15,189
the universe moves ahead because of its non-equilibrium nature.
756
01:03:15,460 --> 01:03:25,749
+So it does make some sense that in subverting the second law, some sort of very clever technological mechanism would need to be imported
757
01:03:26,110 --> 01:03:26,890
yeah, it would.
758
01:03:26,890 --> 01:03:28,869
And that's really what it requires.
759
01:03:28,871 --> 01:03:30,486
Nature is not going to come up with it itself.
760
01:03:30,490 --> 01:03:39,071
I don't think. I'm not aware of any process I wish it would. But you need to engineer the geometry and composition of your devices
761
01:03:39,072 --> 01:03:48,429
in such a way that you can create these special conditions whereby he creates its own downfall.
762
01:03:48,430 --> 01:03:50,949
Something like this electric field in the gap.
763
01:03:51,430 --> 01:03:54,395
Nature is not going to create a device like this spontaneously,
764
01:03:54,595 --> 01:03:59,289
and even if it did, it would have to create a perfectly micro machined dielectric plug to go in and out.
765
01:03:59,770 --> 01:04:01,179
That's just not going to happen by itself.
766
01:04:01,930 --> 01:04:06,256
The superconducting ones, which are proposed by "Kes" and by "Nicolav",
767
01:04:06,456 --> 01:04:14,829
these superconducting states, are not going to occur naturally and exist except in very, very exotic locations in the universe.
768
01:04:14,830 --> 01:04:17,559
And even then, it's not going to necessarily result in creation of work.
769
01:04:17,560 --> 01:04:26,139
So all of these, virtually all of the ones that I'm aware of are or have to be manmade, except for one possibility.
770
01:04:26,140 --> 01:04:28,814
And I'm not sure you want to cover this in your in your talk or not.
771
01:04:29,080 --> 01:04:34,742
There have always been speculations that if, in fact, the second law can be violated,
772
01:04:34,942 --> 01:04:38,739
why hasn't life resorted to second law violation mechanisms?
773
01:04:40,270 --> 01:04:42,849
Okay. That's that's a legitimate question.
774
01:04:42,850 --> 01:04:46,875
I mean, in fact, it's often used to say, well, the second law is absolute,
775
01:04:47,075 --> 01:04:52,510
because if it weren't absolute nature in its soaring cleverness and diversity would have already found a way of subverting it.
776
01:04:53,380 --> 01:04:55,239
I don't find that convincing for a number of reasons.
777
01:04:56,110 --> 01:05:02,230
The first being that is not proven that all biochemical processes actually conform to the second law.
778
01:05:02,440 --> 01:05:04,344
All the ones that we know of do
779
01:05:04,544 --> 01:05:13,179
But the human genome has 32,000 genes or so, I believe, and makes on the order of what, 100 million proteins of some some enormous number.
780
01:05:13,180 --> 01:05:16,090
Only a small number of these biochemical pathways have actually been explored.
781
01:05:16,600 --> 01:05:20,619
And so you can't claim with absolute certainty that that's not the case.
782
01:05:21,610 --> 01:05:26,050
if were to bet money, I'd say they probably all do follow the second law.
783
01:05:26,710 --> 01:05:31,418
On the other hand, I would also argue that the conditions that you find on the Earth's surface,
784
01:05:31,419 --> 01:05:35,491
for instance, ones in which you have lots of energy streaming from the sun to the surface,
785
01:05:35,691 --> 01:05:41,770
lots of chemical energy available for plants and animals is not the ideal condition to have what I would call thermal synthetic life.
786
01:05:42,190 --> 01:05:44,349
And this word was coined just recently.
787
01:05:44,680 --> 01:05:53,110
but the idea is this, there are two basic kinds of life that inhabit the earth, photosynthetic life and chemosynthetic life.
788
01:05:53,500 --> 01:05:59,319
Photosynthetic life takes photons, light and convert it into chemical energy.
789
01:05:59,320 --> 01:06:07,809
As photosynthesis is photosynthetic, chemosynthetic life takes chemicals and uses raw chemicals for the energy of life.
790
01:06:07,810 --> 01:06:11,770
That would be something like you eating a beef steak, something like that.
791
01:06:11,770 --> 01:06:13,139
You're not photosynthesizing anything.
