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Gemstones, precious metals,
and power...
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...the building blocks
of civilization.
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But how are they created?
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Our Earth is a master chef.
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She knows how to cook.
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It's not easy
to make an element.
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You need temperatures
that are extreme.
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In this episode, how do metals
shape our world?
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I love steel.
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It's actually the backbone
of our society.
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And will these gifts be used
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to build the tools of tomorrow?
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So I think of the Terminator.
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He can change shape
and then self-heal.
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And actually, our material
does all those things.
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We're going to launch
this incredible telescope,
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and we're going to send it
a million miles
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into space from the earth
to actually unlock
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the secrets of the universe.
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And it will all rely
on two ounces of gold.
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"The Power of Metals."
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Right now on
NOVA.
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Major funding for
NOVA
is provided by the following...
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By the light
of an ancient campfire,
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a discovery was made that
changed the course of history.
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We don't know exactly
how it happened,
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but I sometimes wonder whether
it wasn't a complete accident.
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Whether by chance
or through sheer determination,
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once humankind learned how
to harness the power of fire,
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we left the Stone Age behind,
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forging our way
into the modern world
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with copper, bronze,
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iron, and steel-- the metals.
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A world without metals
would not have tall buildings,
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it would not have fast vehicles,
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you wouldn't be able
to have electricity.
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Really, our entire modern world
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is built on the backbone
of metals.
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Our journey begins with a metal
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that's transformed life on Earth
through its beauty.
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A metal that fortune hunters
were willing to die for,
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and not just in the movies.
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There's nothing more beautiful
than gold, nothing in the world.
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You just feel it
when you see it.
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Ancient people valued gold
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before the concept of currency
or money even existed.
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It's something that people
intrinsically knew had worth.
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Gold is absolutely magical.
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Gold is the most fantastic
jewelry metal to work with.
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It's so soft, it's so flexible,
it's like butter.
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Working with gold ruins you
for any other metal.
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You're never the same again.
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Jeanette, a master jeweler,
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is making a pair
of gold earrings.
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I specialize in ancient
jewelry-making techniques.
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The kind of expertise
and skill that were used
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for making jewelry
really made it an art form.
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I make my own wire and sheet...
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...and practice techniques
like granulation.
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The technique I'm going to use
for the hanging fringe
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actually originates from Troy
from about 2450 BC.
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Gold is unique
among the elements.
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Gold is extremely resistant
to oxidation, to rusting.
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If you make an object
out of gold,
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it's the one thing that you have
that doesn't degrade.
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So to ancient people,
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that must have been very,
very appealing.
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The color of gold draws you in.
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Ancient people saw it
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and knew that it was something
incredibly special.
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Gold is not only beautiful,
it's rare.
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In fact,
if you take all the gold
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that's been mined to date,
it's estimated it would fill
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about a third
of the Washington Monument.
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But to understand
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what makes this rare
and noble metal last forever,
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we need to take a closer look--
a much, much closer look.
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Using one of the most powerful
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electron microscopes
in the world,
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David Muller studies
the elements.
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Probably the most fun in the lab
is when we put something in
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and the picture comes up
and you look and you go,
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Wow, that's not
what I expected.
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That's interesting.
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And that's usually the start
of a new scientific discovery.
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Today, Muller is observing
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the curious behavior of gold,
atom by atom.
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All elements are made of atoms.
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Inside is a nucleus filled
with positively charged protons
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along with neutrons that have
no charge at all.
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Swirling around the nucleus
in a cloud
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are negatively charged
electrons.
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It's the relationship between
gold's nucleus and its electrons
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that holds the key
to its resilience.
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We're now at 7,000 times
magnification,
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seven times higher than
the highest magnification
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of an optical microscope.
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And if we zoom up some more,
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we start to see
there's this nice pattern.
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These are little islands
of gold.
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00:06:03,466 --> 00:06:06,200
And if we zoom up a little bit
further on them,
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we'll start to see little bright
spots all by themselves.
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Those are individual atoms.
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Every one of these clusters
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contains thousands
of bright dots,
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thousands of gold atoms.
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Little gold atoms
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form small clusters,
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and they keep rearranging
and changing.
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They're not static,
they're not stable.
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They're dynamic--
they're moving all the time.
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Gold atoms love to be together.
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But when it comes to bonding
with other elements,
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they're downright antisocial.
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When atoms bond,
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they do it through
their outermost electrons
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by sharing or swapping them.
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But gold's 79 protons
fight the urge
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because they have
an immense positive charge.
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That positive charge
pulls in the electrons.
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The real consequence is that
the outermost electrons in gold
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are much less available
for doing chemistry
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than we might otherwise expect.
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That's why gold doesn't bond
with elements like oxygen
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that cause metals
to tarnish and rust.
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The reason that
we're able to appreciate
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the gold masterpieces
from 2400 BC
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is because gold lasts forever.
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It's just as beautiful today
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as it was
thousands of years ago.
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You can't say that
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about anything else
that you could work in.
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How did such
a unique metal form?
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It's not easy
to make an element.
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00:07:44,833 --> 00:07:47,400
You need temperatures
that are extreme,
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and we're talking
millions of degrees.
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The heavier the element,
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the hotter the temperatures
required to make it.
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And you find those temperatures
in the cores of stars
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that are ten times the mass
of the sun or greater.
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It's within the intense heat
and pressure
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of these massive cores
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that the elements
progressively take shape,
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bonding together
in a process called fusion.
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You can sort of imagine
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building up all the elements
that exist in the universe
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by taking a pile of neutrons
and protons and electrons
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and putting them together
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to build up bigger and bigger
and bigger atoms.
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When the number of protons
and electrons hit 26,
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forming iron, the process stops.
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Once iron's made in the core,
that's it.
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There's no more available energy
for fusion.
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Those massive stars will explode
and go what's called supernova.
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One of the key
open questions, though, was
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what about the heavier elements?
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What about gold and platinum
and uranium?
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Where do those come from?
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At the end of supernova
explosions,
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new kinds of stars are formed
called neutron stars.
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They often come in pairs--
binary stars.
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They're extremely dense
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and compact and heavy.
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It weighs about one-and-a-half
times the mass of our sun,
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but it's the size of a city like
New York or London or Boston.
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And they incorporate
a lot of neutrons,
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which is why they're called
neutron stars.
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Some scientists theorize that
elements heavier than iron
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were created in the collision
of two neutron stars.
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What happens when they collide?
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Fusion on a massive scale.
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The elements were spread
throughout the cosmos,
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so they were in the mix
when our solar system formed
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4.5 billion years ago.
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And later, more were delivered
to Earth
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by comets and asteroids.
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Most of the elements
on the periodic table
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came to us from space.
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We classify them in groups
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defined by their
characteristics.
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The largest group is the metals,
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and one of the most beautiful
by far is gold.
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Now this ancient treasure
is going back to space
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onboard the most advanced
telescope ever built.
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It's the next big
space telescope.
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We like to call it Hubble 2.0.
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Hubble 2.0 is the James Webb
Space Telescope.
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In 2018, we're going to launch
this incredible telescope,
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the largest space telescope
mankind has ever built,
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and we're going to send it
a million miles into space
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to stare at the earliest part
of the universe,
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and it will all rely
on two ounces of gold.
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The ultra-thin layers of gold
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that coat the telescope's
mirrors
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give it the power to detect
galaxies light years away.
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Hubble has sort of found
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the edge of the visible
universe,
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but we know there's
a whole universe beyond that
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at wavelengths called
infrared wavelengths.
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00:11:12,100 --> 00:11:15,733
And that's where gold
comes into the picture.
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Infrared light
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is invisible to our eyes,
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but we can detect it as heat.
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00:11:22,466 --> 00:11:24,700
And that's why this
thermal infrared camera
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will pick it up.
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00:11:25,933 --> 00:11:29,133
So this is my hand
as viewed by the camera,
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00:11:29,233 --> 00:11:31,666
and it's about 97 degrees
Fahrenheit.
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00:11:31,766 --> 00:11:33,666
Now let's look at my hand
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reflected in this ordinary
silver-coated mirror.
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00:11:36,700 --> 00:11:38,966
It says that my hand is
84 degrees Fahrenheit,
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which is a lot less than 97,
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and that's because
the silver-coated mirror
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00:11:43,500 --> 00:11:46,366
is not a perfect reflector
of infrared light.
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00:11:46,466 --> 00:11:49,933
But if we try this
gold-coated mirror...
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00:11:51,000 --> 00:11:52,633
Now, when I pass
my hand's reflection
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00:11:52,733 --> 00:11:54,833
over the gold,
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00:11:54,933 --> 00:11:58,633
it says that my hand is
97 degrees Fahrenheit.
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00:11:58,733 --> 00:12:01,100
And so what this shows
is that gold
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00:12:01,200 --> 00:12:04,466
is an almost perfect reflector
of infrared light,
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00:12:04,566 --> 00:12:07,033
and that's why we coat
all of the mirrors
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00:12:07,133 --> 00:12:09,266
of the James Webb telescope
in gold--
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00:12:09,366 --> 00:12:12,100
so that it has
an almost perfect view
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00:12:12,200 --> 00:12:14,466
of the infrared
invisible universe.
