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This is the vibrant heart
of a 21st century city.
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There's something strange but
wonderful about Piccadilly Circus.
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Strange because,
as far as the eye can see,
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there's nothing natural.
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There's not a tree, not a flower,
not a blade of grass.
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But wonderful because we made it.
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We've transformed matter
to create the world that we live in.
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My name is Mark Miodownik,
and as a materials scientist
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I've spent my life
trying to understand
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what's hidden
deep beneath the surface
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00:00:47,560 --> 00:00:50,280
of everything
that makes up our modern world.
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For me, the story of how materials
have driven human civilisation
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from the Stone Age
to the Silicon Age
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00:01:04,000 --> 00:01:06,280
is the most exciting story
in science.
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Without our mastery of the stuff
that we found around us,
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we would have no buildings, no cars,
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no roads, no art.
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Nothing.
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This series is the story of how
we created our 21st century world,
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how we unlocked the secrets
of the raw materials of our planet
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and created our future.
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Gleaming, lustrous, volatile metals.
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Everything around us
is shaped by metal.
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Metal has driven human civilisation
- power, war, industry -
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and yet it's mysterious stuff.
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It's only in the last 60 years
that we've begun to unravel
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the secrets hidden deep within
the metal at the atomic scale,
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how it is that it can be
strong enough to build empires
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and yet soft enough
that 1 can crumple it in my hand,
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why it is
that it seems inert and unchanging
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and yet sometimes can behave
almost as if it's alive.
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Take a look at this.
It looks like a normal paperclip,
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but if I scrunch it up
so it's unrecognisable
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and then put a blowtorch on it...
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HE LAUGHS
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Isn't that amazing?
Isn't that marvellous?
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1 mean, that is indistinguishable
from magic.
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This...
This metal remembers its shape.
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Normal metals don't do this.
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We've engineered this metal
to have a memory.
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00:02:53,200 --> 00:02:57,120
How we got from the Stone Age
to being able to manipulate matter
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and make metals like this
is the story of this programme.
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Let me take you back
to when it all began -
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the dawn of civilisation.
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This is where our ancestors
first settled.
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It's where East meets West,
where Africa meets Asia.
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Underneath my feet,
the Earth's crust is shifting.
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And the geology here
gave our ancestors
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00:03:40,160 --> 00:03:44,440
access to something
that would change their world.
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00:03:46,480 --> 00:03:49,480
This is one of
the first places on Earth
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00:03:49,480 --> 00:03:52,040
that man stepped out
of the Stone Age
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and transformed rock into metal.
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00:03:55,280 --> 00:03:58,000
And it all started with copper.
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It's these green streaks
that may have been the first clue
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00:04:03,280 --> 00:04:05,760
there was something
a bit special about this rock.
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00:04:05,760 --> 00:04:09,480
Somehow, we worked out that
when you've got this type of rock,
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you can do something amazing
with it.
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00:04:17,120 --> 00:04:20,840
We don't really know
when our ancestors first discovered
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00:04:20,840 --> 00:04:23,280
what this marvellous
green rock can do.
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00:04:23,280 --> 00:04:24,960
They might have just ground it up
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00:04:24,960 --> 00:04:28,360
to use it as a powder
to decorate their pottery,
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or maybe it happened to be
just lying by the fire.
63
00:04:31,880 --> 00:04:35,600
But either way, they discovered
something really rather marvellous
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00:04:35,600 --> 00:04:38,720
about what this stuff can do
if you add it to a fire.
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00:04:38,720 --> 00:04:42,960
Now, the thing about the fire is,
you need it to be very, very hot
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and for that you need a lot of air,
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00:04:45,920 --> 00:04:48,800
and that's why they built
their fires on hillsides.
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These hillsides are extremely windy,
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00:04:50,880 --> 00:04:53,520
so the air is being funnelled
into the fire.
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00:04:53,520 --> 00:04:56,320
It's actually a genius idea.
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00:04:56,320 --> 00:04:58,800
And then,
when they'd got a very hot fire,
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they added the green rock.
73
00:05:01,640 --> 00:05:05,440
And then they kept the temperature
high for hours, and they waited.
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00:05:12,680 --> 00:05:15,160
So when the fire died down,
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00:05:15,160 --> 00:05:19,880
they would have found bits
of a hard stone, black stone,
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00:05:19,880 --> 00:05:22,040
but amongst that black stone,
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look, there's tiny little
shiny bits of metal.
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00:05:26,480 --> 00:05:30,680
They'd transformed rock into metal,
it's absolutely extraordinary!
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00:05:30,680 --> 00:05:33,920
Here we have rock...
1 mean, there's rock everywhere,
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but they'd found
the power of transformation.
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00:05:39,120 --> 00:05:43,160
Look! Look how bright that is!
A bright piece of copper.
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00:05:43,160 --> 00:05:46,880
We know they did it on this hillside
because we've found the remnants
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from early smelting
of our ancestors.
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00:05:49,920 --> 00:05:52,120
So they did that here,
85
00:05:52,120 --> 00:05:56,360
and this was the beginning
of human civilisation,
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00:05:56,360 --> 00:05:58,400
the age of metals.
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00:06:11,600 --> 00:06:13,960
Our ancestors realised that
with copper,
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they could make strong tools,
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00:06:16,680 --> 00:06:19,520
better than anything
they'd had before.
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00:06:19,520 --> 00:06:23,520
This copper chisel represents
the leap out of the Stone Age.
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00:06:23,520 --> 00:06:26,040
Everything we have
in our civilisation today
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00:06:26,040 --> 00:06:28,400
is due to metal tools like this.
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00:06:28,400 --> 00:06:30,400
If they get blunt,
we can sharpen them.
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00:06:30,400 --> 00:06:32,720
If they get bent,
we can re-straighten them.
95
00:06:32,720 --> 00:06:34,920
If they get damaged,
we can repair them.
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It's simply
the perfect material for tools.
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Nothing else
our ancestors had in their world
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could have done this -
not stone, not bone, not wood.
99
00:06:49,720 --> 00:06:52,800
So what's so special about metal?
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It's all down
to its inner structure.
101
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Metals are made of crystals,
and that's a very surprising fact,
102
00:07:01,840 --> 00:07:03,600
because they don't seem to behave
103
00:07:03,600 --> 00:07:06,480
anything like the crystals
we are more familiar with.
104
00:07:06,480 --> 00:07:09,720
I'll show you what I mean.
I've got a quartz crystal here.
105
00:07:09,720 --> 00:07:12,080
That's what you mean
when you say "crystal".
106
00:07:12,080 --> 00:07:16,040
And this is what a quartz crystal
says when you hit it with a hammer.
107
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You see? That's what we think of
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when we think of crystals being hit
with a hammer.
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00:07:24,200 --> 00:07:28,600
But if 1 say 10 you that this piece
of metal is made of crystals,
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you know already
that it's not going to do that.
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It's going to be quite malleable,
I can do this.
112
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In fact, that's how you work metal,
you change its shape.
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And that's...that's really strange,
because that means
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00:07:42,240 --> 00:07:46,520
that the crystals in this metal are
changing shape instead of exploding.
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00:07:47,640 --> 00:07:49,360
Inside the metal crystal,
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the basic building blocks of
everything in the universe, atoms,
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are arranged
in a regular lattice structure.
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But they're not static.
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00:08:00,840 --> 00:08:04,840
When they're hit, metals can shuffle
atoms from one side to the other,
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00:08:04,840 --> 00:08:06,480
like a Mexican wave.
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00:08:08,680 --> 00:08:11,280
They can move, rearrange themselves,
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and this is why
the crystal can change shape.
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Metals alone behave like this.
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As well as not shattering
when you hit them,
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they actually get stronger.
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00:08:27,960 --> 00:08:30,800
The impact creates waves
of shuffling atoms
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which collide with each other
and create blockages.
128
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These make it harder
for the atoms to shuffle around,
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making the metal stronger.
130
00:08:42,040 --> 00:08:44,000
So the more hammering you do,
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the more blockages you form
in the crystal,
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and so the stronger the metal gets.
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It was the strength of metal
over stone and wood
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that became its main attraction.
135
00:09:02,640 --> 00:09:04,440
With metal tools,
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00:09:04,440 --> 00:09:09,240
our ancestors could conceive
of grandiose projects.
137
00:09:09,240 --> 00:09:13,480
It's believed the limestone blocks
that built the pyramids of Egypt
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were carved using copper chisels.
139
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But soon copper wasn't enough.
140
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Our love affair with metals
consumed us.
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Here on the shores
of what's now Israel,
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metals from distant lands
were traded.
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And it was one of these, tin,
that moved on the story of metals,
144
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as our ancestors
began to mix metals together.
145
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So they took some copper...some tin,
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and they melted them together
to make a mixture,
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which we call an alloy.
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And they created a new metal,
bronze.
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Bronze was the creation
of man the metal-smith,
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rather than a gift of nature,
151
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and it gave its name to a new era,
the Bronze Age.
152
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Now, this is a nail
made out of pure copper,
153
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and as metals go,
copper's pretty weak.
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Have a look at this.
155
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After a while,
it just can't get any further,
156
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and so the metal itself buckles.
157
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If I do the same with tin nail...
let's see what happens.
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Tin is actually softer
than copper, even.
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That's a real joke for a nail,
isn't it?
160
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But here's the odd thing.
161
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The mixture, a bronze nail...
162
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well, this is much stronger.
163
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Ha-ha-ha-ha!