792
01:06:13,150 --> 01:06:14,150
Even though you're sure it's green.
793
01:06:15,070 --> 01:06:21,923
You're basically taking chemical energy, breathing oxygen, and combining that oxygen with the proteins and the carbohydrates
794
01:06:21,924 --> 01:06:24,729
and getting mechanical work out of the process.
795
01:06:24,730 --> 01:06:29,409
That's right. So you're chemosynthetic life because you have two basic branches of life.
796
01:06:29,680 --> 01:06:37,329
Well, what if you were to have some sort of life form that could use heat directly and convert it into work?
797
01:06:37,330 --> 01:06:39,219
That would be thermo synthetic life.
798
01:06:39,220 --> 01:06:43,585
And so there have been a few proposals for this.
799
01:06:43,785 --> 01:06:49,679
I think there is a possibility you could find it in certain places.
800
01:06:50,220 --> 01:06:55,083
You'd have to look for a place where it's not competing with chemosynthetic or photosynthetic life,
801
01:06:55,084 --> 01:07:01,529
which means if you're going to find it, it would have to be in an energy poor environment away from the sun and chemical energy sources.
802
01:07:01,530 --> 01:07:06,386
The best place to find it would be probably deep in the earth, probably down a few kilometers where it's dark.
803
01:07:06,390 --> 01:07:12,269
And so we're in an energy desert where there's somewhere like granite where you wouldn't have very many chemicals available to use.
804
01:07:13,620 --> 01:07:18,932
We have I've looked at the possibilities for this, and it turns out that the cell membrane
805
01:07:19,132 --> 01:07:24,480
a cell membrane is, you know, surrounds cells and these can be charged positive or negatively.
806
01:07:26,590 --> 01:07:27,749
It's basically like this.
807
01:07:28,890 --> 01:07:32,219
You have a natural capacitor which can be built into cells in principle.
808
01:07:32,220 --> 01:07:41,700
And I have proposed, at least in this book, the possible mechanisms by which you could possibly take
809
01:07:41,701 --> 01:07:47,849
the electrostatic potential, the electrostatic energy, electric field inside a cell membrane and convert it into chemical energy.
810
01:07:47,850 --> 01:07:52,825
And that's I think it's quite a long shot, but it's certainly worth proposing
811
01:07:52,826 --> 01:08:00,479
and it turns out that a lot of the chemical machinery necessary for thermal synthetic life, at least as I envision it.
812
01:08:01,080 --> 01:08:05,986
When I proposed the idea originally, I started looking into the biochemical literature,
813
01:08:05,987 --> 01:08:13,949
and it turns out most most of the basic chemical structures which I proposed already exist in cells, which is rather remarkable.
814
01:08:14,850 --> 01:08:18,898
So it's almost like all the electrical characteristics are all in place.
815
01:08:18,899 --> 01:08:23,499
But the question is, when would these be employed? I don't know.
816
01:08:23,500 --> 01:08:27,899
i'm not sure you could find thermo synthetic life easily, but I don't think that it's out of the question.
817
01:08:27,960 --> 01:08:31,319
if we proposed ways of violating the second law, which are viable.
818
01:08:31,590 --> 01:08:35,976
I think nature, which is a lot more clever than I am, would certainly come up with a to eventually
819
01:08:36,176 --> 01:08:43,520
+I may have this all wrong. don't systems far from thermodynamic equilibrium violate the second law?
820
01:08:43,750 --> 01:08:44,099
No.
821
01:08:44,100 --> 01:08:54,568
+I'm thinking of something that again, I may have this completely wrong, but the "Ilya Romanovich Prigogine" Wasn't involved in this?
822
01:08:54,569 --> 01:08:56,858
He was looking at systems far from equilibrium.
823
01:08:56,859 --> 01:09:07,380
But his claim was that this movement of systems, far from equilibrium into organized structures like life itself can occur only if they're driven.
824
01:09:07,470 --> 01:09:12,270
In other words, only if you keep feeding energy in, can you keep these organized structures going.
825
01:09:12,810 --> 01:09:21,299
And so the non-equilibrium aspect of them is there, certainly, but they are large entropy generators also.
826
01:09:22,560 --> 01:09:29,399
So, no, he would not support necessarily the violation of second law, in the way we did.