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00:12:17,800 --> 00:12:19,833
Gold is that ancient treasure
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00:12:19,933 --> 00:12:22,900
that we've lusted over
over mankind's history,
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00:12:23,000 --> 00:12:25,666
and here we are
in the 21st century using this
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00:12:25,766 --> 00:12:28,500
to actually unlock
the secrets of the universe
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00:12:28,600 --> 00:12:30,733
and perhaps the origins
of where we came from.
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00:12:30,833 --> 00:12:35,133
What a wonderful historical
transformation.
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00:12:35,233 --> 00:12:38,900
Historically, this glittering
treasure of the earth
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00:12:39,000 --> 00:12:41,100
could be found in riverbeds
and streams.
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00:12:43,033 --> 00:12:45,533
But in order to leave
the Stone Age behind,
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00:12:45,633 --> 00:12:47,800
we needed another metal,
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00:12:47,900 --> 00:12:51,300
one strong enough
to shape into tools.
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00:12:51,400 --> 00:12:55,166
And we found it
in the flames of a fire.
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00:12:57,133 --> 00:13:00,733
Copper, atomic number 29--
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00:13:00,833 --> 00:13:06,866
29 electrons, 29 protons,
and 35 neutrons--
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00:13:06,966 --> 00:13:11,466
is embedded in a mineral
called malachite.
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00:13:11,566 --> 00:13:14,666
Malachite has this incredible
color, doesn't it?
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00:13:14,766 --> 00:13:17,766
It's like aWizard of Oz
Emerald City green.
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00:13:17,866 --> 00:13:19,166
Malachite has been
really important
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00:13:19,266 --> 00:13:21,266
throughout the history
of our civilization.
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00:13:21,366 --> 00:13:24,966
This is probably the first
mineral that humans used
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00:13:25,066 --> 00:13:27,900
to actually extract
copper metal.
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00:13:28,000 --> 00:13:29,466
Just imagine the following.
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00:13:29,566 --> 00:13:33,966
Someone comes home
with a beautiful green rock--
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00:13:34,066 --> 00:13:36,533
malachite.
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00:13:36,633 --> 00:13:38,833
They decide to grind it
into a powder
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00:13:38,933 --> 00:13:41,966
and throw it into a campfire.
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00:13:42,066 --> 00:13:43,600
A magical process occurs.
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00:13:43,700 --> 00:13:46,400
Nature puts on a light show
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00:13:46,500 --> 00:13:50,700
as the edges of the flames
turn emerald green.
253
00:13:50,800 --> 00:13:52,900
The flame suddenly becomes
greenish.
254
00:13:53,000 --> 00:13:55,466
You get these incredible colors.
255
00:13:55,566 --> 00:13:57,833
You have no idea
where they come from,
256
00:13:57,933 --> 00:14:00,000
but it certainly provides
entertainment.
257
00:14:00,100 --> 00:14:02,033
And at the same time,
258
00:14:02,133 --> 00:14:05,733
that beautiful green rock
slowly turns black.
259
00:14:05,833 --> 00:14:09,366
The beautiful green malachite
has burnt away.
260
00:14:09,466 --> 00:14:11,966
What's left behind is copper
261
00:14:12,066 --> 00:14:16,333
combined with oxygen
from the air-- copper oxide.
262
00:14:16,433 --> 00:14:19,766
If you left it in the fire
overnight to burn,
263
00:14:19,866 --> 00:14:23,200
then the transformation
would have gone even further.
264
00:14:23,300 --> 00:14:26,500
But in order to free copper
from oxygen
265
00:14:26,600 --> 00:14:30,133
requires another ingredient,
carbon,
266
00:14:30,233 --> 00:14:33,433
which is conveniently provided
by charcoal--
267
00:14:33,533 --> 00:14:35,933
the residue of burning wood.
268
00:14:36,033 --> 00:14:38,766
I want to recreate that for you.
269
00:14:38,866 --> 00:14:41,666
Sella drops a disk
of copper oxide
270
00:14:41,766 --> 00:14:43,300
into a crucible of charcoal
271
00:14:43,400 --> 00:14:46,866
and heats it up
in a modern day fireplace:
272
00:14:46,966 --> 00:14:48,866
the microwave.
273
00:14:48,966 --> 00:14:52,300
What heat really means is
the molecules
274
00:14:52,400 --> 00:14:55,166
and atoms begin to move
much, much faster.
275
00:14:55,266 --> 00:14:58,000
Now it's possible
for the carbon
276
00:14:58,100 --> 00:15:00,166
to actually strip away
the oxygen,
277
00:15:00,266 --> 00:15:06,333
disappearing off invisibly
into the air as carbon dioxide.
278
00:15:06,433 --> 00:15:10,366
But the next morning, the person
who's cleaning up the fireplace,
279
00:15:10,466 --> 00:15:12,266
almost certainly a woman,
280
00:15:12,366 --> 00:15:16,033
would've found tiny
little shiny nodules
281
00:15:16,133 --> 00:15:17,866
lying amongst the ash.
282
00:15:17,966 --> 00:15:19,666
That would've been metal.
283
00:15:19,766 --> 00:15:22,666
This is a magical transformation
284
00:15:22,766 --> 00:15:25,300
that would suddenly have
given you a material
285
00:15:25,400 --> 00:15:27,833
that you could shape,
that you could reuse,
286
00:15:27,933 --> 00:15:29,933
that you could make tools with.
287
00:15:30,033 --> 00:15:32,366
This was power indeed.
288
00:15:32,466 --> 00:15:36,333
This was a birth
of a whole new technology.
289
00:15:36,433 --> 00:15:38,933
This was copper.
290
00:15:39,033 --> 00:15:43,166
Once our ancestors discovered
how to free metal from stone--
291
00:15:43,266 --> 00:15:45,633
the art of smelting--
292
00:15:45,733 --> 00:15:51,400
they had a material they could
shape into bowls and tools.
293
00:15:51,500 --> 00:15:55,233
But they also discovered it has
another surprising quality.
294
00:15:55,333 --> 00:15:58,033
An ancient Egyptian
medical text
295
00:15:58,133 --> 00:16:00,733
dating back to 1600 BC
296
00:16:00,833 --> 00:16:06,033
reveals copper was used as
a disinfectant to clean wounds.
297
00:16:06,133 --> 00:16:11,100
It was also used to make
surgical tools.
298
00:16:11,200 --> 00:16:13,366
As late as the 19th century,
299
00:16:13,466 --> 00:16:15,566
during a cholera epidemic
in Paris,
300
00:16:15,666 --> 00:16:19,800
copper workers seemed to be
immune to the disease.
301
00:16:19,900 --> 00:16:21,566
But by the 1940s,
302
00:16:21,666 --> 00:16:23,633
with the development
of antibiotics,
303
00:16:23,733 --> 00:16:28,166
people lost interest in copper,
its medicinal powers forgotten.
304
00:16:29,800 --> 00:16:31,766
Until now.
305
00:16:31,866 --> 00:16:34,500
At the University
of Southampton,
306
00:16:34,600 --> 00:16:36,866
Bill Keevil has set out to prove
307
00:16:36,966 --> 00:16:40,100
copper can help solve
a dangerous problem:
308
00:16:40,200 --> 00:16:42,600
hospital-borne infections.
309
00:16:42,700 --> 00:16:47,000
If a jumbo jet full of people
crashed each day
310
00:16:47,100 --> 00:16:48,700
and everyone died,
would you fly?
311
00:16:48,800 --> 00:16:49,866
Probably not.
312
00:16:49,966 --> 00:16:53,233
That's how many people die
in America each day
313
00:16:53,333 --> 00:16:55,100
from hospital-acquired
infection.
314
00:16:55,200 --> 00:16:59,500
Hospitals are a breeding ground
for dangerous superbugs.
315
00:16:59,600 --> 00:17:03,700
Just about any surface you touch
is a hot zone.
316
00:17:03,800 --> 00:17:06,266
We know superbugs are perfectly
happy to survive
317
00:17:06,366 --> 00:17:09,099
for many weeks
on a dry touch surface
318
00:17:09,200 --> 00:17:11,033
such as stainless steel
or plastics.
319
00:17:11,133 --> 00:17:12,800
So we need something that works
320
00:17:12,900 --> 00:17:16,666
24 hours a day,
seven days a week.
321
00:17:16,766 --> 00:17:19,266
Could copper be an answer?
322
00:17:19,366 --> 00:17:21,333
Keevil puts it to the test.
323
00:17:21,433 --> 00:17:24,400
He takes a piece of copper
324
00:17:24,500 --> 00:17:28,533
and a metal commonly used
in hospitals, stainless steel,
325
00:17:28,633 --> 00:17:31,633
and coats them
with the superbug MRSA,
326
00:17:31,733 --> 00:17:35,633
along with a green
fluorescent dye.
327
00:17:35,733 --> 00:17:39,133
Next, they place it
in a microscope.
328
00:17:39,233 --> 00:17:40,400
Please start your clocks,
329
00:17:40,500 --> 00:17:42,266
and we will follow
this experiment
330
00:17:42,366 --> 00:17:43,700
over the next five minutes.
331
00:17:43,800 --> 00:17:46,333
At first, the bacteria
332
00:17:46,433 --> 00:17:48,233
on the copper
and stainless steel
333
00:17:48,333 --> 00:17:50,300
glows bright green.