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It's so strong it's knocking
the wood out of this vice.
165
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So that's odd, isn't it?
You add two soft metals together,
166
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and you get something much harder
and much stronger.
167
00:11:00,480 --> 00:11:01,800
How do you explain that?
168
00:11:04,080 --> 00:11:07,320
In bronze, the tin atoms
replace some of the copper atoms,
169
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which are smaller.
170
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This interferes
with the lattice structure,
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making it more difficult for the
atoms to shuffle across the crystal.
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This makes the new alloy
much stronger.
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The strength of bronze
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gave us the means not only to build,
but to destroy.
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As well as tools,
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we made the swords and shields
of conquest and dominion.
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00:11:38,040 --> 00:11:39,840
Bronze propelled the evolution
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of a new, complex,
more technological society.
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It also created new occupations,
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such as mining, manufacturing
and trading metals.
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Bronze dominated the world
for 2,000 years.
182
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But it wasn't the metal
to take us into the industrial age.
183
00:12:00,240 --> 00:12:04,440
About 1200 BC,
another metal rose to prominence.
184
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Iron.
185
00:12:08,720 --> 00:12:13,720
Iron is one of the most plentiful
elements in the Earth's crust,
186
00:12:13,720 --> 00:12:17,240
but it's fiendishly difficult
to work with.
187
00:12:19,720 --> 00:12:25,160
Owen Bush has spent nearly 20 years
learning how to tame iron.
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00:12:25,160 --> 00:12:27,600
It doesn't look very promising
189
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as a way to start a civilisation,
does it?
190
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It's the basics, the beginning of it.
So what happens next?
191
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You take this stuff... Heat it up.
OK. And hit it.
192
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Pure iron can't be easily extracted
from its native rock.
193
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There are several stages before
it can be hammered into submission.
194
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So this whole process of bashing it
195
00:12:57,280 --> 00:13:01,200
and putting it back in the furnace
is to get purer and purer iron.
196
00:13:01,200 --> 00:13:03,640
Yes, it is. You're trying to purify
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00:13:03,640 --> 00:13:07,760
this very strange substance
that's come out of the furnace.
198
00:13:07,760 --> 00:13:10,320
Yeah, I'm literally
beating the crap out of it.
199
00:13:12,200 --> 00:13:14,920
As Owen continues
to hammer the iron,
200
00:13:14,920 --> 00:13:21,040
more and more impurities are exposed
to the air and burn off as sparks.
201
00:13:21,040 --> 00:13:25,920
By bashing it,
you're left with a purer metal.
202
00:13:25,920 --> 00:13:28,520
This is wrought iron,
203
00:13:28,520 --> 00:13:31,640
wrought at the blacksmith's anvil.
204
00:13:31,640 --> 00:13:33,800
If you'd like to have a bash,
by all means.
205
00:13:33,800 --> 00:13:36,640
I would love to do that,
I've never done that before.
206
00:13:36,640 --> 00:13:41,920
Mastery of iron by our ancestors
would not have been easy.
207
00:13:41,920 --> 00:13:45,440
To show me just how difficult it is
to work with, Owen challenges me
208
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to make the simplest and most common
of iron products.
209
00:13:49,080 --> 00:13:52,520
Well, we're going to try and squash
it flat and forge a nail out of it.
210
00:13:52,520 --> 00:13:55,840
1 know in theory
what this stuff should do,
211
00:13:55,840 --> 00:13:59,920
but I've never hit it with a hammer,
I've never done what you do.
212
00:13:59,920 --> 00:14:01,440
That's good to go. OK.
213
00:14:01,440 --> 00:14:02,800
Right.
214
00:14:04,720 --> 00:14:08,360
That's it. Oh, yeah, so there's bits
flying off, 1 can really feel...
215
00:14:08,360 --> 00:14:10,760
You can feel something happening
in the metal.
216
00:14:10,760 --> 00:14:13,200
There's a kind of response to you.
217
00:14:13,200 --> 00:14:17,200
There's something addictive to this.
Yeah, it's primal, isn't it? Yeah!
218
00:14:17,200 --> 00:14:19,920
Now, yeah, back in. Back in, yeah.
219
00:14:19,920 --> 00:14:22,480
You can see, when it came out,
it was bubbling,
220
00:14:22,480 --> 00:14:24,000
and as it cools down the...
221
00:14:24,000 --> 00:14:26,480
Yeah, then 1 can see it
becoming a bit brittle.
222
00:14:26,480 --> 00:14:31,080
It sort of freezes in your hands
and you're not making any headway.
223
00:14:31,080 --> 00:14:34,000
Yeah, well,
you're getting feedback from it,
224
00:14:34,000 --> 00:14:37,520
and because every bit's different,
you have to use that feedback
225
00:14:37,520 --> 00:14:42,040
so you don't end up with a flattened,
destroyed blob, fundamentally.
226
00:14:49,720 --> 00:14:51,800
What I began to learn with Owen
227
00:14:51,800 --> 00:14:54,720
is just how much of this process
is trial and error,
228
00:14:54,720 --> 00:14:58,280
how different iron ores
could behave very differently.
229
00:14:58,280 --> 00:15:02,840
All the variables
of heat, of ore, of fuel
230
00:15:02,840 --> 00:15:05,320
meant that the quality of your iron
231
00:15:05,320 --> 00:15:08,600
depended absolutely
on the quality of your blacksmith.
232
00:15:10,960 --> 00:15:14,000
You're just hammering down to give
it a bit of a head.
233
00:15:16,320 --> 00:15:17,480
Lovely.
234
00:15:18,520 --> 00:15:20,240
That's quite satisfying.
235
00:15:20,240 --> 00:15:22,360
You got some good hits in there.
236
00:15:22,360 --> 00:15:24,640
There we have our little nail.
237
00:15:24,640 --> 00:15:27,920
What a beauty! My first nail.
238
00:15:29,120 --> 00:15:30,280
And it was the iron nail
239
00:15:30,280 --> 00:15:33,120
that was to underpin
the next great civilisation.
240
00:15:38,840 --> 00:15:42,680
The Romans were expert
at manipulating iron.
241
00:15:42,680 --> 00:15:45,680
Their blacksmiths traveled
everywhere with them,
242
00:15:45,680 --> 00:15:48,800
forging the weapons
and shields of Empire.
243
00:15:52,760 --> 00:15:55,880
But the Romans never
built big with iron.
244
00:15:55,880 --> 00:16:00,520
They were limited by what the
blacksmith could do at his anvil.
245
00:16:03,160 --> 00:16:06,080
And so, we would be constrained
for another 1,500 years
246
00:16:06,080 --> 00:16:11,160
until the next great step
in our mastery of metals -
247
00:16:11,160 --> 00:16:15,600
a new technology that would unleash
the Industrial Revolution.
248
00:16:15,600 --> 00:16:19,360
Ironbridge Gorge in Shropshire was
at the heart of this new revolution.
249
00:16:19,360 --> 00:16:22,440
A man called Abraham Darby
started making iron pots
250
00:16:22,440 --> 00:16:24,600
and, almost overnight,
251
00:16:24,600 --> 00:16:28,760
he turned this sleepy valley
into the iron capital of England.
252
00:16:33,400 --> 00:16:35,760
The key was the fuel.
253
00:16:35,760 --> 00:16:39,280
Darby realised that,
with fires made from coke,
254
00:16:39,280 --> 00:16:42,640
partially burned coal, he could
reach much higher temperatures.
255
00:16:42,640 --> 00:16:46,120
And that would do something
that would transform iron.
256
00:16:51,240 --> 00:16:53,560
When it got hot enough,
something happened
257
00:16:53,560 --> 00:16:56,200
that opened up
vast new possibilities for iron.
258
00:16:56,200 --> 00:16:58,120
It melted and became liquid.
259
00:16:59,600 --> 00:17:03,640
This was the birth of a new
type of iron - cast iron.
260
00:17:09,720 --> 00:17:12,880
18th century engineers
must barely have been able
261
00:17:12,880 --> 00:17:14,760
to contain their excitement.
262
00:17:14,760 --> 00:17:19,040
Now, instead of working
iron at an anvil,
263
00:17:19,040 --> 00:17:21,680
they could pour it into a mould.
264
00:17:21,680 --> 00:17:24,640
And the mould could be
any shape or size they wanted.
265
00:17:30,240 --> 00:17:34,240
Darby's furnaces
worked around the clock.
266
00:17:34,240 --> 00:17:35,920
They turned the night sky red.
267
00:17:35,920 --> 00:17:39,400
And the roar could be
heard for miles around.
268
00:17:39,400 --> 00:17:43,880
There seemed no limit to what this
exuberant new industry could do.
269
00:17:43,880 --> 00:17:48,200
And this was proof of it. It was
built by Abraham Darby's grandson.
270
00:17:48,200 --> 00:17:52,040
And it was the first iron
bridge in the world.
271
00:18:07,440 --> 00:18:09,360
This was a golden
age of engineering,
272
00:18:09,360 --> 00:18:13,320
when it seemed only our imaginations
could limit us.
273
00:18:13,320 --> 00:18:15,880
We crossed whole countries
with iron railways.
274
00:18:15,880 --> 00:18:17,880
We crossed rivers with iron bridges.
275
00:18:17,880 --> 00:18:19,920
TRAIN WHISTLE SOUNDS
276
00:18:19,920 --> 00:18:23,120
The engineers of
the industrial world
277
00:18:23,120 --> 00:18:27,160
were seduced into thinking that
their every ambition was achievable.