827
01:09:30,270 --> 01:09:33,943
On the other hand, he wanted to come to the conference but was too sick to come.
828
01:09:35,069 --> 01:09:37,019
He sent one of his students instead.
829
01:09:37,020 --> 01:09:38,249
Yeah, but he wanted to come to the conference.
830
01:09:38,250 --> 01:09:43,229
He was very interested in this because of his interest in thermodynamics and in organized states.
831
01:09:44,100 --> 01:09:45,359
+he was a Nobel?
832
01:09:45,840 --> 01:09:47,339
Yes. 1977, I believe.
833
01:09:47,520 --> 01:09:55,999
But my impression of my readings of his work, he would not himself subscribe to violation of the second law.
834
01:09:56,000 --> 01:10:02,789
+Now, what motivates you to, you've been involved in this for a long time, he seems like in doubt about this.
835
01:10:02,790 --> 01:10:04,880
What motivated me?.
836
01:10:05,380 --> 01:10:12,180
I grew up with the second law being the son of a physical chemist, and it's always been in the background growing up.
837
01:10:12,181 --> 01:10:17,771
It's always intrigued me. It is a deep subject which touches almost every aspect of our lives.
838
01:10:18,120 --> 01:10:19,590
I did it more or less as a challenge.
839
01:10:19,590 --> 01:10:23,609
I have to say it was in the early 1990s.
840
01:10:25,740 --> 01:10:33,629
"Zurek" and "Bennett" and other people had come to the conclusion that the "Maxwell Demon" would be foiled by his own erasure of information,
841
01:10:33,630 --> 01:10:35,579
and that made big news at the time.
842
01:10:35,580 --> 01:10:40,919
But the national team had finally been slain, and I thought, well, that seemed rather obvious what they were doing.
843
01:10:41,490 --> 01:10:44,130
I wonder if the second law really can be violated in a different way.
844
01:10:44,130 --> 01:10:53,340
And so I started thinking about it, and one thing led to another, and I started coming up with ideas on chemical challenges and plasma challenges.
845
01:10:53,340 --> 01:10:55,169
And it just kind of led from there.
846
01:10:55,530 --> 01:10:58,350
I did not wish to be in this field as long as I have
847
01:10:58,380 --> 01:11:00,270
I expected to be in it for just maybe a few years.
848
01:11:00,270 --> 01:11:06,899
But in seeing the extreme resistance and hostility of the scientific community, I dug in my heels and said, I'm not going to take this.
849
01:11:06,900 --> 01:11:09,930
And so I just continued to work in the area to try to justify the ideas.
850
01:11:10,710 --> 01:11:15,630
And it just so happened that at the same time, several other groups were working in the area as well
851
01:11:15,631 --> 01:11:20,383
and they made headway and we reached a critical mass at which point we could actually have a conference
852
01:11:20,583 --> 01:11:22,229
and then it starts to legitimize the field.
853
01:11:22,230 --> 01:11:28,730
This conference proceedings is actually published by the American Institute of Physics,
854
01:11:28,930 --> 01:11:34,109
which is the main conference proceedings publisher in the United States.
855
01:11:34,110 --> 01:11:42,060
Maybe the world, just having a conference which is published by AIP adds legitimacy to the question, which It never had before.
856
01:11:42,330 --> 01:11:45,980
So I think that was important. I'm proud of that.
857
01:11:45,980 --> 01:11:50,493
But I think at this point, there are so many questions surrounding the second law
858
01:11:50,693 --> 01:11:57,680
that no honest scientist can legitimately dismiss second law challenges out of hand any more.
859
01:11:57,680 --> 01:11:59,689
It's intellectually untenable to do so.
860
01:12:00,500 --> 01:12:10,159
And it's now a political struggle to gain enough visibility and enough converts to get it actually examined carefully.
861
01:12:10,160 --> 01:12:15,502
Certainly a handful of scientists, maybe a couple dozen of us who are actually in the challenging business
862
01:12:15,503 --> 01:12:18,603
could be squashed by the scientific community or more easily ignored.
863
01:12:19,730 --> 01:12:23,639
But I think ultimately people are going to have to come to grips with the second law,
864
01:12:23,640 --> 01:12:27,577
particularly if somebody comes up with a real challenge, a real violator experimentally,
865
01:12:27,578 --> 01:12:29,289
they're going to say, well, why does it work?