334
00:17:50,400 --> 00:17:51,900
But within minutes,
335
00:17:52,000 --> 00:17:58,766
the copper in the screen
on the right turns black.
336
00:17:58,866 --> 00:18:00,900
This is what they looked like
and this is after five minutes.
337
00:18:01,000 --> 00:18:03,500
So you can see they're all dead.
338
00:18:03,600 --> 00:18:06,600
How does copper do it?
339
00:18:06,700 --> 00:18:10,033
Scientists suspect
it has something to do
340
00:18:10,133 --> 00:18:15,133
with the membrane of a superbug,
which has an electrical charge.
341
00:18:15,233 --> 00:18:20,233
When it meets up with copper,
a kind of short circuit occurs.
342
00:18:20,333 --> 00:18:22,633
The copper penetrates
the membrane,
343
00:18:22,733 --> 00:18:25,800
leaving it with gaping,
oozing holes.
344
00:18:25,900 --> 00:18:31,766
The copper invades the superbug,
destroying its DNA.
345
00:18:31,866 --> 00:18:33,966
If there's no DNA,
there's no growth,
346
00:18:34,066 --> 00:18:36,700
and, in fact,
there's no chance of mutation,
347
00:18:36,800 --> 00:18:39,733
and, therefore,
you can't get resistance.
348
00:18:39,833 --> 00:18:42,333
Copper's ability to kill germs
349
00:18:42,433 --> 00:18:46,100
could one day save
millions of lives.
350
00:18:46,200 --> 00:18:50,600
But it's already revolutionized
the way we live,
351
00:18:50,700 --> 00:18:54,133
because copper has another
extraordinary ability:
352
00:18:54,233 --> 00:18:59,066
it conducts the electricity
that powers the planet.
353
00:18:59,166 --> 00:19:02,266
Metals are extremely
unusual materials.
354
00:19:02,366 --> 00:19:05,133
They can conduct electricity
extremely well.
355
00:19:05,233 --> 00:19:08,300
And when we think
about conducting electricity,
356
00:19:08,400 --> 00:19:10,000
what that means is that
357
00:19:10,100 --> 00:19:12,333
there are electrons
within the material
358
00:19:12,433 --> 00:19:15,400
which are able to move.
359
00:19:15,500 --> 00:19:17,866
Sometimes this is described as
a sea of electrons.
360
00:19:17,966 --> 00:19:21,233
You can kind of picture these
individual atom cores
361
00:19:21,333 --> 00:19:24,733
and then this sea of electrons
all around them.
362
00:19:24,833 --> 00:19:29,166
Metal atoms are arranged
in orderly rows and columns.
363
00:19:29,266 --> 00:19:32,166
In between those columns
are electrons
364
00:19:32,266 --> 00:19:34,600
that are able to move around.
365
00:19:34,700 --> 00:19:36,266
When we apply a voltage
with a battery,
366
00:19:36,366 --> 00:19:39,500
we can start to draw electrons
367
00:19:39,600 --> 00:19:42,900
so that they all move
collectively in one direction.
368
00:19:43,000 --> 00:19:44,833
With a voltage applied,
369
00:19:44,933 --> 00:19:48,400
electrons hop
from one atom to the next.
370
00:19:48,500 --> 00:19:49,566
That's what gives us
371
00:19:49,666 --> 00:19:52,966
the electric currents
that are so useful.
372
00:19:53,066 --> 00:19:56,400
While all metals
can conduct electricity,
373
00:19:56,500 --> 00:19:58,666
copper is one of the best.
374
00:19:58,766 --> 00:20:00,900
And it's abundant.
375
00:20:01,000 --> 00:20:06,366
The worldwide supply is
about six trillion pounds.
376
00:20:06,466 --> 00:20:08,433
But the qualities
that make copper
377
00:20:08,533 --> 00:20:10,666
the metal of choice
to wire the planet
378
00:20:10,766 --> 00:20:13,133
also limit its usefulness.
379
00:20:13,233 --> 00:20:17,166
That sea of electrons
not only conducts electricity;
380
00:20:17,266 --> 00:20:20,900
it creates flexible bonds
between the atoms.
381
00:20:21,000 --> 00:20:22,400
The atom cores
382
00:20:22,500 --> 00:20:24,866
can move through this
sea of electrons
383
00:20:24,966 --> 00:20:26,800
in a relatively easy way,
384
00:20:26,900 --> 00:20:28,500
and that's what makes metals
malleable.
385
00:20:28,600 --> 00:20:32,566
But a metal like copper,
which is malleable enough
386
00:20:32,666 --> 00:20:35,733
to be stretched into thin,
flexible cable,
387
00:20:35,833 --> 00:20:39,100
does not a dagger make.
388
00:20:39,200 --> 00:20:41,433
Copper is actually too soft.
389
00:20:41,533 --> 00:20:45,233
A blade made of copper
loses its edge within moments.
390
00:20:45,333 --> 00:20:47,633
And yet, by combining it
391
00:20:47,733 --> 00:20:51,566
with other rocks
in the fireplace made of tin,
392
00:20:51,666 --> 00:20:53,400
you could make a material
393
00:20:53,500 --> 00:20:56,700
which was stronger, harder,
and stiffer.
394
00:20:56,800 --> 00:20:59,200
That was bronze.
395
00:20:59,300 --> 00:21:01,800
Around 2500 BC,
396
00:21:01,900 --> 00:21:06,033
humankind took the art
of smelting one step further
397
00:21:06,133 --> 00:21:10,100
by mixing metals
to create an alloy.
398
00:21:10,200 --> 00:21:12,133
When you look at copper,
it's pretty boring--
399
00:21:12,233 --> 00:21:13,600
every single atom
looks the same.
400
00:21:13,700 --> 00:21:15,133
But when you look at bronze,
401
00:21:15,233 --> 00:21:16,533
there are two different types
of atoms.
402
00:21:16,633 --> 00:21:18,033
There's copper and there's tin.
403
00:21:18,133 --> 00:21:20,600
Adding tin to copper
404
00:21:20,700 --> 00:21:23,033
changes the properties
of the metal.
405
00:21:23,133 --> 00:21:25,100
The larger tin atoms
406
00:21:25,200 --> 00:21:28,466
restrict the movement
of the copper atoms.
407
00:21:28,566 --> 00:21:31,066
It makes it more difficult
for the atoms
408
00:21:31,166 --> 00:21:34,433
to move past one another
to change shape.
409
00:21:34,533 --> 00:21:36,300
Saying that it's more difficult
to move them around
410
00:21:36,400 --> 00:21:38,200
is equivalent to saying that
the metal is stronger.
411
00:21:38,300 --> 00:21:43,033
Bronze would've provided useful
implements for agriculture,
412
00:21:43,133 --> 00:21:45,766
but more importantly,
it would've provided you
413
00:21:45,866 --> 00:21:48,733
with weapons
to establish your dominance.
414
00:21:48,833 --> 00:21:51,266
And dominance, of course,
means control,
415
00:21:51,366 --> 00:21:53,633
and control means power.
416
00:21:55,566 --> 00:21:58,533
The movies paint a vivid picture
417
00:21:58,633 --> 00:22:03,066
of how bronze transformed
the nature of warfare.
418
00:22:03,166 --> 00:22:04,833
It's the bronze age,
so without bronze,
419
00:22:04,933 --> 00:22:06,166
you don't stand a chance
in battle.
420
00:22:06,266 --> 00:22:08,466
Bronze is like no other material
421
00:22:08,566 --> 00:22:10,366
people would have handled
before.
422
00:22:10,466 --> 00:22:14,033
With it, you can make
harder weapons,
423
00:22:14,133 --> 00:22:16,166
you can make sharper blades,
424
00:22:16,266 --> 00:22:17,766
and you can make them
consistently.
425
00:22:17,866 --> 00:22:19,400
You can cast them in mold
426
00:22:19,500 --> 00:22:21,800
and make them always
of equal quality.
427
00:22:21,900 --> 00:22:24,266
With bronze, you can,
for the first time, really,
428
00:22:24,366 --> 00:22:26,766
equip hundreds,
thousands of warriors
429
00:22:26,866 --> 00:22:28,933
with the same types of weapons,
430
00:22:29,033 --> 00:22:32,366
all of which will perform
and be equally lethal.
431
00:22:32,466 --> 00:22:35,066
So it probably meant
a revolution in warfare.
432
00:22:37,133 --> 00:22:41,133
But not all swords
are created equal.
433
00:22:41,233 --> 00:22:45,366
Back in 1965,
a group of archeologists
434
00:22:45,466 --> 00:22:48,333
discovered more than 50
ancient tombs
435
00:22:48,433 --> 00:22:51,066
in the Hubei province of China.
436
00:22:51,166 --> 00:22:52,633
During the excavation,
437
00:22:52,733 --> 00:22:55,333
they unearthed something
extraordinary.
438
00:22:55,433 --> 00:22:59,933
Jigao Hu was one of the first
people to lay eyes on it.
439
00:23:00,033 --> 00:23:03,733
Hu, an expert in the
preservation of ancient relics,
440
00:23:03,833 --> 00:23:09,933
vividly remembers seeing
a most unusual sword.
441
00:23:10,033 --> 00:23:14,133
The sword had
a golden sheen to it
442
00:23:14,233 --> 00:23:16,133
and had a decent weight to it.