278
00:18:30,000 --> 00:18:33,760
But, the dreams were
about to come crashing down.
279
00:18:33,760 --> 00:18:38,400
On 1st June, 1878, the great
and the good of Victorian Britain
280
00:18:38,400 --> 00:18:42,880
were assembled by the banks
of the River Tay here in Dundee
281
00:18:42,880 --> 00:18:46,880
to applaud the opening of
the longest bridge in the world.
282
00:18:56,880 --> 00:18:59,360
It had been
designed by Thomas Bouch,
283
00:18:59,360 --> 00:19:02,480
an ambitious railway engineer,
who may have considered
284
00:19:02,480 --> 00:19:05,600
the Tay Bridge a stepping stone
to a knighthood.
285
00:19:07,640 --> 00:19:11,680
But, one dark winter's night
in 1879 would change all that.
286
00:19:13,720 --> 00:19:17,320
A train left Edinburgh, north,
on the Aberdeen line.
287
00:19:17,320 --> 00:19:20,400
Storms were raging
across the country.
288
00:19:20,400 --> 00:19:22,360
And when the train got to the Tay,
289
00:19:22,360 --> 00:19:26,520
gale force winds were
ripping through here.
290
00:19:26,520 --> 00:19:30,000
As the train crossed the bridge,
something terrible happened.
291
00:19:30,000 --> 00:19:34,400
The iron girders cracked,
and the bridge collapsed.
292
00:19:34,400 --> 00:19:37,400
The train plunged
into the icy waters.
293
00:19:39,040 --> 00:19:40,720
There were no survivors.
294
00:19:42,680 --> 00:19:45,280
It was a terrible human tragedy.
295
00:19:45,280 --> 00:19:49,360
But what made it worse was that
it was a man-made tragedy.
296
00:19:49,360 --> 00:19:52,160
The pinnacle of our engineering
achievement,
297
00:19:52,160 --> 00:19:54,200
the iron bridge, had failed.
298
00:19:57,400 --> 00:20:00,440
Nobody had any idea why.
299
00:20:00,440 --> 00:20:02,600
It was a Victorian mystery.
300
00:20:17,440 --> 00:20:21,680
1 asked Rhona Rogers, from Dundee
Museum, how events unfolded that night.
301
00:20:21,680 --> 00:20:26,280
A couple of hours after the train
had plunged into the water,
302
00:20:26,280 --> 00:20:29,680
crowds began to gather on
the north side of the bridge.
303
00:20:29,680 --> 00:20:33,400
People looking for loved ones
that were expected home
304
00:20:33,400 --> 00:20:36,560
waited for news with none coming.
305
00:20:36,560 --> 00:20:39,840
Tell me about Thomas Bouch,
how did he react?
306
00:20:39,840 --> 00:20:43,000
He was on the boat the next day
that went out
307
00:20:43,000 --> 00:20:46,520
to look for survivors
or any signs of the wreckage,
308
00:20:46,520 --> 00:20:50,040
and he was described as being
in a very sorry state.
309
00:20:50,040 --> 00:20:55,520
And he rapidly became very ill and
then died a couple of months later.
310
00:20:55,520 --> 00:21:00,960
He died from water on the lung,
that's the official cause of death,
311
00:21:00,960 --> 00:21:04,600
but a lot of people say it was
shame and stress,
312
00:21:04,600 --> 00:21:08,160
the shame and stress of what had
happened, about his loss of career
313
00:21:08,160 --> 00:21:11,640
and not becoming the success in life
he had wanted.
314
00:21:11,640 --> 00:21:14,840
How did the rest of the country
react?
315
00:21:14,840 --> 00:21:16,440
Was it just a local tragedy?
316
00:21:16,440 --> 00:21:20,840
No, it was the longest bridge of
its type at this time in the world,
317
00:21:20,840 --> 00:21:23,920
so reactions were global.
318
00:21:23,920 --> 00:21:27,160
It affected engineering
on a world scale.
319
00:21:27,160 --> 00:21:30,320
And it was a very personal
thing for people in Dundee.
320
00:21:30,320 --> 00:21:33,840
Quite significant, isn't it, that you can
still see the remnants of the bridge now?
321
00:21:33,840 --> 00:21:36,320
They're like tombstones,
aren't they?
322
00:21:36,320 --> 00:21:39,120
Yes, a permanent memorial
to the dead, yes,
323
00:21:39,120 --> 00:21:44,160
the 75 who lost their lives,
of which only 45 were washed ashore.
324
00:21:45,600 --> 00:21:50,480
The cornerstone of the
Industrial Revolution - cast iron -
325
00:21:50,480 --> 00:21:52,960
had failed catastrophically.
326
00:21:52,960 --> 00:21:56,600
Now the burning question was, why?
327
00:21:59,120 --> 00:22:01,680
In the immediate aftermath
of the disaster,
328
00:22:01,680 --> 00:22:04,400
there were many theories
as to what had gone wrong.
329
00:22:04,400 --> 00:22:07,760
I've come to Sheffield University
to test my own theory.
330
00:22:10,440 --> 00:22:14,800
Postgraduate students Ben Thomas
and Lucy Johnson have designed
331
00:22:14,800 --> 00:22:18,200
and built a scale model of one
of the bridge's iron pillars,
332
00:22:18,200 --> 00:22:20,840
and we're going to put it
to the test.
333
00:22:22,960 --> 00:22:26,840
So, just like in the real structure, you had
these cast irons and this cross brace stuff
334
00:22:26,840 --> 00:22:31,240
is exactly how the piers of this
railway bridge were constructed? Yeah.
335
00:22:31,240 --> 00:22:35,120
'The corners of each pier of the
bridge were made of cast iron,
336
00:22:35,120 --> 00:22:37,800
'and that's what
we're testing today.
337
00:22:39,120 --> 00:22:43,760
'The first test is to see how good the pillar
is at carrying loads under compression.'
338
00:22:45,560 --> 00:22:50,160
'Could the cast iron have collapsed
just under the weight of the train?
339
00:22:50,160 --> 00:22:53,320
Cast iron's supposed to be quite
strong in compression,
340
00:22:53,320 --> 00:22:56,720
so we've got a very simple compression
test straight through the middle here.
341
00:22:58,360 --> 00:23:01,560
'We started to apply
pressure to the model.
342
00:23:01,560 --> 00:23:04,840
'But before the pillar gave way,
this happened..
343
00:23:04,840 --> 00:23:06,560
LOUD METALLIC CLANG
344
00:23:06,560 --> 00:23:11,680
Oh dear, what was that?
What happened there?
345
00:23:11,680 --> 00:23:15,400
There's no obvious breaks,
which is good news.
346
00:23:15,400 --> 00:23:20,080
It may be that it started to crack
up here on the test rig.
347
00:23:20,080 --> 00:23:21,280
Really?
348
00:23:21,280 --> 00:23:25,400
So we might have broken the test
rig... No, don't say that!
349
00:23:25,400 --> 00:23:27,120
Lucy, give me hope.
350
00:23:27,120 --> 00:23:32,040
We can't see that anything's obviously
broken with the bridge itself. OK.
351
00:23:32,040 --> 00:23:35,160
So, the good news is that the bridge
is stronger than our test rig?
352
00:23:35,160 --> 00:23:36,800
It looks that way, yeah.
353
00:23:36,800 --> 00:23:40,000
'Cast iron is known to be strong
under compression,
354
00:23:40,000 --> 00:23:44,800
'and the bridge had taken the weight
of the train many times before.
355
00:23:44,800 --> 00:23:47,920
'But there were other forces at play
on the bridge that night,
356
00:23:47,920 --> 00:23:50,480
'not least the strong winds.'
357
00:23:50,480 --> 00:23:54,960
So, because of the wind, the gale
force winds, there were forces
358
00:23:54,960 --> 00:23:59,160
on these cast iron struts that
would be making them bend that way.
359
00:23:59,160 --> 00:24:01,920
They were all trying to bend
over like a tree in the wind,
360
00:24:01,920 --> 00:24:05,800
and the question is, can that
material take that kind of force?
361
00:24:07,000 --> 00:24:10,520
'In that situation, one side
of the bridge will be compressed,
362
00:24:10,520 --> 00:24:13,560
'but the other side will stretch.
363
00:24:13,560 --> 00:24:16,880
'So 1 took a single bar
from the model
364
00:24:16,880 --> 00:24:20,120
"and this time 1 put it in a machine
hat tests the metal under tension.
365
00:24:21,360 --> 00:24:24,200
'I'm going to see what happens
when you stretch it.'
366
00:24:25,720 --> 00:24:26,840
BANG
367
00:24:26,840 --> 00:24:29,520
'With very little force, it snaps.'
368
00:24:31,920 --> 00:24:36,440
'At the point where the bar broke is
evidence of what makes cast-iron weak.'
369
00:24:36,440 --> 00:24:40,760
Look at where it's fractured.
There's this enormous hole there.
370
00:24:40,760 --> 00:24:45,120
That is an impurity in the material
which has very little strength,
371
00:24:45,120 --> 00:24:48,360
and when you use a microscope
to look at this material
372
00:24:48,360 --> 00:24:52,160
you see not only big flaws in it,
like these strange holes,
373
00:24:52,160 --> 00:24:56,680
but deep inside the metal there
are loads of little black blobs,
374
00:24:56,680 --> 00:25:01,280
black-grey blobs, and they are
a material called graphite.