866
01:12:29,300 --> 01:12:30,449
They can't simply ignore that.
867
01:12:30,560 --> 01:12:33,740
I mean, it's one thing to have your theory is another thing to ignore experiment.
868
01:12:34,850 --> 01:12:38,119
So we're just plugging away.
869
01:12:38,210 --> 01:12:39,260
That's all I can say right now.
870
01:12:39,260 --> 01:12:43,729
We're just biding our time and waiting for things to develop, working as hard as we can.
871
01:12:43,730 --> 01:12:45,920
But ultimately, it's a political struggle.
872
01:12:46,110 --> 01:12:47,419
-I have another question.
873
01:12:49,530 --> 01:13:03,240
-I think we're all agreed that the vacuum possesses huge amount of energy.
874
01:13:03,240 --> 01:13:09,090
that's a theoretical prediction. There's nothing measured.
875
01:13:10,980 --> 01:13:12,659
It is predicted to have high energy content.
876
01:13:12,690 --> 01:13:13,140
-Fair enough.
877
01:13:13,540 --> 01:13:17,569
-Now, hypothetically or theoretically, assuming that prediction is correct.
878
01:13:18,900 --> 01:13:27,239
-How would the second law, rigid application of a second rule impinge on any theoretical ability to tap into that energy?
879
01:13:27,530 --> 01:13:35,489
I'm not really aware that the second law would put a monkey wrench in the utilization of the vacuum energy assuming that it exists.
880
01:13:35,560 --> 01:13:42,599
because the vacuum energy itself would represent a new, in a sense, untapped form of energy.
881
01:13:42,600 --> 01:13:45,449
We haven't been able to actually draw out and use.
882
01:13:45,900 --> 01:13:48,689
So the second law really doesn't directly speak to that.
883
01:13:49,640 --> 01:13:53,460
That would be more in terms of conservation of energy or the definition of energy.
884
01:13:53,940 --> 01:13:58,680
So if vacuum energy exists, they were just it would go into the category of a new kind of energy.
885
01:13:58,720 --> 01:14:04,379
Like originally there was only one kind of energy thought that existed, mechanical energy.
886
01:14:04,380 --> 01:14:14,399
And there was the discovery that heat constituted molecular random energy around in motion or heat or something, that heat was a form of energy.
887
01:14:15,480 --> 01:14:18,330
Then you throw heat into the category of energy also.
888
01:14:19,530 --> 01:14:22,199
Then you're going to throw in chemical energy.
889
01:14:22,200 --> 01:14:25,290
Then when you find out that you can convert mass into energy, you have mass energy.
890
01:14:25,530 --> 01:14:27,930
Then you find the vacuum as energy, you call it vacuum energy.
891
01:14:27,930 --> 01:14:33,090
You keep adding new kinds of energy into your definition of energy, all of which apparently can convert one into another.
892
01:14:34,050 --> 01:14:37,649
But I don't know anybody who can give a perfectly suitable definition of even energy.
893
01:14:39,120 --> 01:14:43,413
I mean, it's energy is something that you can in principle use to make things go.
894
01:14:43,414 --> 01:14:45,014
Maybe that's the best way to put it.
895
01:14:45,360 --> 01:14:48,660
But their inner convertible, that seems to be a property of them.
896
01:14:50,580 --> 01:14:54,180
But I've never heard anyone give me a suitable definition of energy.
897
01:14:54,180 --> 01:14:57,930
So it's funny because you talk about all these absolutes in science.
898
01:14:58,890 --> 01:15:00,270
You know, second law is absolute.
899
01:15:00,600 --> 01:15:06,209
Entropy always increases, energy is conserved, but no one can even define what they're talking about necessarily.
900
01:15:08,220 --> 01:15:16,399
it's a lot naughtier than people think when a lot of people think scientists think in terms of absolutes.
901
01:15:16,410 --> 01:15:17,699
Well, scientists are artists.
902
01:15:17,700 --> 01:15:20,100
They have a view of the world which is often very personal.
903
01:15:20,730 --> 01:15:26,580
And my view of the world it's my personal view of the world, which is more or less orthodox.
904
01:15:26,760 --> 01:15:34,109
I mean, I agree with most things with most people in the scientific community, but I'm not orthodox when it comes to the second law.