443
00:23:16,233 --> 00:23:19,933
It had the shine
of fresh copper.
444
00:23:20,033 --> 00:23:22,966
There was no rust at all.
445
00:23:23,066 --> 00:23:27,066
Although it had been buried
for more than 2,400 years,
446
00:23:27,166 --> 00:23:30,133
the sword was perfectly
preserved.
447
00:23:30,233 --> 00:23:33,100
Hu found eight characters
448
00:23:33,200 --> 00:23:36,866
written in ancient Chinese
script on the base of the blade.
449
00:23:36,966 --> 00:23:40,200
They identified
the sword's owner:
450
00:23:40,300 --> 00:23:42,733
Goujian, the king of Yue,
451
00:23:42,833 --> 00:23:47,266
a famous ruler
in the 5th century BC.
452
00:23:47,366 --> 00:23:51,000
Everyone came to see the sword,
453
00:23:51,100 --> 00:23:55,366
ecstatic because there were
characters on it.
454
00:23:55,466 --> 00:23:58,133
One young man was
particularly excited,
455
00:23:58,233 --> 00:24:01,066
and he tried to reach for it
and he bumped into me.
456
00:24:01,166 --> 00:24:04,266
I leaped forward a little
and must've touched the sword,
457
00:24:04,366 --> 00:24:06,933
and the sword made a cut
458
00:24:07,033 --> 00:24:11,500
about two to three centimeters
on my hand.
459
00:24:11,600 --> 00:24:15,033
There were droplets of blood
coming from my wound.
460
00:24:15,133 --> 00:24:18,966
It wasn't a deep cut,
but a cut anyhow,
461
00:24:19,066 --> 00:24:21,533
like a shaving razor.
462
00:24:21,633 --> 00:24:24,866
The sword was that sharp.
463
00:24:24,966 --> 00:24:29,066
Later, they tested the sword.
464
00:24:29,166 --> 00:24:32,566
It could cut through
20 sheets of paper.
465
00:24:32,666 --> 00:24:37,700
It was so beautifully crafted,
I was astounded.
466
00:24:40,966 --> 00:24:43,700
The Goujian sword
is well preserved
467
00:24:43,800 --> 00:24:46,200
because of its burial condition.
468
00:24:46,300 --> 00:24:48,533
It is dry,
and no water leaked inside.
469
00:24:48,633 --> 00:24:50,633
Thus, it did not rust.
470
00:24:50,733 --> 00:24:54,233
But its longevity
may also be due
471
00:24:54,333 --> 00:24:56,800
to the extraordinary
craftsmanship
472
00:24:56,900 --> 00:25:00,633
with which it was made.
473
00:25:00,733 --> 00:25:03,100
The smelting technology
from ancient times
474
00:25:03,200 --> 00:25:04,700
has been lost.
475
00:25:04,800 --> 00:25:09,133
But recently, there are people
who start to imitate the styles.
476
00:25:09,233 --> 00:25:13,833
However, they can't manage
to replicate its sharpness.
477
00:25:13,933 --> 00:25:20,500
The sophistication cannot
match up to ancient times.
478
00:25:20,600 --> 00:25:24,433
But bronze has another
resounding quality.
479
00:25:27,333 --> 00:25:29,433
It's the perfect metal
to forge a bell.
480
00:25:31,766 --> 00:25:36,066
In South Korea,
master craftsman Song Chang-Il
481
00:25:36,166 --> 00:25:40,866
is making a ten-ton bell
for a Buddhist temple.
482
00:25:40,966 --> 00:25:42,900
After decades of experience,
483
00:25:43,000 --> 00:25:46,333
combined with an artist's
instincts,
484
00:25:46,433 --> 00:25:49,433
he knows exactly what it takes
485
00:25:49,533 --> 00:25:53,666
to make a bell
with the perfect ring.
486
00:25:53,766 --> 00:25:58,066
First, ten tons
of copper and tin
487
00:25:58,166 --> 00:26:02,033
are heated
to 1,150 degrees Celsius.
488
00:26:03,266 --> 00:26:04,833
When the time is right,
489
00:26:04,933 --> 00:26:09,900
Chang-Il pours his concoction
into a massive clay mold.
490
00:26:10,000 --> 00:26:12,600
The metal is so hot,
491
00:26:12,700 --> 00:26:17,966
it takes two-and-a-half days
for the bronze to cool.
492
00:26:18,066 --> 00:26:23,366
Finally, the mold
is carefully removed
493
00:26:23,466 --> 00:26:29,400
and the bell is tested
for the first time.
494
00:26:33,466 --> 00:26:34,933
That sound that we hear
495
00:26:35,033 --> 00:26:39,600
is really telling us
about the stiffness
496
00:26:39,700 --> 00:26:42,066
and the resilience
of the material.
497
00:26:42,166 --> 00:26:46,066
So when we hear
the ringing sound of a bell,
498
00:26:46,166 --> 00:26:49,433
the entire material
kind of swings.
499
00:26:49,533 --> 00:26:50,766
It becomes elastic
500
00:26:50,866 --> 00:26:53,533
and can then come back
and go forward
501
00:26:53,633 --> 00:26:55,433
and back and forward and back.
502
00:27:00,333 --> 00:27:01,966
Over thousands of years,
503
00:27:02,066 --> 00:27:05,800
through trial and error,
craftsmen like Chang-Il
504
00:27:05,900 --> 00:27:10,133
discovered that the perfect ring
could only be achieved
505
00:27:10,233 --> 00:27:12,633
with the perfect recipe:
506
00:27:12,733 --> 00:27:17,600
a balance between tin
and copper.
507
00:27:17,700 --> 00:27:22,666
But around 1200 BC,
as the use of bronze spread,
508
00:27:22,766 --> 00:27:25,733
and with supplies of tin scarce,
509
00:27:25,833 --> 00:27:29,633
once again,
the flames of a fire
510
00:27:29,733 --> 00:27:32,233
brought us a powerful metal.
511
00:27:32,333 --> 00:27:34,966
Iron.
512
00:27:35,066 --> 00:27:38,633
Atomic number 26--
513
00:27:38,733 --> 00:27:44,666
26 electrons, 26 protons,
and 30 neutrons.
514
00:27:44,766 --> 00:27:47,700
Freeing iron from stone
515
00:27:47,800 --> 00:27:50,166
meant taking the technology
of smelting
516
00:27:50,266 --> 00:27:52,466
one giant step further.
517
00:27:54,733 --> 00:27:59,233
Charcoal burns at
about 1,000 degrees Celsius,
518
00:27:59,333 --> 00:28:05,466
but to smelt iron, the flames
need to be a lot hotter.
519
00:28:05,566 --> 00:28:11,466
a technology that
could literally fan the flames--
520
00:28:11,566 --> 00:28:14,833
a furnace called a bloomery.
521
00:28:14,933 --> 00:28:18,466
This ancient furnace was built
with heat-resistant walls
522
00:28:18,566 --> 00:28:22,366
made of earth, clay, or stone.
523
00:28:22,466 --> 00:28:25,066
At the base,
pipes allowed air to enter
524
00:28:25,166 --> 00:28:28,633
through an elaborate system
of bellows.
525
00:28:28,733 --> 00:28:35,500
The air was pumped manually
by hand or by foot.
526
00:28:35,600 --> 00:28:39,666
Anyone who's been camping
and has made a little campfire
527
00:28:39,766 --> 00:28:43,633
knows that if you lean down
and you blow into the embers,
528
00:28:43,733 --> 00:28:47,533
what they do is they glow
much more brightly.
529
00:28:47,633 --> 00:28:49,433
Because you're introducing
oxygen
530
00:28:49,533 --> 00:28:52,000
and you're raising
its concentration,
531
00:28:52,100 --> 00:28:53,266
you're making it more available.
532
00:28:53,366 --> 00:28:57,200
A fire needs oxygen to burn,
533
00:28:57,300 --> 00:29:01,933
and the more oxygen,
the hotter the flames.
534
00:29:02,033 --> 00:29:05,333
The reaction of oxygen
with the charcoal,
535
00:29:05,433 --> 00:29:07,266
which makes carbon dioxide,
536
00:29:07,366 --> 00:29:09,433
is one which generates
an increase in temperature.
537
00:29:09,533 --> 00:29:13,200
You get a release of heat.
538
00:29:13,300 --> 00:29:18,833
Oxygen made the fire hot enough
to separate iron from stone,
539
00:29:18,933 --> 00:29:23,600
and once again, metal
transformed the way we live,
540
00:29:23,700 --> 00:29:27,166
from tools to weapons.
541
00:29:27,266 --> 00:29:29,766
In time,
the bloomery was replaced
542
00:29:29,866 --> 00:29:33,766
with the more powerful
blast furnace.
543
00:29:33,866 --> 00:29:39,433
And by the 20th century,
iron was everywhere.
544
00:29:39,533 --> 00:29:41,233
The Industrial Revolution
545
00:29:41,333 --> 00:29:44,766
changed nearly every aspect
of life on earth.
546
00:29:44,866 --> 00:29:47,233
But there was a catch.
547
00:29:47,333 --> 00:29:49,666
In the process of smelting iron,
548
00:29:49,766 --> 00:29:54,033
impurities called slag
are left behind.