375
00:25:01,280 --> 00:25:06,120
They're embedded in the material,
and there's no way to remove them,
376
00:25:06,120 --> 00:25:09,800
you can make them smaller but they
are always going to be in cast iron.
377
00:25:10,920 --> 00:25:15,400
It's the very process of making
cast iron that causes its weakness.
378
00:25:15,400 --> 00:25:18,680
The casting process
traps in many of the impurities
379
00:25:18,680 --> 00:25:21,440
that a blacksmith
would have hammered out.
380
00:25:23,280 --> 00:25:26,760
The most important one is
graphite - carbon.
381
00:25:29,080 --> 00:25:33,880
It forms lumps that sit within
the microstructure of the metal.
382
00:25:33,880 --> 00:25:36,560
And it's these lumps
that make the metal weak.
383
00:25:37,920 --> 00:25:39,720
This is what graphite looks like.
384
00:25:39,720 --> 00:25:42,560
You know it, because
it's the stuff of your pencil.
385
00:25:42,560 --> 00:25:43,920
It's a very weak material,
386
00:25:43,920 --> 00:25:48,720
so if you have loads of this stuff
embedded in your iron,
387
00:25:48,720 --> 00:25:52,160
it's not surprising that
that iron is going to be weak.
388
00:25:53,200 --> 00:25:57,720
But back in the 19th century,
this interior world of metals
389
00:25:57,720 --> 00:25:59,680
was still hidden from us.
390
00:26:03,440 --> 00:26:07,160
What it comes down to is this -
we were building bridges out of iron
391
00:26:07,160 --> 00:26:09,640
without fully
understanding the material.
392
00:26:09,640 --> 00:26:12,160
We needed to change our relationship
with metal
393
00:26:12,160 --> 00:26:14,680
from one of mastery
to one of understanding.
394
00:26:16,480 --> 00:26:20,040
All we really knew was that
cast iron had failed us.
395
00:26:20,040 --> 00:26:22,880
We desperately needed
a stronger metal.
396
00:26:24,040 --> 00:26:27,080
But the answer wouldn't lie in
making the purist iron possible.
397
00:26:27,080 --> 00:26:30,760
It would turn out to be far
more complex.
398
00:26:33,840 --> 00:26:38,240
The Victorian engineers looked to history
for the strongest iron they could find.
399
00:26:40,160 --> 00:26:44,600
The metal smiths of old used it to
make swords of legendary strength.
400
00:26:45,720 --> 00:26:48,120
They called it 'good iron'.
401
00:26:48,120 --> 00:26:50,320
We call it steel.
402
00:26:53,560 --> 00:26:58,480
Back in the forge, Owen is going to
reveal the secret of good iron -
403
00:26:58,480 --> 00:27:01,960
making the iron pure,
but not too pure.
404
00:27:03,520 --> 00:27:06,880
Following the techniques
of ancient swordsmiths,
405
00:27:06,880 --> 00:27:11,440
he hammers the iron and then folds,
and heats and folds again,
406
00:27:11,440 --> 00:27:15,880
exposing more and more of the iron to
the air, so the impurities burn away.
407
00:27:19,480 --> 00:27:22,240
So I'm just going to
cut it in half...
408
00:27:24,840 --> 00:27:26,440
Then bend it back on itself.
409
00:27:30,200 --> 00:27:31,600
Back in the fire.
410
00:27:31,600 --> 00:27:34,640
We had four layers,
now we've got eight, next fold 16.
411
00:27:34,640 --> 00:27:38,280
If this was to be the edge material
of the blade I'd probably
412
00:27:38,280 --> 00:27:41,120
take it up to somewhere between 700
and couple of thousand layers.
413
00:27:41,120 --> 00:27:42,760
A thousand layers?
414
00:27:49,800 --> 00:27:53,240
So what's coming off the edge there?
That's iron oxide.
415
00:27:53,240 --> 00:27:54,880
So that's its skin, really? Yeah.
416
00:27:57,560 --> 00:28:02,240
'Through a combination of skill
and experience the swordsmiths knew
417
00:28:02,240 --> 00:28:06,160
'when their metal was pure enough
to hammer into a blade.
418
00:28:07,320 --> 00:28:11,440
'Then they added at touch of magic
- it's called quenching.
419
00:28:13,600 --> 00:28:16,360
'They thrust the red hot
blade into a cooling liquid.
420
00:28:19,200 --> 00:28:23,280
"When they drew it out again
the edge had hardened!
421
00:28:24,280 --> 00:28:27,280
When you read the accounts
written down about this process,
422
00:28:27,280 --> 00:28:31,240
you find all sorts
of weird materials,
423
00:28:31,240 --> 00:28:36,000
like, people would get the urine
of a redheaded boy,
424
00:28:36,000 --> 00:28:40,320
or they'd get a goat which had
only fed on the fern for three days
425
00:28:40,320 --> 00:28:43,480
and they would quench into that -
what do you think about this?
426
00:28:43,480 --> 00:28:49,920
If it worked, if your master smith taught you
to quench in the urine of a redheaded boy,
427
00:28:49,920 --> 00:28:53,880
then if it worked for him there's
no reason why you'd stop.
428
00:28:53,880 --> 00:28:55,680
And, also it adds mystique,
doesn't it?
429
00:28:55,680 --> 00:28:59,840
'Technique and temperature
worked a mysterious alchemy,
430
00:28:59,840 --> 00:29:03,440
'creating a metal
that kept its sharp edge.
431
00:29:03,440 --> 00:29:06,800
"A metal with almost magical
properties.
432
00:29:08,200 --> 00:29:12,160
The master swordsmiths
had manipulated iron so skilfully
433
00:29:12,160 --> 00:29:15,800
they had unwittingly
created a totally new metal.
434
00:29:15,800 --> 00:29:17,600
Steel.
435
00:29:17,600 --> 00:29:21,120
The strong, reliable metal
the Victorian engineers needed
436
00:29:21,120 --> 00:29:23,560
to fulfil their growing ambitions.
437
00:29:26,080 --> 00:29:28,960
But the problem is,
as we've just seen,
438
00:29:28,960 --> 00:29:32,800
it takes a huge amount of time,
effort, expertise,
439
00:29:32,800 --> 00:29:35,280
to just make this one, small blade.
440
00:29:35,280 --> 00:29:37,600
So, if the Victorians
were going to use steel,
441
00:29:37,600 --> 00:29:40,680
they were going to have to learn
how to mass-produce it.
442
00:29:40,680 --> 00:29:45,360
And in order to do that they would have to
find out what was going on inside this metal.
443
00:29:47,000 --> 00:29:51,760
A clue would come from another
feature of the swordsmith's art.
444
00:29:51,760 --> 00:29:56,280
The pattern of the sword was
the must-have mark of quality.
445
00:29:57,560 --> 00:30:01,400
Dipping the swords in acid made
the intricate swirling patterns,
446
00:30:01,400 --> 00:30:06,480
created by the folding, twisting and
hammering, become more pronounced.
447
00:30:07,760 --> 00:30:10,280
This process was called etching.
448
00:30:11,640 --> 00:30:16,720
And etching would be the key
to revealing the secret of steel,
449
00:30:16,720 --> 00:30:19,000
exactly what it was made of.
450
00:30:20,080 --> 00:30:25,880
Here in Sheffield, in 1863,
the single-minded dedication
451
00:30:25,880 --> 00:30:29,600
of one man provided the flash
of insight that changed everything.
452
00:30:32,000 --> 00:30:36,640
Henry Clifton Sorby was perhaps
the last great scientific amateur
453
00:30:36,640 --> 00:30:41,320
in an age when science was becoming
the concern of professionals.
454
00:30:41,320 --> 00:30:46,760
Sorby pretty much invented the idea of
looking at metals through microscopes.
455
00:30:46,760 --> 00:30:49,800
He was ridiculed by his colleagues.
456
00:30:51,240 --> 00:30:54,440
But he persevered,
and it's lucky for as he did.
457
00:30:54,440 --> 00:30:57,600
Here, I'm proud to say,
I have in front of me
458
00:30:57,600 --> 00:31:00,320
the original samples he first made.
459
00:31:01,480 --> 00:31:05,160
Sorby prepared his steel
samples in exactly the same way
460
00:31:05,160 --> 00:31:08,720
as the ancient sword Smiths -
he etched them.
461
00:31:10,280 --> 00:31:14,400
And when he looked at the intricate
patterns under the microscope,
462
00:31:14,400 --> 00:31:17,400
Sorby discovered
the secret of steel's strength.
463
00:31:19,200 --> 00:31:23,040
This is a 150-year-old
sample that he prepared.
464
00:31:23,040 --> 00:31:27,920
Let me show you what he saw
and no-one else had ever seen.
465
00:31:29,000 --> 00:31:36,240
The microscope revealed that steel was a very
pure form of iron, much purer than cast-iron.
466
00:31:36,240 --> 00:31:39,600
But there's still a small
amount of impurity there.
467
00:31:39,600 --> 00:31:43,920
The dark bits that look like rivers
are crystals that contain carbon.
468
00:31:45,160 --> 00:31:49,480
It turned out the whole premise
of the iron industry had been false.
469
00:31:49,480 --> 00:31:53,400
Everyone had thought that what you had
to do was beat out the impurities -
470
00:31:53,400 --> 00:31:55,960
the purer the iron you could get
the better it would be -
471
00:31:55,960 --> 00:31:57,160
And they were wrong.