905
01:15:34,770 --> 01:15:39,094
Only in as much as I think that there are regimes where it can be violated, for the most part,
906
01:15:39,294 --> 01:15:43,649
I would agree with everybody that the world is free of second law violations.
907
01:15:44,400 --> 01:15:50,660
The only place where I run into trouble with everybody, everyone else is that I say there might be places where you can subvert it.
908
01:15:50,670 --> 01:15:54,035
It's a very small thing, but it turns out to be very important to a lot of people
909
01:15:54,235 --> 01:15:57,450
because they would prefer to have absolute certainty on this issue. You know?
910
01:15:57,450 --> 01:16:00,307
I'm not willing to admit that you yet
911
01:16:00,507 --> 01:16:06,277
+can you to try to give me a sixth grade level definition of the second law?
912
01:16:06,477 --> 01:16:11,580
Second law is the tendency of the universe to increase its disorder.
913
01:16:15,380 --> 01:16:18,020
Now that's different than the conservation of energy system.
914
01:16:18,110 --> 01:16:18,450
That's right.
915
01:16:18,450 --> 01:16:20,119
conservation of energy says.
916
01:16:20,360 --> 01:16:24,596
What you start with in terms of energy you end with, is all conservation of energy says.
917
01:16:24,796 --> 01:16:30,050
You can turn your energy from one form into another, from work into heat, from heat into work.
918
01:16:30,890 --> 01:16:34,284
To a certain degree, you can have gravitational energy, you can have chemical energy,
919
01:16:34,484 --> 01:16:37,279
you can have mass energy, have vacuum energy, you can have spring energy.
920
01:16:38,030 --> 01:16:39,320
You can have all different kinds of energy.
921
01:16:39,440 --> 01:16:40,699
And they might be able to convert.
922
01:16:40,700 --> 01:16:46,369
But whatever you start with, even after they all transmute into each other, what you start with, you end with.
923
01:16:46,490 --> 01:16:51,619
That's all the first of all says, first law just says you can't destroy it and you can't create it.
924
01:16:51,770 --> 01:16:52,770
You just have what you have.
925
01:16:54,290 --> 01:17:04,586
The second law tells you that the energy that you start with tends to degrade
926
01:17:04,587 --> 01:17:11,420
and you can't recreate that energy into a non useful form to useful form very easily.
927
01:17:11,540 --> 01:17:17,029
There are so many different ways of stating the second law that no matter how I state the second law, I'm going to miss something.
928
01:17:18,440 --> 01:17:26,930
I can give you 21 different definitions if you want, to me is also like a pointillism, a painting.
929
01:17:26,960 --> 01:17:31,683
I mean, you can stand back and look at all the definitions and you have a good view of what the second law is,
930
01:17:31,883 --> 01:17:36,620
but you try zeroing in on one little definition of the second law, and you've got a point and you lost the picture.
931
01:17:38,240 --> 01:17:42,869
So the way I think about the second law is in terms of all the definitions,
932
01:17:42,870 --> 01:17:48,068
all the statements of the second law, and see, this pretty much covers all circumstances,
933
01:17:48,069 --> 01:17:55,369
but any one definition is usually going to leave you a little bit deficient in terms of your overall understanding of nature.
934
01:17:56,210 --> 01:18:03,140
I think there are two probably the two key definitions of the second law or the key formulation of the second law.
935
01:18:03,500 --> 01:18:08,689
One deals with entropy and one deals with heat work, which is probably the two basic ways in terms of entropy.
936
01:18:08,690 --> 01:18:14,330
You would say for any spontaneous process, the entropy of the universe does not decrease.
937
01:18:16,710 --> 01:18:26,700
In terms of heat work, you would say there is no physical process by which you can turn heat solely back into work.
938
01:18:31,540 --> 01:18:37,319
So once in terms of heat work to turn terms as written in terms of entropy,
939
01:18:37,320 --> 01:18:41,059
but they're equivalent, probably not exactly
940
01:18:41,060 --> 01:18:44,560
+in electricity, how does that form ¿?
941
01:18:46,830 --> 01:18:48,539
in terms of the second law?
942
01:18:49,320 --> 01:18:54,990
Well, if you put electricity through a resistor, for instance, the resistor heats up.