549
00:29:54,133 --> 00:29:58,233
Slag weakens metal.
550
00:29:58,333 --> 00:30:01,700
Over hundreds of years,
craftsmen discovered that
551
00:30:01,800 --> 00:30:05,400
if iron is hammered and reheated
over and over again,
552
00:30:05,500 --> 00:30:09,700
it gets purer and stronger.
553
00:30:11,666 --> 00:30:13,700
Over time, bit by bit,
554
00:30:13,800 --> 00:30:16,600
they discovered
how to get more and more
555
00:30:16,700 --> 00:30:18,933
of what they wanted
in terms of properties.
556
00:30:19,033 --> 00:30:21,466
But they certainly didn't have
any understanding
557
00:30:21,566 --> 00:30:24,000
at anything even remotely
like the atomic level
558
00:30:24,100 --> 00:30:25,933
of what was going on.
559
00:30:26,033 --> 00:30:30,200
But now we understand that
at the atomic level,
560
00:30:30,300 --> 00:30:34,100
an extraordinary transformation
was taking place.
561
00:30:34,200 --> 00:30:38,166
Iron was turning into one
of the strongest alloys
562
00:30:38,266 --> 00:30:41,666
Earth-- steel.
563
00:30:41,766 --> 00:30:43,333
While hammering
drove out the slag,
564
00:30:43,433 --> 00:30:45,333
the charco in the fire
565
00:30:45,433 --> 00:30:49,666
provided an essential
carbon.
566
00:30:49,766 --> 00:30:53,366
The combination of iron
and carbon to make steel
567
00:30:53,466 --> 00:30:57,633
is almost a unique combination
in the world,
568
00:30:57,733 --> 00:30:59,500
and key to it is that
569
00:30:59,600 --> 00:31:01,966
the iron atom
and the carbon atom
570
00:31:02,066 --> 00:31:03,900
are very different sizes.
571
00:31:04,000 --> 00:31:06,833
When you add a little bit
of carbon to iron,
572
00:31:06,933 --> 00:31:10,433
it tends to hide
in the little gaps
573
00:31:10,533 --> 00:31:12,733
in between the large iron atoms.
574
00:31:12,833 --> 00:31:16,700
The way tin transforms copper
into bronze,
575
00:31:16,800 --> 00:31:21,133
carbon turns iron into steel.
576
00:31:21,233 --> 00:31:24,033
And this is one of the amazing
things about steel.
577
00:31:24,133 --> 00:31:27,066
Just using more or less
just these two elements,
578
00:31:27,166 --> 00:31:30,766
iron and carbon, you can create
lots of different properties
579
00:31:30,866 --> 00:31:33,766
that can be useful
for different applications.
580
00:31:33,866 --> 00:31:38,766
To demonstrate the difference
between iron and steel,
581
00:31:38,866 --> 00:31:40,566
Vinci got access to a piece
582
00:31:40,666 --> 00:31:44,800
of one of the most famous
iron towers ever built.
583
00:31:44,900 --> 00:31:47,433
This is our piece
of the Eiffel Tower.
584
00:31:47,533 --> 00:31:50,033
Discarded after a repair.
585
00:31:50,133 --> 00:31:51,366
I never thought in my life
586
00:31:51,466 --> 00:31:53,433
I would be holding a piece
of the Eiffel Tower.
587
00:31:53,533 --> 00:31:56,133
I mean, I've been up the Eiffel
Tower a couple of times.
588
00:31:56,233 --> 00:31:59,333
The Eiffel Tower is made
of wrought iron,
589
00:31:59,433 --> 00:32:01,800
which has less carbon
than steel.
590
00:32:01,900 --> 00:32:03,633
When the Eiffel Tower was built,
591
00:32:03,733 --> 00:32:06,633
wrought iron construction
was really at its peak.
592
00:32:06,733 --> 00:32:08,833
It's an amazing structure
593
00:32:08,933 --> 00:32:11,100
using an amazing material,
especially for its day.
594
00:32:11,200 --> 00:32:14,700
How does the strength
of the wrought iron
595
00:32:14,800 --> 00:32:18,966
in the Eiffel Tower hold up
against steel?
596
00:32:19,066 --> 00:32:21,833
Rick Vinci and Helen Chan are
about to find out.
597
00:32:21,933 --> 00:32:25,066
Not only do we get to hold
a piece of the Eiffel Tower,
598
00:32:25,166 --> 00:32:26,833
we also get to cut it up
and bend it
599
00:32:26,933 --> 00:32:27,833
and maybe even break it.
600
00:32:27,933 --> 00:32:31,733
They conduct a bends test
601
00:32:31,833 --> 00:32:34,200
to determine how much force
can be applied
602
00:32:34,300 --> 00:32:36,766
to the wrought iron
before it bends.
603
00:32:36,866 --> 00:32:37,800
Here we go.
604
00:32:39,066 --> 00:32:43,333
It not only bends; it breaks.
605
00:32:44,833 --> 00:32:46,366
Wow, it broke.
606
00:32:46,466 --> 00:32:49,200
Okay.
This is actually cracked.
607
00:32:49,300 --> 00:32:52,133
When they test the steel,
608
00:32:52,233 --> 00:32:56,266
there are similarities
and differences.
609
00:32:57,366 --> 00:33:00,233
Well, it actually seems
as if the two samples
610
00:33:00,333 --> 00:33:02,666
behave pretty much
the same.
611
00:33:02,766 --> 00:33:05,300
The load that it took to bend it
was comparable.
612
00:33:07,500 --> 00:33:09,200
Okay, so I see
two differences right away.
613
00:33:09,300 --> 00:33:11,600
First of all,
the wrought iron bar cracked
614
00:33:11,700 --> 00:33:12,966
and the modern steel didn't.
615
00:33:13,066 --> 00:33:15,633
But I see another really
important difference,
616
00:33:15,733 --> 00:33:17,200
which is the modern steel bar
617
00:33:17,300 --> 00:33:20,500
is only half the thickness
of the Eiffel Tower bar,
618
00:33:20,600 --> 00:33:23,900
despite the fact that it carried
exactly the same load.
619
00:33:24,000 --> 00:33:27,066
So all that means is if
you are using a modern steel,
620
00:33:27,166 --> 00:33:28,666
for the same amount of material,
621
00:33:28,766 --> 00:33:30,666
you can support
four times the load.
622
00:33:31,766 --> 00:33:32,333
Wow.
623
00:33:32,433 --> 00:33:33,766
All right.
624
00:33:33,866 --> 00:33:37,000
In fact, around the time
the Eiffel Tower was built,
625
00:33:37,100 --> 00:33:41,133
steel was already on its way
to becoming the metal of choice
626
00:33:41,233 --> 00:33:42,766
for building high.
627
00:33:42,866 --> 00:33:47,200
Chicago's towering ten-story
Home Insurance Building,
628
00:33:47,300 --> 00:33:51,733
the world's first skyscraper,
had a steel frame.
629
00:33:51,833 --> 00:33:54,600
Steel had a huge influence
630
00:33:54,700 --> 00:33:56,666
on the development
of this country
631
00:33:56,766 --> 00:33:58,800
as an dustrial nation.
632
00:33:58,900 --> 00:34:04,500
And today, steel can do things
that are hard to imagine.
633
00:34:04,600 --> 00:34:06,333
Nothing demonstrates that
634
00:34:06,433 --> 00:34:09,400
quite like the Beijing
National Stadium,
635
00:34:09,500 --> 00:34:12,133
nicknamed the Bird's Nest,
636
00:34:12,233 --> 00:34:20,699
42,000 tons packed into a design
that seems to defy logic.
637
00:34:20,800 --> 00:34:24,199
Engineer Michael Kwok
was a project manager
638
00:34:24,300 --> 00:34:28,033
for the design and construction
of the Bird's Nest.
639
00:34:28,133 --> 00:34:29,699
It's more like a jigsaw puzzle,
640
00:34:29,800 --> 00:34:32,566
you just try to figure out
how this was put together.
641
00:34:36,300 --> 00:34:38,633
It is very unlike
642
00:34:38,733 --> 00:34:42,000
pretty much any other structure
that's been built.
643
00:34:42,100 --> 00:34:44,533
If you want to make
a strong structure,
644
00:34:44,633 --> 00:34:46,733
there are certain classic shapes
that work very, very well,
645
00:34:46,833 --> 00:34:48,166
and the truss is a classic one.
646
00:34:48,266 --> 00:34:52,166
If you look at bridges
all over the place,
647
00:34:52,266 --> 00:34:54,333
they have these
triangular elements,
648
00:34:54,433 --> 00:34:56,566
these truss elements that are
very, very strong.
649
00:34:56,666 --> 00:34:59,433
The geometry of a triangle
650
00:34:59,533 --> 00:35:02,500
makes it an inherently
stable shape.
651
00:35:02,600 --> 00:35:04,466
Put several of them in a row
652
00:35:04,566 --> 00:35:06,800
and they distribute the weight
of a structure
653
00:35:06,900 --> 00:35:08,600
to its load-bearing beams.
654
00:35:08,700 --> 00:35:12,066
But the Bird's Nest
looks nothing like that.
655
00:35:12,166 --> 00:35:15,633
But looks can be deceiving.