472
00:31:58,880 --> 00:32:03,920
Instead, what was needed was precisely
the right amount of impurity.
473
00:32:03,920 --> 00:32:08,520
An alloy of iron and carbon
in exactly the right proportions.
474
00:32:12,800 --> 00:32:15,600
This is the crystal
lattice of pure iron.
475
00:32:17,720 --> 00:32:19,480
And this is steel.
476
00:32:20,880 --> 00:32:23,800
Carbon atoms sit in the gaps
between the iron atoms,
477
00:32:23,800 --> 00:32:25,520
making steel much stronger.
478
00:32:26,960 --> 00:32:30,440
But you have to have just
the right amount of carbon.
479
00:32:33,280 --> 00:32:36,520
In cast iron,
there's too much carbon
480
00:32:36,520 --> 00:32:40,360
and the spare carbon atoms form
larger blobs within the crystal
481
00:32:40,360 --> 00:32:42,320
and make the metal weaker.
482
00:32:49,560 --> 00:32:52,680
Now we knew what made steel
so strong.
483
00:32:54,400 --> 00:32:57,440
But we were still in the dark
about how to produce it cheaply
484
00:32:57,440 --> 00:33:01,840
and on the industrial scale
that the 19th-century demanded.
485
00:33:03,120 --> 00:33:07,000
One day, a Sheffield-based engineer
called Henry Bessemer
486
00:33:07,000 --> 00:33:10,160
stood up at a British science
meeting and shocked his audience
487
00:33:10,160 --> 00:33:13,160
by announcing he could
mass-produce steel.
488
00:33:13,160 --> 00:33:17,600
It required no hammering,
no beating, no folding.
489
00:33:17,600 --> 00:33:22,800
He could make tonnes of the stuff
in this, his Bessemer converter.
490
00:33:27,560 --> 00:33:32,440
This huge bucket that Bessemer
designed would have contained
491
00:33:32,440 --> 00:33:34,360
an enormous amount of molten iron,
492
00:33:34,360 --> 00:33:37,720
and that, of course,
was full of carbon.
493
00:33:37,720 --> 00:33:42,520
So what Bessemer suggested was that you made
this pipe that goes down the bottom here,
494
00:33:42,520 --> 00:33:45,960
and they pumped air
through the liquid iron,
495
00:33:45,960 --> 00:33:49,400
and that air contained oxygen,
and the oxygen reacted
496
00:33:49,400 --> 00:33:52,960
with the carbon to create
carbon dioxide.
497
00:33:52,960 --> 00:33:57,040
And Bessemer's idea was to just
do that long enough to get
498
00:33:57,040 --> 00:34:00,080
the carbon content of the iron
down to about 1%.
499
00:34:00,080 --> 00:34:03,920
And he designed these enormous
cranks on the side here,
500
00:34:03,920 --> 00:34:07,880
so when the carbon content
of the steel is exactly right
501
00:34:07,880 --> 00:34:11,360
you just crank the whole bucket
over and out pours masses
502
00:34:11,360 --> 00:34:14,560
and masses of this
beautiful, liquid steel.
503
00:34:19,760 --> 00:34:24,560
'I'm going to make steel in a way
that's based on Bessemer's principle.
504
00:34:24,560 --> 00:34:29,880
'"Molten iron, which is full of impurities
like carbon, is poured into a bucket.
505
00:34:29,880 --> 00:34:32,480
"1 blow oxygen through it,
506
00:34:32,480 --> 00:34:35,600
'just as air was blown
through Bessemer's converter.
507
00:34:35,600 --> 00:34:39,160
'The oxygen reacts with a carbon
to form carbon dioxide,
508
00:34:39,160 --> 00:34:42,160
'removing most of the carbon.
509
00:34:42,160 --> 00:34:47,400
'So you should be left with just the
right amount of carbon to make steel.'
510
00:34:49,040 --> 00:34:51,840
Well, the process may be simple,
but it's insane.
511
00:34:51,840 --> 00:34:55,880
I mean you are pumping oxygen
or air through a liquid metal,
512
00:34:55,880 --> 00:34:59,320
and it gets white hot
and it's bubbling and you think,
513
00:34:59,320 --> 00:35:01,440
this is fine,
making a small cauldron of it,
514
00:35:01,440 --> 00:35:05,360
but imagine making a bucket load
of the stuff the size of this room!
515
00:35:05,360 --> 00:35:07,720
That's what Bessemer was doing,
and having a go at it
516
00:35:07,720 --> 00:35:11,240
1 realise quite
how avant-garde he was.
517
00:35:11,240 --> 00:35:13,760
What he was proposing was
really extraordinary.
518
00:35:15,240 --> 00:35:19,600
But the process had a major
disadvantage - it just didn't work.
519
00:35:21,960 --> 00:35:25,560
It was too difficult
to hit precisely
520
00:35:25,560 --> 00:35:28,200
the right amount of carbon -
just under 1%.
521
00:35:30,440 --> 00:35:33,720
Bessemer and his converter
faced financial ruin.
522
00:35:36,120 --> 00:35:37,760
But not for long.
523
00:35:39,000 --> 00:35:43,920
British metallurgist Robert Forester
Mushet came to his rescue.
524
00:35:46,400 --> 00:35:49,920
He suggested they should
remove all the carbon
525
00:35:49,920 --> 00:35:52,560
and then add 1% back in.
526
00:35:54,640 --> 00:35:55,800
It worked.
527
00:35:59,400 --> 00:36:04,080
For the first time we could
mass-produce high-quality steel.
528
00:36:04,080 --> 00:36:06,240
We now had a metal
that was strong enough
529
00:36:06,240 --> 00:36:09,440
and tough enough
to fulfil our ambitions.
530
00:36:13,520 --> 00:36:16,320
The breakthrough
made Bessemer's name,
531
00:36:16,320 --> 00:36:20,280
but he had to be forced to acknowledge
the part Mushet had played.
532
00:36:22,720 --> 00:36:25,760
In the end,
Bessemer had to agree to pay him
533
00:36:25,760 --> 00:36:28,640
£300 a year for
the rest of his life.
534
00:36:30,760 --> 00:36:36,000
With mass-produced steel we'd
cracked the problem of strength.
535
00:36:36,000 --> 00:36:38,720
90% of the metal
we make today is steel.
536
00:36:41,760 --> 00:36:46,520
It's allowed as to travel across the
globe by rail...
537
00:36:46,520 --> 00:36:48,320
...by road...
538
00:36:48,320 --> 00:36:50,520
...and by sea.
539
00:36:50,520 --> 00:36:56,040
Strong, reliable steel enabled us
to build great cities.
540
00:36:56,040 --> 00:36:59,320
The construction industry
would be nowhere without steel,
541
00:36:59,320 --> 00:37:04,200
and the destruction industry
benefited just as much.
542
00:37:07,320 --> 00:37:11,160
But steel was not the answer
to all our ambitions.
543
00:37:11,160 --> 00:37:14,960
Aluminium would be
the metal of the next century.
544
00:37:16,600 --> 00:37:20,920
The century when the secret inner world
of metals would finally be revealed.
545
00:37:22,640 --> 00:37:26,560
The thing about metals is
they all look roughly the same.
546
00:37:26,560 --> 00:37:30,160
But they're not the same.
This is steel and this is aluminium.
547
00:37:33,040 --> 00:37:36,000
Aluminium is three times
lighter than steel.
548
00:37:38,840 --> 00:37:42,880
Here was the perfect metal
to take us into the next age -
549
00:37:42,880 --> 00:37:45,240
the age of flight.
550
00:37:45,240 --> 00:37:50,000
Except for one thing - aluminium
is just not strong enough.
551
00:37:52,720 --> 00:37:58,000
Scientists around the world began to
look for ways to make aluminium stronger.
552
00:37:59,080 --> 00:38:02,680
Among them was the German
metallurgist, Alfred Wilm.
553
00:38:04,520 --> 00:38:10,240
Wilm knew that our ancestors had
strengthened copper by mixing it with tin,
554
00:38:10,240 --> 00:38:15,840
and what made steel strong was having
the right combination of iron and carbon.
555
00:38:15,840 --> 00:38:20,400
So, he set about mixing aluminium
with other metals.
556
00:38:22,080 --> 00:38:25,800
He finally ended up with
an alloy of aluminium, copper,
557
00:38:25,800 --> 00:38:28,040
manganese and magnesium.
558
00:38:28,040 --> 00:38:29,800
He named it duralumin.
559
00:38:31,640 --> 00:38:34,480
And then he thought, when you want
to make really hard steel,
560
00:38:34,480 --> 00:38:37,360
what you do is you quench it,
so he took those alloys
561
00:38:37,360 --> 00:38:41,160
and he put them
in a furnace and he quenched them.
562
00:38:41,160 --> 00:38:42,600
Here it is...
563
00:38:44,000 --> 00:38:47,160
...and I'm going to quench it.
564
00:38:50,560 --> 00:38:56,080
Now, once he'd quenched the alloys
the moment of truth came.
565
00:38:57,840 --> 00:39:00,920
Would it be as strong as steel?
566
00:39:05,040 --> 00:39:06,440
No.
567
00:39:07,720 --> 00:39:12,080
And this happened time and time
and time and time again.
568
00:39:13,400 --> 00:39:16,760
Until he could take
the disappointment no more.
569
00:39:16,760 --> 00:39:19,480
He stormed out of his lab and...
570
00:39:19,480 --> 00:39:22,400
...went boating for a few days.