943
01:18:55,350 --> 01:19:03,270
That electrical work, electrical energy work would be I squared R or a B squared R or whatever,
944
01:19:03,271 --> 01:19:07,521
that in the resistor doctrine that electrical energy turns into heat in the resistor
945
01:19:07,721 --> 01:19:17,001
and basically turn it all into, you change this organized electronic flow into some sort of jiggled motion of molecules in the resistor,
946
01:19:17,002 --> 01:19:22,086
and you've turned coherent electronic motion into random thermal vibrations.
947
01:19:22,140 --> 01:19:25,349
So we've turned heat into work or excuse me, turned work into heat.
948
01:19:25,350 --> 01:19:26,350
Sorry, my apologies
949
01:19:28,780 --> 01:19:34,689
so any process you can name, any national process you can name aside from the second law challenges.
950
01:19:34,690 --> 01:19:38,560
I can probably identify where and how the interview turns up, but it always does.
951
01:19:39,580 --> 01:19:47,739
in throwing up all this paper into the air and letting it fall down illustrates that, this is a standard kind of process, no matter what you do.
952
01:19:48,130 --> 01:19:53,950
if you throw water up in the air to splash all over the place, if you see water sitting on the table, it's just not going to sit there.
953
01:19:53,950 --> 01:19:56,470
It's going to evaporate, fill the room, which is a more disorganized state.
954
01:19:58,360 --> 01:20:01,330
If you breathe and your breath comes out, just doesn't hang there.
955
01:20:01,330 --> 01:20:02,689
It spreads out and fills the room.
956
01:20:02,710 --> 01:20:07,180
Everything you do tends to increase the possibilities available to it, to increase the disorder.
957
01:20:08,350 --> 01:20:12,369
On the flip side of that, everyone talks about disorder being a bad thing.
958
01:20:12,370 --> 01:20:13,689
It's a wonderful thing.
959
01:20:13,690 --> 01:20:24,790
I mean, disorder in a sense, is a greater complexity and richness to the atomic structure or the atomic description of the universe.
960
01:20:25,360 --> 01:20:28,149
The universe becomes richer as it becomes more disorganized.
961
01:20:29,350 --> 01:20:33,660
It's just a question of how useful is that new richness to us.
962
01:20:33,670 --> 01:20:35,350
We call it disorder and call it heat.
963
01:20:35,350 --> 01:20:36,530
We call it friction.
964
01:20:36,560 --> 01:20:38,920
We call it wasted energy because we can't use it anymore.
965
01:20:39,460 --> 01:20:44,290
But it's still there on a microscopic level, increasing the diversity of what's going on down into the atomic level.
966
01:20:44,710 --> 01:20:49,350
I would not want to see second law violators use on a universal basis because you freeze the universe out.
967
01:20:49,360 --> 01:20:51,670
You basically take all the heat, turn it into work.
968
01:20:51,670 --> 01:20:55,090
When you're all done, everything's cold and you're just as dead as if you had died by heat death.
969
01:20:56,530 --> 01:20:59,350
+Is this in relation to the universe continuosly expanding?
970
01:21:00,040 --> 01:21:07,586
Well, the fact the universe is continuously expanding that in a sense adds more possible microstates for the universe
971
01:21:07,587 --> 01:21:14,169
and in a sense gives the universe more possibilities continuously in which to which to play, so to speak.
972
01:21:15,010 --> 01:21:18,069
So classical heat death was described in the 19th century.
973
01:21:18,070 --> 01:21:22,600
Victorian heat death, as they call it, will never really occur, at least not in the way they say.
974
01:21:24,100 --> 01:21:29,398
But the real source of entropy in the universe turns out to be gravitational sources, things falling, planets forming,
975
01:21:29,598 --> 01:21:33,260
stars forming, black holes forming in particular, and then their ultimate evaporation.
976
01:21:33,280 --> 01:21:36,520
That's really where the entropy of the universe increases.
977
01:21:39,610 --> 01:21:48,790
-Does this mean that they could make a move just to revisit something that I mentioned earlier this morning, the work that "Evans" did in Australia?
978
01:21:48,880 --> 01:21:49,680
Yes.
979
01:21:49,680 --> 01:21:52,869
-And how does that relate to what...?