656
00:35:15,733 --> 00:35:19,566
24 sets of columns
connect to a series of trusses
657
00:35:19,666 --> 00:35:22,133
that support the roof.
658
00:35:22,233 --> 00:35:26,266
All this is hidden
behind a maze of steel.
659
00:35:26,366 --> 00:35:30,400
You can't make that out of just
any run-of-the-mill steel.
660
00:35:30,500 --> 00:35:33,433
You need a particularly
high-strength and tough steel.
661
00:35:33,533 --> 00:35:36,566
The stadium is made
of two kinds of steel.
662
00:35:36,666 --> 00:35:40,866
The recipe for the trusses
provides extra strength.
663
00:36:00,333 --> 00:36:04,533
But to create the beauty
of its winding exterior
664
00:36:04,633 --> 00:36:07,700
required steel
with more flexibility.
665
00:36:07,800 --> 00:36:11,766
For a massive steel structure
like this,
666
00:36:11,866 --> 00:36:16,300
the combination of flexibility
and strength is critical...
667
00:36:18,266 --> 00:36:22,900
especially in an earthquake-
prone region like Beijing.
668
00:36:49,000 --> 00:36:53,366
The bowl of the stadium,
made primarily of concrete,
669
00:36:53,466 --> 00:36:56,166
does not have the elasticity
of steel.
670
00:36:56,266 --> 00:37:00,333
So the engineers and architects
came up with an innovative idea:
671
00:37:00,433 --> 00:37:03,400
separate concrete from steel;
672
00:37:03,500 --> 00:37:07,166
make them work as two
independent structures.
673
00:37:16,566 --> 00:37:19,366
The extraordinary properties
inherent in steel
674
00:37:19,466 --> 00:37:23,733
make it possible for engineers
like Michael Kwok
675
00:37:23,833 --> 00:37:29,866
to build structures like this
that capture the imagination.
676
00:37:42,300 --> 00:37:46,733
Today, by mixing different types
of steel for different purposes,
677
00:37:46,833 --> 00:37:49,700
engineers have taken
the art of steelmaking
678
00:37:49,800 --> 00:37:52,933
to new heights-- literally.
679
00:37:53,033 --> 00:37:58,500
The tallest bridge in the world,
the Millau Viaduct in France,
680
00:37:58,600 --> 00:38:02,333
is made of steel that contains
an element that's quite rare:
681
00:38:02,433 --> 00:38:04,966
niobium.
682
00:38:05,066 --> 00:38:08,900
It is a soft,
whitish gray metal,
683
00:38:09,000 --> 00:38:12,166
and if you add it to steel,
684
00:38:12,266 --> 00:38:15,866
you get a stronger,
lighter material.
685
00:38:15,966 --> 00:38:19,200
When you think about a solid
piece of metal,
686
00:38:19,300 --> 00:38:21,466
it just looks like
it's all the same.
687
00:38:21,566 --> 00:38:23,533
But in fact,
if you really zoom in,
688
00:38:23,633 --> 00:38:25,800
that chunk of metal
is typically made up
689
00:38:25,900 --> 00:38:28,033
of lots of little individual
metal grains.
690
00:38:28,133 --> 00:38:32,133
And it turns out that if you can
make those grains really tiny,
691
00:38:32,233 --> 00:38:33,933
then it makes it
much more difficult
692
00:38:34,033 --> 00:38:36,933
for the atoms to move past
one another to change shape.
693
00:38:37,033 --> 00:38:40,966
So by making the grains tiny,
you make the metal stronger.
694
00:38:41,066 --> 00:38:45,233
Now, niobium prevents
the growth of these grains
695
00:38:45,333 --> 00:38:48,600
very effectively, and then
you can get incredible strength
696
00:38:48,700 --> 00:38:52,033
that comes from having this
very tiny grain size.
697
00:38:52,133 --> 00:38:55,666
Different kinds of steel
can have other additives,
698
00:38:55,766 --> 00:38:59,366
like nickel, chromium,
or manganese.
699
00:38:59,466 --> 00:39:03,233
But there's one
rather bizarre recipe
700
00:39:03,333 --> 00:39:08,266
that could help solve one
of the world's biggest problems.
701
00:39:08,366 --> 00:39:11,733
We've been seeing landfills
as a huge environmental burden,
702
00:39:11,833 --> 00:39:13,666
and of course it appears
that way on the surface
703
00:39:13,766 --> 00:39:17,633
because we don't know
what else to do with it.
704
00:39:17,733 --> 00:39:19,633
But if we can reform
end-of-life materials
705
00:39:19,733 --> 00:39:21,066
into completely different
products,
706
00:39:21,166 --> 00:39:25,266
then suddenly, landfills
shouldn't be seen as a burden;
707
00:39:25,366 --> 00:39:28,700
they should actually be seen
as this amazing possibility.
708
00:39:28,800 --> 00:39:30,033
It's a treasure.
709
00:39:30,133 --> 00:39:34,166
Veena Sahajwalla
has developed a way
710
00:39:34,266 --> 00:39:38,533
to recycle the stuff
nobody wants-- trash--
711
00:39:38,633 --> 00:39:40,733
and turn it into steel.
712
00:39:40,833 --> 00:39:42,433
The most basic steel
713
00:39:42,533 --> 00:39:44,966
is nothing but an alloy
of iron and carbon.
714
00:39:45,066 --> 00:39:46,566
Well, guess what?
715
00:39:46,666 --> 00:39:48,900
We can find carbon in plastics.
716
00:39:49,000 --> 00:39:50,766
The first step:
717
00:39:50,866 --> 00:39:54,300
take some plastic
like this broken headlight.
718
00:39:54,400 --> 00:39:57,500
Look at what I got you!
719
00:39:57,600 --> 00:40:01,000
Cut off a piece and melt it down
720
00:40:01,100 --> 00:40:04,566
to a small pellet
chock full of carbon.
721
00:40:04,666 --> 00:40:08,900
Top it off with a lump
of pure iron.
722
00:40:10,666 --> 00:40:12,966
Place the combo
back in the furnace
723
00:40:13,066 --> 00:40:16,266
and heat it up.
724
00:40:16,366 --> 00:40:20,133
Now watch the alchemy unfold
725
00:40:20,233 --> 00:40:24,733
as the carbon in plastic
bonds with iron.
726
00:40:24,833 --> 00:40:27,200
What's exciting here is that
727
00:40:27,300 --> 00:40:29,033
we're actually seeing
this high-temperature reaction
728
00:40:29,133 --> 00:40:31,033
taking place
right in front of our very eyes.
729
00:40:31,133 --> 00:40:32,366
We've got this liquid metal.
730
00:40:32,466 --> 00:40:36,866
We're now looking
at how this is interacting
731
00:40:36,966 --> 00:40:40,533
with this source of carbon,
which of course is the plastic
732
00:40:40,633 --> 00:40:43,566
that came from a waste
out of a car.
733
00:40:43,666 --> 00:40:45,466
Carbon from that plastic
734
00:40:45,566 --> 00:40:48,266
is actually able to dissolve
into liquid metal.
735
00:40:48,366 --> 00:40:51,133
So this is what's come out
of the furnace.
736
00:40:51,233 --> 00:40:53,733
We've dissolved the carbon
from the plastic
737
00:40:53,833 --> 00:40:55,800
into liquid iron.
738
00:40:55,900 --> 00:40:57,400
And of course,
what we have here is steel.
739
00:40:57,500 --> 00:41:00,133
After a decade of research,
740
00:41:00,233 --> 00:41:04,966
Veena's "green steel" is slowly
making its way out of the lab.
741
00:41:05,066 --> 00:41:08,900
Partnering with the manufacturer
One Steel,
742
00:41:09,000 --> 00:41:13,266
they have already recycled
over two million tires.
743
00:41:13,366 --> 00:41:16,466
Today's tires are made
of a synthetic rubber,
744
00:41:16,566 --> 00:41:19,966
produced from oil
rich in carbon--
745
00:41:20,066 --> 00:41:23,866
the perfect ingredient
for green steel.
746
00:41:23,966 --> 00:41:27,800
And when it comes
to greenhouse gases,
747
00:41:27,900 --> 00:41:31,500
Veena's steel requires
less coal to cook,
748
00:41:31,600 --> 00:41:34,900
and that reduces
its carbon footprint.
749
00:41:35,000 --> 00:41:36,400
As the saying goes, you know,
750
00:41:36,500 --> 00:41:38,733
one person's trash is
somebody else's treasure.
751
00:41:38,833 --> 00:41:39,933
Guess what?
752
00:41:40,033 --> 00:41:43,533
This could become
our society's treasure.
753
00:41:43,633 --> 00:41:45,466
I love steel because
it has really given us
754
00:41:45,566 --> 00:41:49,000
the structures that have
changed this world around us.
755
00:41:49,100 --> 00:41:55,933
Steel has given us the power
to build high and strong.
756
00:41:56,033 --> 00:42:00,566
But as wonderful and versatile
as it is, steel has limitations.
757
00:42:00,666 --> 00:42:05,900
One of the drawbacks to steel
is that it is relatively heavy.
758
00:42:06,000 --> 00:42:09,166
Iron is fairly dense,
and for its strength,
759
00:42:09,266 --> 00:42:11,200
you have to make
massive structures.