571
00:39:24,800 --> 00:39:28,040
But while he was
messing about on the river,
572
00:39:28,040 --> 00:39:30,920
something remarkable happened.
573
00:39:30,920 --> 00:39:36,000
Something that Wilm had neither
planned nor even imagined possible.
574
00:39:36,000 --> 00:39:38,280
This is the same alloy.
575
00:39:38,280 --> 00:39:41,920
The only differences is it's a week
later now, and watch this.
576
00:39:45,000 --> 00:39:47,000
It's much, much stronger.
577
00:39:49,480 --> 00:39:54,240
'And this is what Wilm found when
he returned from his boating trip.
578
00:39:54,240 --> 00:39:58,280
'Without Wilm lifting a finger,
his alloy had transformed itself
579
00:39:58,280 --> 00:40:02,320
'from a weak, bendy substance
into a strong, rigid one.
580
00:40:03,840 --> 00:40:06,800
'It was almost as though
the lump of inert metal
581
00:40:06,800 --> 00:40:12,520
'he had left behind was a living
thing that had changed over time.
582
00:40:12,520 --> 00:40:14,480
'It had grown harder as it aged.'
583
00:40:16,280 --> 00:40:19,480
What Wilm had discovered was
something called age hardening.
584
00:40:19,480 --> 00:40:21,080
Let me show you how it works.
585
00:40:21,080 --> 00:40:23,840
So, if this is a crystal
of aluminium,
586
00:40:23,840 --> 00:40:26,560
we know that's really soft.
587
00:40:26,560 --> 00:40:29,280
What we need is something
that's going to make it stronger.
588
00:40:29,280 --> 00:40:32,760
Actually, he'd found an alloy
which, when you leave it over time,
589
00:40:32,760 --> 00:40:37,400
tiny little crystals
grow inside the aluminium crystals.
590
00:40:37,400 --> 00:40:42,440
They emerge out of a kind
of atomistic mist, and it's those
591
00:40:42,440 --> 00:40:47,040
that harden the crystal, they make
it stronger, they reinforce it.
592
00:40:52,560 --> 00:40:55,720
As new crystals grow,
they interfere with the lattice,
593
00:40:55,720 --> 00:41:00,080
and the aluminium alloy's ability
to shuffle atoms and change shape.
594
00:41:01,160 --> 00:41:03,200
This makes it harder and stronger.
595
00:41:08,560 --> 00:41:11,960
Wilm had solved the problem of
how to make aluminium stronger.
596
00:41:13,560 --> 00:41:18,120
And he had also revealed metals to
be mutable, almost living materials.
597
00:41:19,640 --> 00:41:25,000
So many of the great discoveries
of science come by happy accident.
598
00:41:25,000 --> 00:41:29,960
From Alfred Wilm's despair
came a new understanding of metals,
599
00:41:29,960 --> 00:41:34,280
an understanding that would finally
allow us to conquer the skies.
600
00:41:37,680 --> 00:41:44,280
His alloy, duralumin, was used to
make the fuselage of the Spitfire -
601
00:41:44,280 --> 00:41:49,480
the only Allied aircraft to remain a front
line fighter throughout the Second World War.
602
00:41:51,600 --> 00:41:55,720
War forced the pace,
with new and better alloys.
603
00:41:55,720 --> 00:41:58,440
Peacetime brought the desire
for passenger flight.
604
00:41:59,640 --> 00:42:03,320
We were about to push metals
harder than ever before.
605
00:42:08,080 --> 00:42:13,360
In great secrecy, the De Havilland
company here in Hertfordshire
606
00:42:13,360 --> 00:42:19,120
embarked on an ambitious plan to build
the world's first commercial jet aircraft,
607
00:42:19,120 --> 00:42:23,640
to tame and harness changeable,
mutable metal
608
00:42:23,640 --> 00:42:27,440
and build a plane strong
and reliable enough
609
00:42:27,440 --> 00:42:31,000
to soar twice as high as man
had gone before.
610
00:42:34,200 --> 00:42:37,080
The plane was
the ultimate in modern technology.
611
00:42:37,080 --> 00:42:41,600
It went higher and faster,
and boasted a pressurised cabin
612
00:42:41,600 --> 00:42:45,760
for the comfort of the jet age
passengers and crew.
613
00:42:45,760 --> 00:42:49,040
It was also the most tested
aircraft of its time.
614
00:42:53,640 --> 00:42:58,720
Mike Ramsden was one of
the test engineers on this,
615
00:42:58,720 --> 00:43:00,240
"the De Havilland Comet.
616
00:43:00,240 --> 00:43:03,520
Can you remember the moment
when you stood on an airfield
617
00:43:03,520 --> 00:43:07,000
looking at this Comet taking off,
the comet you'd tested?
618
00:43:07,000 --> 00:43:09,000
It was...
619
00:43:09,000 --> 00:43:14,200
It was like watching something
from outer space, it was so...
620
00:43:14,200 --> 00:43:18,080
...new, and it sounds corny,
doesn't it?
621
00:43:18,080 --> 00:43:21,120
But there was nothing
else like it in the world.
622
00:43:21,120 --> 00:43:24,480
When the crew were up
at double the height
623
00:43:24,480 --> 00:43:27,640
and double the speed of propeller
airliners,
624
00:43:27,640 --> 00:43:30,120
they just couldn't believe it,
625
00:43:30,120 --> 00:43:33,760
being able to see both sides
of the Channel at the same time.
626
00:43:33,760 --> 00:43:35,840
And flying high,
you had pressurised the cabin.
627
00:43:36,880 --> 00:43:40,960
Yes, this was a very big
engineering challenge.
628
00:43:40,960 --> 00:43:43,560
To pressurise the fuselage
629
00:43:43,560 --> 00:43:48,320
so that human beings could
survive at that height.
630
00:43:58,560 --> 00:44:01,040
It was the way to go,
it was the way to fly.
631
00:44:01,040 --> 00:44:03,160
It was the way to arrive.
632
00:44:07,240 --> 00:44:10,840
It seemed that a golden age
of air travel had dawned.
633
00:44:12,360 --> 00:44:15,600
But it was about to
turn to disaster.
634
00:44:18,480 --> 00:44:22,600
A year to the day after
the first passenger flight,
635
00:44:22,600 --> 00:44:26,960
a Comet disintegrated in midair,
killing everybody on board.
636
00:44:28,320 --> 00:44:32,680
Within months, two more Comets
had crashed into the Mediterranean.
637
00:44:32,680 --> 00:44:34,760
The entire fleet was grounded.
638
00:44:36,800 --> 00:44:40,200
There was something going on at the
heart of metal we didn't understand.
639
00:44:41,920 --> 00:44:44,120
Did the whole staff,
you and all your workmates,
640
00:44:44,120 --> 00:44:46,880
did you all feel responsible?
641
00:44:46,880 --> 00:44:52,000
Did we feel guilty,
you mean, of killing 100 people?
642
00:44:52,000 --> 00:44:54,360
Yes, is the short answer.
643
00:45:05,320 --> 00:45:07,600
Finding the cause was now
the priority for Mike
644
00:45:07,600 --> 00:45:09,200
and his colleagues.
645
00:45:09,200 --> 00:45:13,120
They knew metal
was a mutable material,
646
00:45:13,120 --> 00:45:17,720
that it could suffer from a damaging
phenomenon called metal fatigue.
647
00:45:17,720 --> 00:45:20,160
They had tested
extensively for this.
648
00:45:22,200 --> 00:45:24,920
But what they couldn't predict
were the effects
649
00:45:24,920 --> 00:45:28,040
of this extreme new environment
and the pressurising
650
00:45:28,040 --> 00:45:32,520
and de-pressurising of the cabin
needed for high altitude flight.
651
00:45:35,880 --> 00:45:37,960
The real problem was
a combination of factors,
652
00:45:37,960 --> 00:45:41,640
one of which was that this aircraft
had to go higher
653
00:45:41,640 --> 00:45:46,080
than ever before, up five miles
high, which caused a compression
654
00:45:46,080 --> 00:45:48,120
and decompression of the fuselage,
655
00:45:48,120 --> 00:45:51,040
so you have it almost
breathing in and out, in and out,
656
00:45:51,040 --> 00:45:52,920
every time it takes off and lands.
657
00:45:55,240 --> 00:45:58,840
The stress of constant
pressurisation and de-pressurisation
658
00:45:58,840 --> 00:46:00,800
eventually tolled on this aeroplane.
659
00:46:03,120 --> 00:46:05,840
Metal will break
if you bend it often enough.
660
00:46:05,840 --> 00:46:09,400
In the Comet's fuselage,
tiny fatigue cracks appeared.
661
00:46:09,400 --> 00:46:13,560
What began as a very small fracture
close to a window
662
00:46:13,560 --> 00:46:16,280
spread in to a catastrophic crack.
663
00:46:16,280 --> 00:46:18,760
The whole aircraft came
apart mid-flight.
664
00:46:18,760 --> 00:46:21,040
The cause was
a combination of metal fatigue
665
00:46:21,040 --> 00:46:24,600
and concentrations of stress
within the fuselage.
666
00:46:26,480 --> 00:46:30,000
It's a weird quirk of fate
that these windows were square
667
00:46:30,000 --> 00:46:32,480
because that's exactly
the wrong shape
668
00:46:32,480 --> 00:46:35,440
if you want to minimise
the concentration of stress.