980
01:21:52,900 --> 01:22:02,095
Well, the work by "Evans" fills out the picture about how intricate changes occur in microscopic size scales
981
01:22:02,295 --> 01:22:16,689
and exhibits the property or the behavior that short term entropy reductions can occur at the microscopic size scale that this has really been known for a century or so.
982
01:22:16,710 --> 01:22:20,799
In fact, these kinds of things were pointed out by "Maxwell" 30 years ago.
983
01:22:21,310 --> 01:22:29,050
So in terms of actually violating the second law in a real practical sense, the work by "Evans" doesn't really speak to that point.
984
01:22:30,014 --> 01:22:31,220
The work was very good.
985
01:22:31,270 --> 01:22:36,549
There's no question it was it was just good, solid, experimental work with the confirmed theoretical predictions.
986
01:22:36,550 --> 01:22:37,630
Very well
987
01:22:37,810 --> 01:22:48,173
but in terms of making any kind of practical device or even a theoretical or theoretically interesting device that would violate the second law,
988
01:22:48,174 --> 01:22:59,409
it didn't really accomplish that, I don't think, because it demonstrated small systems can for short periods of time decrease entropy locally.
989
01:22:59,410 --> 01:23:07,300
But in terms of being able to harness that for any kind of real practical use, No, because it doesn't achieve that.
990
01:23:07,600 --> 01:23:08,739
Think of it this way.
991
01:23:08,740 --> 01:23:17,979
If I have a box like this and ten molecules go in this box, they'll bounce around randomly and pretty much be on average spread out all through the box.
992
01:23:18,070 --> 01:23:19,314
Would you agree with that?
993
01:23:21,010 --> 01:23:28,159
Every once in a while, all these balls might just all bounce independently such that they all inhabit one little corner of the box.
994
01:23:28,840 --> 01:23:36,189
So it would look as if the entropy of the gas in the box spontaneously decreased against the second law.
995
01:23:37,150 --> 01:23:38,170
That's what it would look like.
996
01:23:38,470 --> 01:23:44,770
And you can you could claim that, in fact, the entropy of these particles all in one corner of the box is less than spread out over the box.
997
01:23:44,980 --> 01:23:45,820
Certainly.
998
01:23:45,820 --> 01:23:48,219
But you could not have predicted when that was going to occur.
999
01:23:48,220 --> 01:23:50,199
There was no necessarily good way of harnessing that.
1000
01:23:50,200 --> 01:23:52,929
It was just a statistical fluctuation that caused it.
1001
01:23:52,930 --> 01:24:01,390
So the statistical fluctuations have been known for a century or more to cause these kinds of spontaneous entropy decreases.
1002
01:24:01,750 --> 01:24:05,579
Nonetheless, they don't really constitute a useful energy source
1003
01:24:05,779 --> 01:24:07,688
-this was for one period of time
1004
01:24:07,888 --> 01:24:11,740
by microseconds probably or tens of seconds at most, something like that.
1005
01:24:12,550 --> 01:24:15,769
I think there is a need to a degree for scientific orthodoxy.
1006
01:24:15,770 --> 01:24:21,040
It's necessary for science to hold certain standards in terms of truth.
1007
01:24:21,040 --> 01:24:28,883
If you did and if you say anything went, science would be in the same shape as the Internet, which is basically just
1008
01:24:28,884 --> 01:24:29,990
-the Wild West.
1009
01:24:29,991 --> 01:24:31,060
And so you don't want that.
1010
01:24:31,060 --> 01:24:37,884
But at the same time, you would expect some sort of a good degree of inquisitiveness, curiosity, intellectual honesty in the scientific community,
1011
01:24:38,084 --> 01:24:41,109
which seems to have been lacking in the discussion of the second law.
1012
01:24:41,140 --> 01:24:46,014
There seem to be a lot of kneejerk reaction, a lot of unscientific attitudes toward it,
1013
01:24:46,015 --> 01:24:51,168
which are dismissive rather than inquisitive or intellectually honest,for that matter.
1014
01:24:51,970 --> 01:24:59,919
The shortest review I ever got on a journal article which I submitted, I could paper my walls with rejections from the journals.
1015
01:24:59,920 --> 01:25:05,300
The shortest one was "This article violates the second law. Do not publish it."