760
00:42:11,300 --> 00:42:13,033
And that's fine
if you're building a bridge,
761
00:42:13,133 --> 00:42:15,000
but it's not fine
if you're building something
762
00:42:15,100 --> 00:42:16,000
that needs to move.
763
00:42:18,066 --> 00:42:20,833
And that's where
another extraordinary metal
764
00:42:20,933 --> 00:42:22,833
comes into the picture.
765
00:42:22,933 --> 00:42:28,533
Atomic number 13, aluminum
has just 13 electrons,
766
00:42:28,633 --> 00:42:32,366
13 protons, and 14 neutrons.
767
00:42:32,466 --> 00:42:35,366
In comparison
with a heavier metal like iron,
768
00:42:35,466 --> 00:42:37,133
which has twice the number
769
00:42:37,233 --> 00:42:39,666
of protons, electrons,
and neutrons,
770
00:42:39,766 --> 00:42:43,433
the aluminum atom
is incredibly light.
771
00:42:43,533 --> 00:42:45,833
Aluminum has
an ethereal lightness
772
00:42:45,933 --> 00:42:48,366
that no one could believe.
773
00:42:48,466 --> 00:42:52,000
And yet, it also has some
of the properties like steel
774
00:42:52,100 --> 00:42:54,333
that allow you
to modify its strength
775
00:42:54,433 --> 00:42:57,466
and its other characteristics
to optimize it.
776
00:42:57,566 --> 00:42:59,100
Aluminum has completely
777
00:42:59,200 --> 00:43:00,633
transformed our world,
778
00:43:00,733 --> 00:43:04,700
from the trivial tent pegs
of our tents
779
00:43:04,800 --> 00:43:06,833
to the frames of our aircraft,
780
00:43:06,933 --> 00:43:09,133
where it really makes
a difference.
781
00:43:09,233 --> 00:43:12,333
If we had to build our airplanes
out of steel,
782
00:43:12,433 --> 00:43:14,100
they would have to have
fuel tanks
783
00:43:14,200 --> 00:43:16,733
five or six times bigger
than they do now
784
00:43:16,833 --> 00:43:20,700
and would carry a third
of the passengers.
785
00:43:20,800 --> 00:43:23,400
Today's aluminum is really
fabulous stuff.
786
00:43:23,500 --> 00:43:25,700
If you can live
with a little bit less strength
787
00:43:25,800 --> 00:43:27,400
in exchange
for a lot less weight,
788
00:43:27,500 --> 00:43:29,266
then aluminum is
an excellent choice.
789
00:43:29,366 --> 00:43:31,800
But as we look to the future,
790
00:43:31,900 --> 00:43:35,133
another way to move forward
is to ask ourselves
791
00:43:35,233 --> 00:43:37,733
if what we have been doing
with metals for all these years
792
00:43:37,833 --> 00:43:39,600
is the only thing we can do.
793
00:43:39,700 --> 00:43:46,366
Imagine a material that is not
just light, not just strong,
794
00:43:46,466 --> 00:43:48,833
but flexible enough
to change its shape.
795
00:43:48,933 --> 00:43:51,433
So I think of the Terminator
with this project,
796
00:43:51,533 --> 00:43:52,833
which is super fun,
797
00:43:52,933 --> 00:43:54,433
and I don't think I've seen
the Terminator
798
00:43:54,533 --> 00:43:55,300
since I was young,
799
00:43:55,400 --> 00:43:56,500
but one of the images
800
00:43:56,600 --> 00:44:00,000
that really stuck with me
is the T-1000,
801
00:44:00,100 --> 00:44:01,833
you know, the all-metal guy,
right?
802
00:44:03,100 --> 00:44:06,733
He can change shape
and then self-heals.
803
00:44:06,833 --> 00:44:08,400
Actually, our material
does all those things.
804
00:44:08,500 --> 00:44:12,166
This is metal foam,
805
00:44:12,266 --> 00:44:15,533
a combination
of metal and rubber.
806
00:44:15,633 --> 00:44:19,566
Heat it up and it morphs
into another shape.
807
00:44:19,666 --> 00:44:23,700
And when it's done,
it becomes a solid again.
808
00:44:23,800 --> 00:44:26,333
The idea of this metal foam
is that we can have sothing
809
00:44:26,433 --> 00:44:28,300
that changes its shape
dramatically,
810
00:44:28,400 --> 00:44:30,166
but then after it changes
its shape,
811
00:44:30,266 --> 00:44:32,000
have a lot of strength.
812
00:44:32,100 --> 00:44:36,633
What's the recipe
for making metal foam?
813
00:44:36,733 --> 00:44:40,666
First, take a dash
of Himalayan salt,
814
00:44:40,766 --> 00:44:43,700
add a little dragon skin--
815
00:44:43,800 --> 00:44:46,233
also known as
uncured silicon.
816
00:44:49,533 --> 00:44:52,533
Mix it up,
817
00:44:52,633 --> 00:44:56,100
pour the mixture into a mold,
818
00:44:56,200 --> 00:44:58,500
and let it cure.
819
00:44:58,600 --> 00:45:01,166
Remove the concoction
from the mold
820
00:45:01,266 --> 00:45:05,133
and place it
in an ultrasonic cleaner.
821
00:45:05,233 --> 00:45:09,466
This dissolves away
the Himalayan salt.
822
00:45:09,566 --> 00:45:14,033
What's left behind is a porous,
sponge-like material
823
00:45:14,133 --> 00:45:16,300
riddled with tiny crevices.
824
00:45:16,400 --> 00:45:19,700
Next, submerge the foam
into a bath
825
00:45:19,800 --> 00:45:22,466
of molten Field's metal.
826
00:45:22,566 --> 00:45:23,966
Field's metal is
827
00:45:24,066 --> 00:45:27,800
a low-melting-temperature alloy
of indium, tin, and bismuth.
828
00:45:27,900 --> 00:45:31,900
So at 60 degrees Celsius,
it is a molten liquid.
829
00:45:32,000 --> 00:45:34,600
Below 60 degrees Celsius,
it's a frozen solid.
830
00:45:34,700 --> 00:45:38,300
The metal-covered foam
is sealed in a vacuum chamber,
831
00:45:38,400 --> 00:45:42,466
where the molten metal
seeps into those tiny crevices
832
00:45:42,566 --> 00:45:45,366
that were left behind
by the salt.
833
00:45:45,466 --> 00:45:48,533
Air trapped in the foam
is pushed out
834
00:45:48,633 --> 00:45:50,733
and rises to the surface.
835
00:45:50,833 --> 00:45:55,066
The sample is then removed
from the vacuum chamber
836
00:45:55,166 --> 00:45:57,400
and cooled down.
837
00:45:57,500 --> 00:46:00,233
Once it's at room temperature,
it hardens again.
838
00:46:00,333 --> 00:46:03,300
Shepherd hopes one day,
839
00:46:03,400 --> 00:46:07,300
metal foam will be able
to make like a bird.
840
00:46:09,033 --> 00:46:10,733
One of the problems I'm trying
to solve with this material
841
00:46:10,833 --> 00:46:13,600
is inspired by a puffin.
842
00:46:13,700 --> 00:46:15,700
A puffin can fly,
843
00:46:15,800 --> 00:46:18,866
but then it can dive underwater
to catch fish,
844
00:46:18,966 --> 00:46:20,800
so it has to sweep
its wings back
845
00:46:20,900 --> 00:46:23,266
in order to not have
its wings torn off.
846
00:46:23,366 --> 00:46:26,166
So in an artificial version
of the puffin,
847
00:46:26,266 --> 00:46:27,700
we would want a vehicle
848
00:46:27,800 --> 00:46:30,633
that could turn from a plane
to an underwater glider.
849
00:46:30,733 --> 00:46:33,866
This idea is quite imaginative
and a far-reaching goal,
850
00:46:33,966 --> 00:46:36,100
but we are currently working
on a wing
851
00:46:36,200 --> 00:46:39,233
that we will coat
in a skin of this metal foam,
852
00:46:39,333 --> 00:46:42,266
and we're going to try it out
on a radio-controlled airplane
853
00:46:42,366 --> 00:46:44,200
in the next year.
854
00:46:44,300 --> 00:46:49,700
But metal foam could find
another home-- in space.
855
00:46:49,800 --> 00:46:52,200
If you think about kind of
a limited resources setup,
856
00:46:52,300 --> 00:46:54,266
certainly if you're, like,
in outer space
857
00:46:54,366 --> 00:46:56,266
and you have a limited number
of things
858
00:46:56,366 --> 00:46:57,633
you can bring with you,
859
00:46:57,733 --> 00:46:59,666
and maybe you don't know exactly
what tools you need,
860
00:46:59,766 --> 00:47:01,066
but here you have this material,
861
00:47:01,166 --> 00:47:03,766
and you can really
change its shape
862
00:47:03,866 --> 00:47:06,500
and then lock it in
to whatever you need.
863
00:47:06,600 --> 00:47:09,500
So you can take it one day
and use it as a wrench,
864
00:47:09,600 --> 00:47:12,066
and take it the next day
and use it as a hammer.
865
00:47:12,166 --> 00:47:13,833
One day, metal foam
866
00:47:13,933 --> 00:47:16,866
could make its way
into your toolbox.
867
00:47:16,966 --> 00:47:18,800
Eventually, we believe
868
00:47:18,900 --> 00:47:21,966
this composite could be used
for reconfigurable tools.