669
00:46:35,440 --> 00:46:39,320
So at the corners the stress
is all concentrated
670
00:46:39,320 --> 00:46:41,440
and started forming little cracks,
671
00:46:41,440 --> 00:46:44,760
it was those that were
the big problem.
672
00:46:44,760 --> 00:46:48,160
Today we know that you mustn't have
square windows
673
00:46:48,160 --> 00:46:50,720
in these kind
of pressure structures.
674
00:46:50,720 --> 00:46:54,040
If you look at any aircraft today,
you'll never see a square window.
675
00:46:56,960 --> 00:46:58,960
Comet changed everything.
676
00:46:58,960 --> 00:47:01,560
New regulations would make sure
that metal was replaced
677
00:47:01,560 --> 00:47:03,480
before it became fatigued.
678
00:47:03,480 --> 00:47:07,240
But the most important lesson we
learnt was just how little we knew.
679
00:47:09,520 --> 00:47:12,800
Extreme conditions were causing
extreme reactions
680
00:47:12,800 --> 00:47:15,760
inside the metal
that we didn't understand.
681
00:47:15,760 --> 00:47:18,760
We desperately needed
to see what was happening
682
00:47:18,760 --> 00:47:21,960
deep inside the metal crystal.
683
00:47:24,920 --> 00:47:27,440
One young scientist was about
to make a breakthrough
684
00:47:27,440 --> 00:47:30,560
and I know him really well because a
few decades later
685
00:47:30,560 --> 00:47:33,600
he was one of my lecturers here
at Oxford University,
686
00:47:33,600 --> 00:47:35,720
Professor Sir Peter Hirsch.
687
00:47:40,200 --> 00:47:44,960
Hirsch's team was one of the first
to take thin foils of metal
688
00:47:44,960 --> 00:47:48,680
and look at them under a brand new
kind of microscope,
689
00:47:48,680 --> 00:47:51,040
a transmission electron microscope,
690
00:47:51,040 --> 00:47:54,520
which increased magnification
by tens of thousands.
691
00:47:54,520 --> 00:47:58,200
Hirsch would finally see inside
the metal crystal
692
00:47:58,200 --> 00:48:02,280
and what he found would send shock waves
around the world of material science.
693
00:48:05,120 --> 00:48:07,120
Meeting up with
Professor Hirsch again,
694
00:48:07,120 --> 00:48:11,000
he explained that in the 1950s
there were theories
695
00:48:11,000 --> 00:48:15,000
about why metals behaved
as they did, but still no proof.
696
00:48:17,080 --> 00:48:21,000
What was really needed
was an experimental technique
697
00:48:21,000 --> 00:48:26,680
which was universally applicable
whereby you could see inside metals.
698
00:48:29,000 --> 00:48:31,400
And that's what Hirsch discovered.
699
00:48:31,400 --> 00:48:34,720
This is the film
he took of his original experiments.
700
00:48:34,720 --> 00:48:40,280
He saw for the first time
deep inside the metal crystal,
701
00:48:40,280 --> 00:48:42,920
where, incredibly,
the metal looked like it was alive.
702
00:48:42,920 --> 00:48:47,640
Those moving little lines and loops
are the Mexican waves of atoms
703
00:48:47,640 --> 00:48:50,720
shuffling across the metal crystal.
704
00:48:50,720 --> 00:48:53,840
They're changing
the shape of the crystal.
705
00:48:53,840 --> 00:48:56,720
Suddenly everything fell into place.
706
00:48:56,720 --> 00:49:00,320
The technique revealed
a new micro-world, if you like,
707
00:49:00,320 --> 00:49:02,160
inside a metal.
708
00:49:02,160 --> 00:49:06,320
You suddenly saw
the inside of a metal
709
00:49:06,320 --> 00:49:09,720
and all sorts of things
were revealed.
710
00:49:09,720 --> 00:49:15,120
It was very, very exciting.
711
00:49:15,120 --> 00:49:17,760
We were now in a position to prove
712
00:49:17,760 --> 00:49:20,120
what had previously
only been guessed at...
713
00:49:20,120 --> 00:49:23,080
That metals were dynamic crystals,
714
00:49:23,080 --> 00:49:25,080
that these ripples were caused
by atoms
715
00:49:25,080 --> 00:49:28,640
shuffling within the crystal,
changing the metal's shape.
716
00:49:31,120 --> 00:49:34,640
This explained what we'd known for
centuries, but never fully understood...
717
00:49:34,640 --> 00:49:36,960
Why metal would change shape
718
00:49:36,960 --> 00:49:41,240
rather than crack
when it was hit with a hammer.
719
00:49:41,240 --> 00:49:45,880
And also why it became stronger
when it was alloyed.
720
00:49:45,880 --> 00:49:49,040
It showed that designing
the internal architecture of metal
721
00:49:49,040 --> 00:49:51,640
was the key to progress.
722
00:49:54,880 --> 00:50:01,000
Microscopy finally allowed us to
master the micro-world of metals.
723
00:50:03,480 --> 00:50:06,680
Hirsch's breakthrough reignited
our passion and belief for metals.
724
00:50:06,680 --> 00:50:08,720
We could start to design
our own metals,
725
00:50:08,720 --> 00:50:11,240
and there was a huge flowering
of metallurgy.
726
00:50:11,240 --> 00:50:14,520
There seemed to be no problem
we couldn't solve.
727
00:50:14,520 --> 00:50:17,880
'And we were facing another.
728
00:50:17,880 --> 00:50:21,600
'How to get a metal to work in the
most extreme environment on earth.
729
00:50:21,600 --> 00:50:24,120
'A jet engine.'
730
00:50:24,120 --> 00:50:26,440
Let me show you what 1 mean.
731
00:50:26,440 --> 00:50:28,080
Inside jet engines,
732
00:50:28,080 --> 00:50:30,760
is an incredibly difficult
place for metals to be.
733
00:50:30,760 --> 00:50:32,760
Extremely hot temperatures.
734
00:50:32,760 --> 00:50:35,320
Extremely high stress
they had to put up with.
735
00:50:35,320 --> 00:50:37,040
So they had to design a new alloy
736
00:50:37,040 --> 00:50:38,960
that could cope
with this environment.
737
00:50:38,960 --> 00:50:40,880
And it was called "superalloy”.
738
00:50:40,880 --> 00:50:43,760
So-called because it was so super.
739
00:50:43,760 --> 00:50:45,360
Here's a bit of it here.
740
00:50:45,360 --> 00:50:47,520
I'm going to pit it against
our old friend steel,
741
00:50:47,520 --> 00:50:49,600
who, of course, we know and love.
742
00:50:49,600 --> 00:50:52,200
I'm going to hang weights
off these two wires.
743
00:50:52,200 --> 00:50:53,840
It's the same weight, in both cases,
744
00:50:53,840 --> 00:50:57,160
and they're the same
thickness of wire.
745
00:50:57,160 --> 00:50:59,000
So, now they're under
the same stress.
746
00:50:59,000 --> 00:51:01,600
Now, I'm going to make it
harder for them,
747
00:51:01,600 --> 00:51:05,240
because they'll have to hold that up
while under huge temperatures,
748
00:51:05,240 --> 00:51:08,920
which means me
putting a blowtorch on them.
749
00:51:08,920 --> 00:51:12,280
OK, are you guys ready? Let's go.
750
00:51:17,400 --> 00:51:20,480
So, the steel wire succumbed
within a few seconds.
751
00:51:20,480 --> 00:51:24,600
And that's only a fraction
of the heat inside a jet engine.
752
00:51:27,160 --> 00:51:31,120
1 could be here all day
with the superalloy.
753
00:51:31,120 --> 00:51:32,680
This superalloy can take this.
754
00:51:34,400 --> 00:51:37,680
I know these metals all look the
same, but inside this superalloy
755
00:51:37,680 --> 00:51:39,720
is the most-exquisite
microstructure,
756
00:51:39,720 --> 00:51:43,280
that was designed for this purpose.
757
00:51:43,280 --> 00:51:45,680
To control the movement
inside the metal,
758
00:51:45,680 --> 00:51:49,080
and make it unbelievably strong
at high temperatures.
759
00:51:51,680 --> 00:51:54,240
'The cubes of material
within the superalloy
760
00:51:54,240 --> 00:51:56,480
'are called "gamma prime crystals".
761
00:51:56,480 --> 00:51:57,960
'They sit within the alloy,
762
00:51:57,960 --> 00:52:00,040
'affecting its ability
to change shape.
763
00:52:01,520 --> 00:52:03,760
'Which makes it incredibly strong,
764
00:52:03,760 --> 00:52:06,600
'even at temperatures
close to its melting point.'
765
00:52:09,400 --> 00:52:10,920
That's pretty impressive,
766
00:52:10,920 --> 00:52:13,120
and, as the jet age progressed,
767
00:52:13,120 --> 00:52:16,080
scientists and engineers
pushed the technology,
768
00:52:16,080 --> 00:52:19,040
to create more and more
powerful engines.
769
00:52:22,000 --> 00:52:24,880
'Superalloys were some
of the strongest metals
770
00:52:24,880 --> 00:52:26,240
'we had ever created.
771
00:52:26,240 --> 00:52:29,360
'But the 21st century jet engine
772
00:52:29,360 --> 00:52:30,760
'would push them to their limit.
773
00:52:30,760 --> 00:52:33,800
'In this extreme environment,
774
00:52:33,800 --> 00:52:36,640
'even superalloys
will change shape.