1016
01:25:05,710 --> 01:25:06,610
And that was it.
1017
01:25:06,610 --> 01:25:14,319
That was the entire review by the reviewer that was accepted by the editors, conclusive proof that it had to be wrong and it was rejected.
1018
01:25:15,400 --> 01:25:16,510
That is not science.
1019
01:25:20,486 --> 01:25:24,319
That's intellectual fascism.
1020
01:25:26,090 --> 01:25:31,260
So on one hand, I can appreciate orthodoxy, but at the same time, scientists should be aware of their own ignorance,
1021
01:25:31,261 --> 01:25:33,889
which is that no one knows why the second law always works.
1022
01:25:33,890 --> 01:25:36,559
Nobody knows why, you can't prove the second law.
1023
01:25:36,560 --> 01:25:39,229
It's an experimentally observed fact for now.
1024
01:25:40,400 --> 01:25:45,996
But to refuse to admit the possibility that it can be violated is completely unscientific
1025
01:25:46,196 --> 01:25:55,489
because it basically throws out the idea of the falsifiability of the law, which is absolutely necessary for the health of any intellectual enterprise.
1026
01:25:55,730 --> 01:25:58,759
You have to always admit the possibility that you're wrong if you're unwilling to do that.
1027
01:26:00,020 --> 01:26:03,949
You really have no right, no real possibility of ever really being right.
1028
01:26:04,490 --> 01:26:06,560
But there's always something to be discovered.
1029
01:26:06,710 --> 01:26:08,989
I don't think there's any end science or to learning.
1030
01:26:08,990 --> 01:26:13,387
And anybody who claims that there's an end to science or that they have a general theory of everything,
1031
01:26:13,388 --> 01:26:15,960
I think should be stripped of their Ph.D. and thrown out of science.
1032
01:26:16,630 --> 01:26:23,869
+And what was that, well, you had earlier a guy who said, we already know everything we need to know, all we need to do is fill in the decimal points
1033
01:26:23,870 --> 01:26:25,789
+and that was what, 1900?
1034
01:26:25,880 --> 01:26:29,629
just before quantum mechanics started
1035
01:26:30,529 --> 01:26:35,659
i'd have to look it up. And it was something like physics is now officially dead.
1036
01:26:37,730 --> 01:26:41,689
All that is required now is to fill in decimal points, something like that.
1037
01:26:42,710 --> 01:26:45,698
But I think that was "Jeanne's". I'm not certain of that. I think it was "Jeanne's"
1038
01:26:45,898 --> 01:26:52,369
+what's important about that ¿?The illustration of the attitude
1039
01:26:52,640 --> 01:26:56,120
the arrogance, but you see it now quite a bit in the string theorists.
1040
01:26:56,120 --> 01:27:02,440
And I shouldn't, just the string theorists, and certain scientists who claim that they're about to have a theory of everything
1041
01:27:02,441 --> 01:27:05,749
or a grand unified theory that will that will explain everything.
1042
01:27:05,750 --> 01:27:10,770
I find that offensive intellectually, because you can always ask the question, am I missing something?
1043
01:27:10,771 --> 01:27:16,179
So to make a claim that you have a theory now that answers all possible questions is to cut off for the questioning.
1044
01:27:16,190 --> 01:27:18,919
Once you've done that, you've committed intellectual suicide.
1045
01:27:18,920 --> 01:27:21,486
And I think that is the greatest thing that you create.
1046
01:27:21,487 --> 01:27:27,949
I think that is just about the greatest, if not the greatest sin that you can commit as a scientist is to stop your questioning.
1047
01:27:29,000 --> 01:27:30,680
I think "Max Planck" said it best.
1048
01:27:30,680 --> 01:27:34,760
He said, You never really, how should I put it?
1049
01:27:35,600 --> 01:27:37,699
Old ideas never really die.
1050
01:27:37,700 --> 01:27:39,999
It's the proponents of those ideas who die.
1051
01:27:40,000 --> 01:27:43,171
It's only then that scientific revolutions take hold.
1052
01:27:43,790 --> 01:27:47,359
So I started this work in my early 30s I'm 45 now.
1053
01:27:47,360 --> 01:27:51,186
I expect to live another 50 years. I'm simply going to outlive the bastards.
120858
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