869
00:47:22,066 --> 00:47:25,533
At thipoint, we think there
are some flaws in the structure
870
00:47:25,633 --> 00:47:27,400
that may cause it to fracture,
871
00:47:27,500 --> 00:47:28,900
but these are
engineering problems
872
00:47:29,000 --> 00:47:30,366
that we think are very solvable.
873
00:47:30,466 --> 00:47:33,233
While some researchers
874
00:47:33,333 --> 00:47:37,066
are exploring new ways
to combine materials,
875
00:47:37,166 --> 00:47:40,433
others, like David Muller,
876
00:47:40,533 --> 00:47:44,100
are fascinated with a newly
discovered treasure,
877
00:47:44,200 --> 00:47:47,066
the strongest material
ever found:
878
00:47:47,166 --> 00:47:48,633
graphene.
879
00:47:48,733 --> 00:47:53,633
Made of pure carbon, graphene
behaves a lot like a metal,
880
00:47:53,733 --> 00:47:57,566
but it's about 200 times
stronger than steel
881
00:47:57,666 --> 00:48:00,566
and harder than diamonds,
882
00:48:00,666 --> 00:48:06,533
even though it's just
one atom thick.
883
00:48:06,633 --> 00:48:08,100
Graphene has incredible
strength.
884
00:48:08,200 --> 00:48:10,433
Combined with incredible
strength,
885
00:48:10,533 --> 00:48:13,466
it has incredible flexibility.
886
00:48:13,566 --> 00:48:17,500
How strong is graphene?
887
00:48:17,600 --> 00:48:19,166
Some researchers estimate
888
00:48:19,266 --> 00:48:22,600
it would take an elephant
balanced on a pencil
889
00:48:22,700 --> 00:48:24,966
to break through
a sheet of graphene
890
00:48:25,066 --> 00:48:27,600
the thickness of Saran wrap.
891
00:48:29,900 --> 00:48:32,433
Where can it be found?
892
00:48:32,533 --> 00:48:35,266
You have to bake it.
893
00:48:36,733 --> 00:48:40,133
First, take a piece of copper
and place it in an oven.
894
00:48:40,233 --> 00:48:43,933
Fill it with a material
that contains carbon.
895
00:48:44,033 --> 00:48:45,533
David Muller uses methane,
896
00:48:45,633 --> 00:48:50,933
a gas that's a combination
of carbon and hydrogen.
897
00:48:51,033 --> 00:48:53,900
We knock all the hydrogen off
by heating it up very hot,
898
00:48:54,000 --> 00:48:56,600
so that gets turned
into just carbon atoms
899
00:48:56,700 --> 00:48:58,766
that are floating around
in a vapor.
900
00:48:58,866 --> 00:49:02,766
Those carbon atoms fall down
and bombard a flat surface.
901
00:49:02,866 --> 00:49:06,300
So the way you think of this is
902
00:49:06,400 --> 00:49:10,266
my copper surface is just like
a cold window on a cold day,
903
00:49:10,366 --> 00:49:13,066
and then little bits of moisture
are in the air
904
00:49:13,166 --> 00:49:15,666
and they start to condense
onto my cold window,
905
00:49:15,766 --> 00:49:17,800
and instead of growing
little ice crystals
906
00:49:17,900 --> 00:49:19,933
that decorate all the way
across my window,
907
00:49:20,033 --> 00:49:22,266
I'm going to grow little
crystals of carbon
908
00:49:22,366 --> 00:49:25,200
that are going to decorate
my copper surface.
909
00:49:25,300 --> 00:49:27,633
And eventually,
these little crystals
910
00:49:27,733 --> 00:49:29,466
are going to grow bigger
and bigger and bigger
911
00:49:29,566 --> 00:49:31,233
until eventually,
they touch each other,
912
00:49:31,333 --> 00:49:33,766
and then I have one uniform
continuous sheet of carbon,
913
00:49:33,866 --> 00:49:36,166
and that will be the graphene.
914
00:49:36,266 --> 00:49:42,600
What makes this incredibly thin
layer of carbon so strong?
915
00:49:42,700 --> 00:49:47,400
It all comes down
to the arrangement of its atoms.
916
00:49:47,500 --> 00:49:51,933
When six carbon atoms bond,
they form a hexagon.
917
00:49:52,033 --> 00:49:56,333
And as more and more
carbon atoms join the group,
918
00:49:56,433 --> 00:49:59,033
more hexagons take shape.
919
00:49:59,133 --> 00:50:00,433
So you can imagine
920
00:50:00,533 --> 00:50:02,233
that if another carbon atom
comes down
921
00:50:02,333 --> 00:50:05,300
and lands over here,
right in the middle,
922
00:50:05,400 --> 00:50:07,200
it's got nothing to stick to.
923
00:50:07,300 --> 00:50:09,133
It's going to keep rolling
around,
924
00:50:09,233 --> 00:50:11,633
but then it gets to the edge
of the sheet of the graphene
925
00:50:11,733 --> 00:50:14,133
and says, "Wait a minute,
there's a dangling bond.
926
00:50:14,233 --> 00:50:15,933
I want to attach to that."
927
00:50:16,033 --> 00:50:17,866
And then it'll continue
to grow out,
928
00:50:17,966 --> 00:50:19,566
and that's why the sheet gets
bigger and bigger and bigger.
929
00:50:21,700 --> 00:50:23,400
Once the baking is done,
930
00:50:23,500 --> 00:50:27,366
the graphene-coated copper
is taken out of the oven
931
00:50:27,466 --> 00:50:30,866
and placed in a solution that
slowly etches the metal away.
932
00:50:33,133 --> 00:50:37,866
What's left is a small sheet
of graphene.
933
00:50:37,966 --> 00:50:42,166
Exactly what can you do
with a single layer of graphene
934
00:50:42,266 --> 00:50:45,700
that's so thin,
it's barely visible?
935
00:50:45,800 --> 00:50:48,566
So we could imagine graphene
would be very valuable
936
00:50:48,666 --> 00:50:50,400
for things on the nanoscale.
937
00:50:50,500 --> 00:50:54,333
Because it's both tiny
and strong,
938
00:50:54,433 --> 00:50:58,333
it could fit inside a cell
for medical applications
939
00:50:58,433 --> 00:51:02,200
or be placed in dust
for environmental monitoring.
940
00:51:02,300 --> 00:51:06,666
But graphene might also have
applications on the megascale.
941
00:51:06,766 --> 00:51:10,366
If you could build cables,
for instance,
942
00:51:10,466 --> 00:51:12,466
for holding up
suspension bridges.
943
00:51:12,566 --> 00:51:14,133
If you could get
to that size scale,
944
00:51:14,233 --> 00:51:16,300
then that would open up
945
00:51:16,400 --> 00:51:19,700
incredible new
engineering opportunities
946
00:51:19,800 --> 00:51:22,133
for creative people
to make structures
947
00:51:22,233 --> 00:51:24,133
that we really can only
dream of today.
948
00:51:24,233 --> 00:51:29,666
Is graphene the next big thing?
949
00:51:29,766 --> 00:51:32,600
No one can predict
if new materials
950
00:51:32,700 --> 00:51:37,766
like metal foam or graphene
will live up to their promise.
951
00:51:40,400 --> 00:51:43,300
But there's no doubt that metals
952
00:51:43,400 --> 00:51:45,633
have revolutionized
life on Earth,
953
00:51:45,733 --> 00:51:50,400
from the beauty of gold
to the smelting of copper
954
00:51:50,500 --> 00:51:54,300
to the creation of bronze
and steel.
955
00:51:54,400 --> 00:51:59,500
And in the future,
materials we can only dream of.
956
00:51:59,600 --> 00:52:03,333
And the astonishing thing
is that the work of engineers,
957
00:52:03,433 --> 00:52:06,766
of metallurgists,
and of chemists every year
958
00:52:06,866 --> 00:52:10,933
brings us new formulations,
new possibilities
959
00:52:11,033 --> 00:52:15,600
that makes things lighter,
stronger, stiffer,
960
00:52:15,700 --> 00:52:19,266
faster than anything
that came before.
961
00:52:26,866 --> 00:52:29,166
Earth's amazing
natural resources.
962
00:52:29,266 --> 00:52:31,466
We use them to build
our civilization.
963
00:52:31,566 --> 00:52:34,800
I love steel because it has
really given us the structures
964
00:52:34,900 --> 00:52:36,933
that have changed this world
around us.
965
00:52:37,033 --> 00:52:39,766
But how will we power
our future?
966
00:52:39,866 --> 00:52:42,733
The magic of the desert,
the sun, the sand,
967
00:52:42,833 --> 00:52:45,333
they produce a lot of energy
and they can power a whole city.
968
00:52:45,433 --> 00:52:47,433
The quest to fuel tomorrow.
969
00:52:47,533 --> 00:52:51,400
"Treasures of the Earth,"
next time on NOVA.
970
00:53:13,266 --> 00:53:15,800
This NOVAprogram is
available on DVD.
971
00:53:15,900 --> 00:53:21,033
To order, visit shopPBS.org,
or call 1-800-play-PBS.
972
00:53:21,133 --> 00:53:23,633
NOVAis also available
for download on iTunes.
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