775
00:52:36,640 --> 00:52:40,320
One of the things we love about
metals is their malleability.
776
00:52:40,320 --> 00:52:42,800
When it's red hot,
it behaves like plastic.
777
00:52:42,800 --> 00:52:45,120
You can make it into
whatever shape you want.
778
00:52:45,120 --> 00:52:49,040
This is wonderful stuff
to make an engine out of.
779
00:52:49,040 --> 00:52:52,120
But the problem is,
when you're making an engine
780
00:52:52,120 --> 00:52:54,600
that needs to be operating
at temperatures
781
00:52:54,600 --> 00:52:56,040
that are themselves red hot,
782
00:52:56,040 --> 00:52:58,880
deep inside the engine,
you've got engine parts
783
00:52:58,880 --> 00:53:01,360
that really musn't change shape.
784
00:53:01,360 --> 00:53:05,960
'These turbine blades operate
at 1,700 degrees centigrade,
785
00:53:05,960 --> 00:53:07,880
'and 10,000 RPM.
786
00:53:07,880 --> 00:53:09,760
'If working in those conditions
787
00:53:09,760 --> 00:53:13,240
'made them lengthen,
even a tiny bit,
788
00:53:13,240 --> 00:53:15,480
a phenomenon known as "creep”,
789
00:53:15,480 --> 00:53:17,960
'catastrophe would follow!
790
00:53:17,960 --> 00:53:21,200
These engines are designed
with the precision of a watchmaker.
791
00:53:21,200 --> 00:53:24,640
Here, at the back of the engine, you
can see the turbine blades rotating
792
00:53:24,640 --> 00:53:26,800
within the casing.
793
00:53:26,800 --> 00:53:29,600
If there's any creep
in those turbine blades,
794
00:53:29,600 --> 00:53:32,360
they'll hit the casing, and the
whole thing will seize up.
795
00:53:32,360 --> 00:53:33,760
And that must not happen.
796
00:53:33,760 --> 00:53:37,160
Unlike with a car, there's no
hard shoulder in the sky.
797
00:53:40,560 --> 00:53:42,920
'Creep can affect any metal.
798
00:53:42,920 --> 00:53:45,560
'In extreme environments,
799
00:53:45,560 --> 00:53:47,640
'the boundaries where crystals join
800
00:53:47,640 --> 00:53:52,480
'can become routes that atoms travel
along, elongating the crystals!
801
00:53:54,440 --> 00:53:58,120
So, what can we do about creep?
802
00:53:58,120 --> 00:54:00,840
Metals are made of crystals,
803
00:54:00,840 --> 00:54:04,520
and if the crystal boundaries
are the problem,
804
00:54:04,520 --> 00:54:07,840
we can't take all the crystals out.
805
00:54:07,840 --> 00:54:09,920
Or can we?
806
00:54:13,680 --> 00:54:17,840
'This is the Rolls-Royce
turbine blade facility, in Derby.
807
00:54:17,840 --> 00:54:21,680
'An entire factory dedicated
to making blades,
808
00:54:21,680 --> 00:54:24,840
'which work right at the heart
of a 21st century jet engine.
809
00:54:27,800 --> 00:54:30,480
'Here, they're actually
producing turbine blades
810
00:54:30,480 --> 00:54:33,840
'from a single metal crystal,
811
00:54:33,840 --> 00:54:35,880
'like a giant diamond of metal.
812
00:54:35,880 --> 00:54:38,840
'These blades are
resistant to creep.
813
00:54:41,920 --> 00:54:46,440
"Paul Withey is a casting specialist
at Rolls-Royce!
814
00:54:46,440 --> 00:54:48,960
This is where we cast
the single crystal turbine blades.
815
00:54:48,960 --> 00:54:50,800
This is the wax model of the blade.
816
00:54:50,800 --> 00:54:53,280
What actually do is,
as part of the assembly process,
817
00:54:53,280 --> 00:54:55,840
we'll fit in the spiral
onto the bottom of it,
818
00:54:55,840 --> 00:54:58,800
to allow us to grow a lot of
crystals in at the bottom.
819
00:54:58,800 --> 00:55:01,040
One crystal is selected
through a spiral,
820
00:55:01,040 --> 00:55:03,720
and made to grow through the whole
of the rest of the blade.
821
00:55:03,720 --> 00:55:07,080
'This is astonishing stuff.
822
00:55:07,080 --> 00:55:09,120
'We've conquered creep,
823
00:55:09,120 --> 00:55:12,040
'by growing our own metal.
824
00:55:12,040 --> 00:55:14,400
'The crystal boundaries
that cause creep
825
00:55:14,400 --> 00:55:16,880
'are prevented by the spiral tube,
826
00:55:16,880 --> 00:55:20,080
'which stops all but one
metal crystal getting through,
827
00:55:20,080 --> 00:55:25,560
"allowing that single crystal
Yo grow into the whole mould!
828
00:55:25,560 --> 00:55:28,400
It's amazing that one of our
earliest activities with metal
829
00:55:28,400 --> 00:55:30,000
was to cast it.
830
00:55:30,000 --> 00:55:32,280
It's really where we came from,
as a civilisation.
831
00:55:32,280 --> 00:55:35,200
Here we are, one of the most
sophisticated pieces of metallurgy
832
00:55:35,200 --> 00:55:38,160
you can possibly do,
and it's casting again.
833
00:55:38,160 --> 00:55:41,520
Yes. And it's actually using the
same process that was used
834
00:55:41,520 --> 00:55:44,880
over 5,000 years ago, to make art
and religious artefacts,
835
00:55:44,880 --> 00:55:46,880
and here today is being used to make
836
00:55:46,880 --> 00:55:50,920
some of the most hi-tech engineering
components that you can find.
837
00:56:00,600 --> 00:56:02,920
'In this age of single crystal
turbine blades,
838
00:56:02,920 --> 00:56:06,200
'it seems that we've finally
understood how metals work,
839
00:56:06,200 --> 00:56:09,040
'and how to make them work for us.
840
00:56:11,000 --> 00:56:13,520
'Paul, and the engineers
at Rolls-Royce,
841
00:56:13,520 --> 00:56:16,400
'are all upbeat about
the future of metals.
842
00:56:16,400 --> 00:56:18,520
'But not everybody agrees.
843
00:56:21,920 --> 00:56:24,720
'Some of my colleagues
in material science
844
00:56:24,720 --> 00:56:27,480
'are beginning to think
we've outgrown metals.
845
00:56:27,480 --> 00:56:29,000
'We've mastered them,
846
00:56:29,000 --> 00:56:31,680
'and now we should move on
to other materials.
847
00:56:31,680 --> 00:56:34,640
'But should we dismiss them
so easily?'
848
00:56:34,640 --> 00:56:37,040
Metals are in everything around us.
849
00:56:37,040 --> 00:56:40,280
The electricity that made
that kettle boil
850
00:56:40,280 --> 00:56:43,360
came down a wire, and that wire
itself is made of metal.
851
00:56:43,360 --> 00:56:44,920
Here's some.
852
00:56:44,920 --> 00:56:46,400
It's copper.
853
00:56:46,400 --> 00:56:49,640
So, the Copper Age is embedded
in our homes.
854
00:56:49,640 --> 00:56:51,800
It delivers all our
electricity to us.
855
00:56:51,800 --> 00:56:54,880
Then, the Bronze Age is still here,
856
00:56:54,880 --> 00:56:56,720
for anyone who likes sculpture.
857
00:56:56,720 --> 00:56:59,360
Beautiful, aesthetic material.
858
00:56:59,360 --> 00:57:02,680
The Iron Age is here,
859
00:57:02,680 --> 00:57:04,800
and steel?
860
00:57:04,800 --> 00:57:08,240
We spent thousands of years honing
this material to be strong, tough,
861
00:57:08,240 --> 00:57:10,320
and ultra-sharp.
862
00:57:10,320 --> 00:57:12,200
Let's not forget the modern metals.
863
00:57:12,200 --> 00:57:14,160
We fly around with aluminium,
864
00:57:14,160 --> 00:57:16,960
but it's in our kitchens, too,
865
00:57:16,960 --> 00:57:19,080
in this lovely, wafer-thin metal,
866
00:57:19,080 --> 00:57:22,720
which is just extraordinarily
versatile.
867
00:57:24,040 --> 00:57:27,120
But there's something a little sad
about the history of metals.
868
00:57:27,120 --> 00:57:29,120
Each one starts out
as a revolution.
869
00:57:29,120 --> 00:57:34,040
But, after a while, they recede,
and we take them for granted.
870
00:57:34,040 --> 00:57:36,480
But 1 really don't think we should.
871
00:57:36,480 --> 00:57:39,760
If it wasn't for metals,
we'd still be in the Stone Age.
872
00:57:39,760 --> 00:57:44,640
Everything around us is shaped
by metals. Everything.
873
00:57:44,640 --> 00:57:49,320
It's that step-by-step understanding
of the internal structure of metals,
874
00:57:49,320 --> 00:57:51,360
the secret world
of the metal crystal,
875
00:57:51,360 --> 00:57:53,880
that's been a huge
intellectual achievement.
876
00:57:53,880 --> 00:57:57,320
Metals have driven
civilisation forward.
877
00:57:57,320 --> 00:58:01,000
And, in doing so, they've defined
who we are as humans.
878
00:58:01,000 --> 00:58:04,160
And that's something
we should be VERY proud of.
879
00:58:26,120 --> 00:58:29,120
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